Due to its physicochemical properties, nanoparticles titanium dioxide (nTiO₂) is being put into mass production and widespread applications, which inevitably results in their increasing exposure to the water body. After it entering the water body, the chemical properties of nTiO₂ can be influenced by ion compositions, ion strength and pH, which affects their ecological risk. Excess of ammonium (NH₄⁺) fertilizer has contaminated soil and water environments. In this paper, the Zeta potentials and hydrodynamic radius of nTiO₂ were studied in NH₄⁺ solution compared to those in Na⁺ solution. In addition, the sedimentation rate of nTiO₂ was also investigated. The experiment results show that high pH inhibits the sedimentation of nTiO₂. Moreover, NH₄⁺ increases the stability of nTiO₂ more than Na⁺ at the same IS, which was attributed the more negative Zeta potentials and the smaller hydraulic radius. Our results provide a theoretical basis for evaluating the ecological risk of nTiO₂ in aqueous solution containing NH₄⁺.

We studied Zeta potentials of nanoparticles titanium dioxides （nTiO₂） in different concentration of NaNO₃ and phosphate (P) solutions. In addition, the effect of flow rate on the transport of nTiO₂ in P was investigated at pH＝6.5. Experimental results show that the Zeta potential of nTiO₂ is compressed with the increasing ion concentration (IC) of NaNO₃ at pH＝6.5. The negative charge increases with the augment of P. Therefore, the high P and low NaNO3 induce the stabilization of nTiO₂ aggregates. The transport experiments suggest that the rapid flow rate is favorable for the transportability of nTiO₂ and soluble phosphate. The breakthrough transport curves (BTCs) of nTiO₂ in sand columns can be fitted well with two-site kinetic attachment model. The modeling results suggest that the values of first-order attachment rate coefficients (k₂) and detachment rate coefficients (k_2d) on site 2 and first-order attachment rate coefficients (k₁) on site 1 are responsible to the attaching efficiency of nTiO₂ on sands and their transportability.