Synthesis of macro-mesoporous Titania (Titanium dioxide-TiO2) nanospheres was successfully achieved using a modified template-free methodology to incorporate macroporous channels into a mesoporous TiO2 framework to form mixed macro-mesoporous TiO2 spheres (MMPT), which were doped with carbon dots (C-dots) to form improved nanocomposites (C-dots@MMPT). Elemental composition, surface bonding and optical properties of these nanocomposites were characterized by X-ray diffraction (XRD), Fourier transforms infrared spectroscopy (FTIR) and ultraviolet-visible absorption spectroscopy (UV-VIS). Evaluation of photocatalytic activity for each (C-Dots@MMPT) sample was performed via degrading the Methylene Blue (MB) dye compared with bare samples (MMPT) under visible light irradiation using 300 Watt halogen lamp.
Lead halide perovskites are the new rising generation of semiconductor materials due to their unique optical and electrical properties. The investigation of the interaction of halide perovskites and light is a key issue not only for understanding their photophysics but also for practical applications. Hence, tremendous efforts have been devoted to this topic and brunch into two: (i) decomposition of the halide perovskites thin films under light illumination; and (ii) influence of light soaking on their photoluminescence (PL) properties. In this review, we for the first time thoroughly compare the illumination conditions and the sample environment to correlate the PL changes and decomposition of perovskite under light illumination. In the case of vacuum and dry nitrogen, PL of the halide perovskite (MAPbI3–xClx, MAPbBr3–xClx, MAPbI3) thin films decreases due to the defects induced by light illumination, and under high excitations, the thin film even decomposes. In the presence of oxygen or moisture, light induces the PL enhancement of halide perovskite (MAPbI3) thin films at low light illumination, while increasing the excitation, which causes the PL to quench and perovskite thin film to decompose. In the case of mixed halide perovskite ((MA)Pb(BrxI1-x)3) light induces reversible segregation of Br domains and I domains.
The mining sector faces a complex dilemma as an economic development agent through social upliftment in places where mining corporations operate. Resource extraction is destructive and non-renewable, making it dirty and unsustainable. To ensure corporate sustainability, this paper examines the effects of knowledge management (KM), organizational learning (OL), and innovation capability (IC) on Indonesian coal mining’s organizational performance (OP). We used factor and path analysis to examine the relationships between the above constructs. After forming a conceptual model, principal component analysis validated the factor structure of a collection of observed variables. Path analysis examined the theories. The hypothesized framework was confirmed, indicating a positive association between constructs. However, due to mining industry peculiarities, IC does not affect organizational performance (OP). This study supports the importance of utilizing people and their relevant skills to improve operational performance. The findings have implications for managers of coal mining enterprises, as they suggest that KM and OL are critical drivers of OP. Managers should focus on creating an environment that facilitates knowledge sharing and learning, as this will help improve their organizations’ performance.
Europium (Eu) doped Calcium borophosphate (CBP) phosphors were synthesized via the solid-state diffusion method. The prepared Europium (Eu) doped Calcium borophosphate (CBP) powder was heated up to 600 ℃ for 6 h for a complete diffusion of ions in the powder system. XRD results showed that the prepared phosphors exhibit a well-crystallized hexagonal phase. The complete diffusion inside the CBP/Eu powder system has been confirmed by the presence of elements such as P, O, Bi, Ca, C, Eu, and B. Apart from that, the synthesized powder system has shown a down-conversion property where the Eu3+-activated ion was excited at 251 nm. Under the excitation of 251 nm, CBP/Eu phosphor showed intense emissions peaking at 591,617, and 693 nm due to the 5D0 → 7F1, 5D0 → 7F2, and 5D0 → 7F4 transition of Eu3+ ions. The obtained results suggest that the CBP/Eu phosphors have the potential for spectral response coating materials to improve photovoltaic (PV) panel efficiency.
This article summarizes the mine safety situation of the Internet of Things, proposes a mine safety system scheme that combines a sense of unity with a sense of isolation, and a sense of mobility with a sense of fixation. It analyzes in detail the feasibility and scientificity of the mine safety system scheme, laying a good foundation for establishing a mine safety system.
the study deals with the issue of mining transport technology and its use in mines in Slovakia and Hungary at the end of the 19th and the beginning of the 20th century. It focuses on the analysis and comparison of the transport infrastructure used in these mines, either as original Slovak inventions or as products of foreign provenance. The research is based on the analysis of monographic and periodical press production from this period, where these technological achievements were presented and discussed. In addition, the study examines the media presentation of these products in the contemporary traditional periodical press. The findings of the study offer an important historical perspective on the development of mining transport technology and related industries in the region and contribute to the understanding of the media presentation and promotion of mining technology. This research is in line with the objectives of the “CultureMind” project, which focuses on the promotion and promotion of cultural heritage through media and education.
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