Metal organic framework is a class of hybrid network of supramolecular solid materials comprised of a large number of inorganic and organic linkers all bounded to metal ions in a well-organized fashion. This type of compounds possess a greater surface area with an advantage of changing pore sizes, diversified and beautiful structure which withdrew an intense interest in this field. In the present review articles, the structural aspects, classification, methods of synthesis, various factors affecting the synthesis and stability, properties and applications have been discussed. Recent advances in the field and new directions to explore the future scope and applications of MOFs have been incorporated in this article to provide current status of the field.
In recent years, nanoporous alloys have presented the advantages of a large specific surface area, low density, and simple operation, and they have been widely used in the fields of catalysis, magnetism, and medicine. Nanoporous Pt-Si alloy was prepared by melt-spun and chemical dealloying, and was characterized by X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscope, and transmission electron microscopy. Pt-Si alloys possess a three-dimensional bicontinuous structure and an average size of 5 nanometers. Compared with commercial Pt/C catalysts, nanoporous Pt-Si alloys exhibit excellent electrocatalytic activity and stability in ethanol-catalyzed oxidation reactions. It is taken into consideration to be a promising catalyst in direct ethanol fuel cells.
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