Excessive usage of chemicals in crops, especially in leafy vegetables, caused people exposed to health and environmental risks. In Iran, spinach used as a winter vegetable that believed has high Iron and is useful for anemia. The objective of the experiment was to determine the optimum use of each macronutrients to obtain safe maximum growth and yield for scaling up among farmers. Treatments were chemical fertilizers including ammonium sulfate, triple superphosphate and potassium sulfate at 50, 100, 150 and 200 kg/h against control in a randomized complete block design. Results showed that nitrogen caused elevation of fresh and dry weight in spinach as the maximum obtained in 200 kg/h ammonium sulfate. Results obtained from effect of phosphorus showed that super phosphate increased fresh and dry weight of spinach; but potassium sulfate had no effect on its growth and yield. Analysis of variance on cross effect of data showed significant differences in fresh and dry weight, number of leaves, chlorophyll content and nitrate, and non-significant differences in length and wide of leaves.

Nanoscale zero-valent iron (nZVI) is thought to be the most effective remediation material for contaminated soil, especially when it comes to heavy metal pollutants. In the current high-industrial and technologically advanced period, water pollution has emerged as one of the most significant causes for concern. In this instance, silica was coated with zero-valent iron nanoparticles at 650 and 800 ℃. Ferric iron with various counter-ions, nitrate (FN) and chloride (FC), and sodium borohydride as a reducing agent were used to create nanoscale zero-valent iron in an ethanol medium with nitrogen ambient conditions. X-ray diffraction (XRD) and field emission scanning electron microscopy (FE-SEM) techniques were employed to describe the structures of the generated zero-valent iron nanoparticles. Further, we investigated the electrical properties and adsorption characteristics of dyes such as alizarin red in an aqueous medium. As a result, zero-valent nano iron (nZVI), a core-shell environmental functional material, has found extensive application in environmental cleanup. The knowledge in this work will be useful for nZVI-related future research and real-world applications.