The present article reports the applications of Caputo-Fabrizio time-fractional derivatives. This article generalizes the idea of unsteady MHD free convective flow in a Walters.-B fluid with heat and mass transfer study over an exponential isothermal vertical plate embedded in a porous medium. The governing equations are converted into dimensionless form and extended to fractional model. The generalized Walters-B fluid model has been solved analytically using the Laplace transform technique. From the general solutions we reduce limiting solutions when to the similar motion for Newtonian fluid. The corresponding expressions for and Nusselt and Sherwood numbers are also assessed. Numerical results for velocity, temperature and concentration are demonstrated graphically for various factors of interest and discussed. As a result, we have plotted the influence of fractional parameter on fluid flow and drawn comparison between fractional Walters’-B and fractional Newtonian fluid and found that fractional Newtonian fluid is faster than fractional Walters’-B fluids.

Energy shortages and environmental damage have become serious problems facing the society today. Biomass can be a renewable energy source, which large-scale development and utilization are of great significance to industry and social life. Biomass pyrolysis technology can achieve effective utilization of biomass energy. It is necessary to optimize the pyrolysis reaction technology and device for realize the industrialization and large-scale production of biomass energy.

Quartz sand was used as bed material in a small fluidized bed reactor with 1 kg/h feed. Corn straw powder with particle size of 20–40 mesh, 40–60 mesh, 60–80 mesh and 80–120 mesh was used as raw material for rapid pyrolysis at reaction temperatures of 400 °C, 450 °C, 500 °C and 550 °C. The bio-oil obtained after liquefaction of pyrolysis gas was analyzed. The variation trend of bio-oil composition in pyrolysis of corn straw powder with different reaction temperatures and raw material sizes was compared. The results show that: (1) the content of 3-hydroxyl-2-phenyl-2-acrylic acid in bio-oil increases with the decrease of raw material particle size, but it is less at 450 °C; (2) with the increase of reaction temperature, the content of hydroxyacetaldehyde in bio-oil increases at first and then decreases: the content of hydroxyacetaldehyde in bio-oil is the highest at 500 °C when the particle size is 20–40 mesh, and the highest at 450 °C with the other three particle sizes. Compared with other particle sizes, raw material with the particle size of 60–80 mesh is not conducive to the formation of aldehyde compounds; (3) the reaction temperature of 500 °C and the particle size of 60–80 mesh of raw materials are more conducive to the formation of phenolic compounds in bio-oil; (4) the ester compounds with particle size of 20–40 mesh in bio-oil is 20% higher than that of other particle sizes; (5) the reaction temperature and the particle size of raw materials had no significant effect on the formation of ketones, alcohols and alkane compounds in bio-oils.

In recent years, nanoporous alloys have presented the advantages of a large specific surface area, low density, and simple operation, and they have been widely used in the fields of catalysis, magnetism, and medicine. Nanoporous Pt-Si alloy was prepared by melt-spun and chemical dealloying, and was characterized by X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscope, and transmission electron microscopy. Pt-Si alloys possess a three-dimensional bicontinuous structure and an average size of 5 nanometers. Compared with commercial Pt/C catalysts, nanoporous Pt-Si alloys exhibit excellent electrocatalytic activity and stability in ethanol-catalyzed oxidation reactions. It is taken into consideration to be a promising catalyst in direct ethanol fuel cells.

In order to maximize the potential energy utilization of agricultural and forestry waste and sludge, the experimental research on co-pyrolysis was carried out for two kinds of sludge (urban industrial sludge, paper sludge) and a typical biomass straw. The results show that adding biomass can effectively improve sludge pyrolysis characteristics; biomass straw and sludge, there are complex interactive effects between components in the co-pyrolysis process, and the characteristic parameters show nonlinear changes. When industrial sludge is mixed with straw, with the increase of straw content, the initial temperature of pyrolysis gradually decreases, the termination temperature increases, the peak of pyrolysis reaction rate and the corresponding temperature gradually increase, and the pyrolysis index gradually increases; when paper sludge is mixed with straw, with the increase of straw content, the initial temperature of pyrolysis gradually decreases, the termination temperature increases, the peak of pyrolysis reaction rate gradually increases, while the peak corresponding temperature gradually decreases, and the pyrolysis index gradually decreases. Combined with characteristic parameters and reaction kinetics analysis, it is suggested that the straw mixing proportion should be controlled at about 25% during the co-pyrolysis of industrial sludge and straw. During the co-pyrolysis of paper sludge and straw, it is suggested to control the straw blending ratio at about 75%.

Research into electro-conductive textiles based on conductive polymers like polypyrrole has increased in recent years due to their high potential applications in various fields. Conductive polymers behave like insulators in their neutral states, with typical electrical conductivity in the range 10^–10 to 10^–25 Scm^–1. These neutral polymers can be converted into semi-conductive or conductive states with conductivities ranging from 1 Scm^–1 to 10^–4 Scm^–1 through chemical or electro-chemical redox reactions. By applying these polymers to a textile surface, we can obtain novel composites that are strong, flexible, lightweight, and highly electroconductive. These textile composites are suitable for applications such as heating pads, sensors, corrosion-protecting materials, actuators, electrochromic devices, EMI shielding, etc. The methods of application of conductive polymers onto the textile surface, such as in-situ chemical, in-situ electrochemical, in-situ vapor phase, in-situ polymerization in a supercritical fluid, and solution coating processes, are described here briefly. The merits and demerits of these methods are mentioned here. The reaction mechanisms of chemical and electrochemical polymerization proposed by the different researchers are described. Different factors affecting the kinetics of chemical and electrochemical polymerization are accounted for. The influence of textile materials on the kinetics of chemical polymerization is reviewed and reported.