This report deals synthesis of CuInGa (CIG) nano materials along with doctor blade and spin coated thin films selenization and their physical properties. The doctor blade and spin coated CIGS/SLG thin films thicknesses are obtained ̴ 2 μm and ̴ 2.95 μm. Raman spectroscopy of these thin films leads the chalcopyrite phase formation by exhibiting the peak at wave number 171 cm-1. The well developed grain growths of spin coated thin film are appeared in the surface morphology. While the grain growths developments in doctoral blade coated thin film is rather hard and fuzzy. EDS measurement recognised the existence of the compositional ratio presence of the alloying elements Cu, In. Ga and Se. The doctor blade and spin coated CIGS/SLG thin films are exhibited the UV- Visible transmission peak in the wave length range 240 nm 320 nm. The optical energy band gaps for the doctor blade and spin coated CIGS thin films are obtained 1.41eV and 1.5 eV.
To increase inter-region connectivity, the Indonesian government initiated infrastructure projects such as toll roads, airport, highways, as well as agriculture ones throughout the countries. One of the big projects in road infrastructure was the Cikampek–Palimanan (Cipali) toll road in West Java with a budget of more than USD1 billion which started to operate in July 2015. This paper is aimed to evaluate the impact of the toll road on accessibilities, trades, and investments in the region it traverses. To carry out the analysis, we used qualitative approach, difference-in-difference approach, and ANOVA, utilizing three kinds of data. The first data is collected from a survey of 331 small-medium enterprises (SMEs) in the logistics and the hotel and restaurant industries. The second one is bank loan data sourced from Bank Indonesia, while the third one is investment data from Investment Coordinating Board of Indonesia (BKPM).
After two years of its operation, Cipali toll road has increased accessibility, mobility, trade, and investment in the region it traverses. The travel time was reduced by 39%, while the cargo volume of the local businesses increased by 30% to 40%. These led to an improvement of wholesale trade volume in almost all regencies. However, SMEs in the hotel and restaurant industry along the traditional northern coastal highway in Subang, Indramayu, and Brebes experienced a decline due to the traffic shifting. Meanwhile, investments from national companies especially those of labor-intensive manufacturing industries flowed significantly especially to Subang and Majalengka, which reflected a “sorting effect”. However, investments from local and foreign businesses did not increase significantly yet after 2.5 years of toll operation.
To reap the benefit from the presence of Cipali toll road, the local governments should improve the ease of doing business to attract investments that boost employment in return. In addition, given a better accessibility from Greater Jakarta and a large number of potential visitors passing through the toll road, local businesses in the trade sector would benefit if they could promote the local attractions such as in tourism activities supported by the local government. The latter strategy should also be implemented by the local governments and local businesses in the northern coastal traditional route to minimize the negative impact of the toll road due to the traffic shifting. This strategy should be strengthened through increasing connectivity from the toll exits to local business areas and through increasing the ease of doing business.
Salicylaldehyde imine transition metal catalyst is a kind of olefin polymerization catalyst that is widely used in the coordination of salicylaldehyde imine ligand and pre-transition metal. Salicylaldehyde imine ligands have the characteristic of easily inserting different substituents via organic synthesis. Therefore, the regulation of the polymerization activity, polymerization product, and product distribution can be achieved by changing the steric hindrance effect, the electronic effect, and the number of metal active sites near the catalytic active center. The development status of the transition metal catalyst of salicylaldehyde imide was summarized in this paper. The influence of the ligand structure of the salicylaldehyde imide transition metal catalyst on the catalytic performance, which involved the high selectivity of ethylene trimerization, ethylene/α-olefin, polar monomer copolymerization, ethylene polymerization production, ultra-high molecular weight polyethylene, and many other areas of olefin polymerization, was elaborated, providing references for further study and industrial applications of this catalyst.
In recent years, the foundry sector has been showing an increased interest in reclamation of used sands. Grain shape, sieve analysis, chemical and thermal characteristics must be uniform while molding the sand for better casting characteristics. The problem that tackled by every foundry industry is that of processing an adequate supply of sand which has the properties to meet many requirements imposed upon while molding and core making. Recently, fluidized bed combustors are becoming core of ‘clean wastes technology’ due to their efficient and clean burning of sand. For proven energy efficient sand reclamation processing, analysis of heating system in fluidized bed combustor (FBC) is required. The objective of current study is to design heating element and analysis of heating system by calculation of heat losses and thermal analysis offluidized bed combustorfor improving efficiency.
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