Tidal sea level variations in the Mediterranean basin, although altered and amplified by resonance phenomena in confined sub-basins (e.g., Adriatic Sea), are generally confined within 0.5 meters and exceptionally up to 1.5 meters. Here we explore the possibility of retrieving sea level measurements using data from GNSS antennas on duty for ground motion monitoring and analyze the spectral outcomes of such distinctive measurements. We estimate one year of GNSS data collected on the Mediterranean coasts in order to get reliable sea level data from all publicly available data and compare it with collocated tide gauges. A total of eleven stations were suitable for interferometric analysis (as of 2021), and all were able to supply centimeter-level sea level estimates. The spectra in the tidal frequency windows are remarkably similar to tide gauge data. We find that the O1 and M2 diurnal and semidiurnal tides and MK3, MS4 shallow sea water tides may be disturbed by aliasing effects.
Seawater desalination has been studied with interest due to the scarcity of fresh water for human consumption. Solar distillation is an old method; the productivity, energy consumption of the process and the cost of the desalinated water thus obtained depend on the efficiency achieved in each of the stages of these systems. The limited capacity to absorb solar radiation and transform it into useful heat for evaporation, interaction with the surrounding medium, and heat losses restrict the overall efficiency of the thermal process and productivity. Since the energy comes from solar radiation, the maximum productivity of this process will be constrained by the magnitude of the total solar radiation available in an area of the planet due to its geographic location, time of year and local climatic conditions. The processes of this energy will be thermodynamically limited by the heat transfer coefficients achieved in the equipment, the maximum value that the evaporation heat can reach, as long as the losses to the environment by convection and radiation are minimal. Comparative analyses of several proposed models, reported data of distillers, reported data of solar radiation that reach average values of up to 7.2–7.4 kwh/m2 in some regions of the planet are presented and estimates are made for productivity of these equipments that they reach between 6.7 and 6.9 kg/m2 day with a theoretical maximum efficiency of about 0.16 of the total solar radiation.
The importance of improving industrial transformation processes for more efficient ones is part of the current challenges. Specifically, the development of more efficient processes in the production of biofuels, where the reaction and separation processes can be intensified, is of great interest to reduce the energy consumption associated with the process. In the case of Biodiesel, the process is defined by a chemical reaction and by the components associated to the process, where the thermochemical study seeks to develop calculations for the subsequent understanding of the reaction and purification process. Thus, the analysis of the mixture of the components using the process simulator Aspen Plus V9® unravels the thermochemical study. The UNIFAC-DMD thermodynamic method was used to estimate the binary equilibrium parameters of the reagents using the simulator. The analyzed aspects present the behavior of the components in different temperature conditions, the azeotropic behavior and the determined thermochemical conditions.
Four alloys based on niobium and containing about 33wt.%Cr, 0.4wt.C and, in atomic content equivalent to the carbon one, Ta, Ti, Hf or Zr, were elaborated by classical foundry under inert atmosphere. Their as-cast microstructures were characterized by X-ray diffraction, electron microscopy, energy dispersion spectrometry and while their room temperature hardness was specified by Vickers indentation. The microstructures are in the four cases composed of a dendritic Nb-based solid solution and of an interdendritic NbCr2 Laves phase. Despite the MC-former behavior of Ta, Ti, Hf and Zr usually observed in nickel or cobalt-based alloys, none of the four alloys contain MC carbides. Carbon is essentially visible as graphite flakes. These alloys are brittle at room temperature and hard to machine. Indentation shows that the Vickers hardness is very high, close to 1000HV10kg. Indentation lead to crack propagation through the niobium phase and the Laves areas. Obviously no niobium-based alloys microstructurally similar to high performance MC-strengthened nickel-based and cobalt-based can be expected. However the high temperature mechanical and chemical properties of these alloys remain to be investigated.
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