In order to scientifically evaluate the germplasm resources of Momordica charantia in southern China, the diversity, correlation and cluster analysis were carried out on the main botanical characters of 56 Momordica charantia varieties, such as melon length, melon transverse diameter, single melon weight, internode length, stem diameter, leaf length and leaf width. The results showed that the variation coefficients of 7 agronomic characters of 56 Momordica charantia varieties ranged from 8.81% to 19.44%, the average variation coefficient was 14.21%, the maximum variation coefficient of single melon weight was 19.44%, and the minimum variation coefficient of melon cross diameter was 8.81%. The correlation analysis showed that there were correlations among the agronomic traits. The positive correlation coefficient between leaf length and leaf width was up to 0.978, and the negative correlation coefficient between single melon weight and internode length was up to 0.451. The 56 varieties were divided into 3 groups by cluster analysis, of which 92.86% of the materials were concentrated in the first and second groups, and there were only 4 materials in the third group. The results can provide a reference for the cultivation, utilization and genetic improvement of Momordica charantia resources in southern China.
Due to its physicochemical properties, nanoparticles titanium dioxide (nTiO2) is being put into mass production and widespread applications, which inevitably results in their increasing exposure to the water body. After it entering the water body, the chemical properties of nTiO2 can be influenced by ion compositions, ion strength and pH, which affects their ecological risk. Excess of ammonium (NH4+) fertilizer has contaminated soil and water environments. In this paper, the Zeta potentials and hydrodynamic radius of nTiO2 were studied in NH4+ solution compared to those in Na+ solution. In addition, the sedimentation rate of nTiO2 was also investigated. The experiment results show that high pH inhibits the sedimentation of nTiO2. Moreover, NH4+ increases the stability of nTiO2 more than Na+ at the same IS, which was attributed the more negative Zeta potentials and the smaller hydraulic radius. Our results provide a theoretical basis for evaluating the ecological risk of nTiO2 in aqueous solution containing NH4+.
Nanoporous nickel has been prepared by electrodeposition using non-ionic surfactant based liquid crystalline template under optimized processing conditions. Physicochemical properties of nanoporous nickel are systematically characterized through XRD, SEM and AFM analyses. Comparison of electrocatalytic activity of nanoporous nickel with smooth nickel was interrogated using cyclic voltammetry (CV), chronoamperometry (CA) and electrochemical impedance spectroscopy (EIS) analyses. Distinctly enhanced electrocatalytic activity with improved surface poisoning resistance related to nanoporous nickel electrode towards methanol oxidation stems from unique nanoporous morphology. This nanoporous morphology with high surface to volume ratio is highly beneficial to promote active catalytic centers to offer readily accessible Pt catalytic sites for MOR, through facilitating mass and electron transports.
Magnesium hydroxide/melamine phosphate borate (nano MH/MPB), a novel nano-composition intumescent flame retardant, was synthesized with the in-situ reaction method from MgCl2·6H2O sodium hydroxide (NaOH) and melamine phosphate borate (MPB) in the absence of H2O. The structure of the product was confirmed by EDAX IR and XRD. The effects of reaction temperature and time on the dimension of magnesium hydroxide were observed. The effects of mass ratio of magnesium hydroxide to MPB on the flame retardancy of nano-MH/MPB/EP were examined with the limiting oxygen test. The results show that the optimal condition of synthesis of MH/MPB is mMH/mMPB = 0.25, reacting under 75 ℃ for 30 minutes. Finally, the mechanism for flame retardancy of nano-MH/MPB/EP was pilot studied by means of IR of char layer and TG of MH/MPB.
Magnetic graphene oxide nanocomposites (M-GO) were successfully synthesized by partial reduction co-precipitation method and used for removal of Sr(II) and Cs(I) ions from aqueous solutions. The structures and properties of the M-GO was investigated by X-ray diffraction, Fourier transformed infrared spectroscopy, X-ray photoelectron spectroscopy, transmission electron microscopy, scanning electron microscopy, vibrating sample magnetometer (VSM) and N2-BET measurements. It is found that M-GO has 2.103 mg/g and 142.070 mg/g adsorption capacities for Sr(II) and Cs(I) ions, respectively. The adsorption isotherm matches well with the Freundlich for Sr(II) and Dubinin–Radushkevich model for Cs(I) and kinetic analysis suggests that the adsorption process is pseudo-second-ordered.
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