Zero-valent iron is a moderately reducing reagent that is both non-toxic and affordable. In the present work, iron nanoparticles were synthesized using bitter guard leaf extract (Momordica charantia L.) (BGL-Fe NP). Using leaf samples from bitter protectant extract, iron nanoparticles were synthesized with secondary metabolites such as flavonoids and polyphenols acting as capping and reducing agents. Polyphenols reduce Fe2+/Fe3+ to nanovalent iron or iron nanoparticles. Iron nanoparticles were synthesized by reducing iron chloride as a precursor with bitter protective leaf extract in an alkaline environment. The obtained BGL-Fe NPs were calcined for 4 h at various temperatures of 400 °C, 500 °C, and 600 °C. The obtained samples were coded as BGL-Fe NPs-4, BGL-Fe NPs-5, and BGL-Fe NPs-6, respectively. The synthesized BGL-Fe NPs were systematically characterized by XRD, SEM, FTIR, UV-Vis and TG-DTA analysis. The obtained BGL-Fe NPs were then used as an adsorbent to remove the aqueous solution of basic methylene blue (MB) dye. MB concentration was monitored using UV-Vis spectroscopy.
Objective: To evaluate the radiographic characteristics of dentigerous cysts (DC) diagnosed at the School of Stomatology of the Universidad Peruana Cayetano Heredia (UPCH) during the period of 2010–2017. Material and methods: Retrospective, descriptive, observational and cross-sectional study, where the panoramic radiographs of 37 cases of DC were selected. Results: The total number of diagnosed cases of dentigerous cysts was 233, which after inclusion and exclusion criteria, 37 cases were obtained, of which 45.9% of cysts were found in the second decade of life with a higher frequency of 51.4 percent for women, and a jaw predilection of 59.5% in all cases. In addition, it was found that 97.3% of the cases were radiolucent, defined limits were found in 67.6%, corticalized edges in 54.1% and unilocular in 94.6%. All dentigerous cysts were associated with a tooth, of which closed apex (48.6%) and tooth displacement (59.5%) were observed. The adjacent tooth was not affected in 56.8% of cases, but its hard lamina was affected (59.5%). The 68.2% of cases did not affect the basal mandibular cortex, but did displace the inferior dental canal (54.5%) and 46.7% of cases displaced the floor of the maxillary sinus. Conclusions: Most of the results obtained on the characteristics in the Peruvian population support previous studies reported in America, Europe and Asia. Radiographically the dentigerous cyst showed characteristics that support its clearly benign behavior.
Magnetic graphene oxide nanocomposites (M-GO) were successfully synthesized by partial reduction co-precipitation method and used for removal of Sr(II) and Cs(I) ions from aqueous solutions. The structures and properties of the M-GO was investigated by X-ray diffraction, Fourier transformed infrared spectroscopy, X-ray photoelectron spectroscopy, transmission electron microscopy, scanning electron microscopy, vibrating sample magnetometer (VSM) and N2-BET measurements. It is found that M-GO has 2.103 mg/g and 142.070 mg/g adsorption capacities for Sr(II) and Cs(I) ions, respectively. The adsorption isotherm matches well with the Freundlich for Sr(II) and Dubinin–Radushkevich model for Cs(I) and kinetic analysis suggests that the adsorption process is pseudo-second-ordered.
A large number of people of the fringe areas of Sundarban enter into the forests every year and encounter with the tigers simply for their livelihood. This study attempts to examine the extent and impact of human-animal conflicts in the Sundarban Reserve Forest (SRF) area in West Bengal, India. An intensive study of the data of the victims (both death and injury) between 1999 and 2014 reveals that, fishermen crab collector, honey collectors and woodcutters are generally victimized by the tiger attack. Pre monsoon period (April to June) and early winter period (Jan to March) are noted for the two-peak periods for casualties. Maximum casualty occurs between 8-10 am, and 2-4 pm. Jhilla (21.1%), Pirkhali (19.72 %), Chandkhali (11.72%), and Arbesi (9.35%) are the four most vulnerable forest blocks accounting more than 60 per cent occurrence of incidences. 67.24 per cent of the tiger attack victims were residents of Gosaba followed by Hingalganja (15%) and Basanti, (9.76%). The vulnerability rating puts the risk of tiger attack to 0.88 for every 10,000 residents of Gosaba block followed by 0.33 at Hingalganj Block and 0.11 at Bansanti Block. The majority of the victims (68%) were found to be males, aged between 30 and 50 years.
The cultivation of sugar beet (Beta vulgaris L.) for table or horticultural purposes is largely carried out in the conventional way which is characterized by intense mechanization causing soil degradation and high labor costs. New cultivation techniques are being employed in the production of vegetables aiming to ensure improvements in environmental and economic conditions, such as the no-till farming system. Thus, the objective of this work was to evaluate the vegetable classification and physicochemical characteristics of beets from different corn planting densities. The experiment was conducted in the period from October 2018 to June 2019 in the municipality of Nova Laranjeiras (PR). Corn was used as a cover plant and the vegetable used was beet cultivar Early Wonder Tall Top. The experimental design used was in interspersed blocks in unifactorial scheme (corn densities 40, 60, 80, 100 thousand plants/ha and control) with four blocks, with plots 3.60 m long and 1.20 m wide. The parameters evaluated 60 days after planting were: commercial classification (class, group, subgroup, category), length, diameter, mass, pulp firmness, soluble solids, titratable acidity, pH and ratio, phenolic compounds. Of which the variables that were not significant at 0.5 probability were length, category (defects), firmness, subgroup (flesh color), soluble solids and phenolic compounds. It is concluded that high densities of corn as mulch for SPDH of sugar beet crop negatively affect the grade and physicochemical characterization of the products.
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