Polymers obtained from renewable sources are gaining popularity over their petroleum based counter parts in recent years due to their capability to address the environmental pollution related concerns emanating from the widespread usage of synthetic polymers. Even though the polymers from renewable sources are attractive in an environmental point of view, some of the property limitations and the high cost of these materials pose limitations for their extensive commercial applications. These aspects opened the door for a large chunk of research activities in development of polyblends and composites containing polymers from renewable sources as one of the components. Poly (lactic acid) (PLA) is one of the most discussed and commercialized polymer originated from renewable resources. Even though it has many useful properties, certain disadvantages like high brittleness, low impact resistance etc. limit the wide spread commercialization of PLA. In this review article, the recent research activities which are aimed to fill this gap by various modifications of PLA are discussed with special emphasis on the latest research advancements in the field of biodegradable and non biodegradable systems containing PLA.
Regarding to the influence of chloride and fluoride ions on the corrosion resistance, the electrochemical behavior of Ti alloys has been deeply studied. In this work, the main goal was to investigate the electrochemical behavior of cp-Ti and Ti-Mo alloys containing 6, 10 and 15 wt% of Mo concentrations. All the samples were immersed in different solutions, such as 0.15 mol L-1 Na2SO4, 0.15 mol L-1 Ringer, 0.15 mol L-1 Ringer plus 0.036 mol L-1 NaF and 0.036 mol L-1 NaF. Simulating the commercial fluorinated gels, the NaF solutions naturally-aerated were prepared with 1450 ppm of fluoride ions. The electrochemical techniques applied in this work were the open-circuit potential, cyclic voltammetry, besides the technique for chemical identification, which was X-ray photoelectron spectroscopy. The formation and growth of TiO2 and MoO2 were identified, without pitting corrosion. The electrochemical stability and the corrosion resistance of the Ti-Mo alloys decreased in the solutions containing chloride and fluoride ions, with an appreciative decrease especially in the fluorinated medium. The Ti-Mo alloy with higher Mo content concentration was the material with higher corrosion resistance. Therefore, it is a promising candidate as a biomaterial, once the osseointegration needs a satisfactory corrosion resistance for being achieved.
Helical deep hole drilling is a process frequently used in industrial applications to produce bores with a large length to diameter ratio. For better cooling and lubrication, the deep drilling oil is fed directly into the bore hole via two internal cooling channels. Due to the inaccessibility of the cutting area, experimental investigations that provide information on the actual machining and cooling behavior are difficult to carry out. In this paper, the distribution of the deep drilling oil is investigated both experimentally and simulatively and the results are evaluated. For the Computational Fluid Dynamics (CFD) simulation, two different turbulence models, i.e. the RANS k-ω-SST and hybrid SAS-SST model, are used and compared. Thereby, the actual used deep drilling oil is modelled instead of using fluid dynamic parameters of water, as is often the case. With the hybrid SAS-SST model, the flow could be analyzed much better than with the RANS k-ω-SST model and thus the processes that take place during helical deep drilling could be simulated with realistic details. Both the experimental and the simulative results show that the deep drilling oil movement is almost exclusively generated by the tool rotation. At the tool’s cutting edges and in the flute, the flow velocity drops to zero for the most part, so that no efficient cooling and lubrication could take place there. In addition, cavitation bubbles form and implode, concluding in the assumption that the process heat is not adequately dissipated and the removal of chips is adversely affected, which in turn can affect the service life of the tool and the bore quality. The carried out investigations show that the application of CFD simulation is an important research instrument in machining technology and that there is still great potential in the area of tool and process optimization.
Entomopathogens are microorganisms that pathogenic to insect pest. Several species of naturally occurring viz; fungi, bacteria, viruses and nematodes, infect a variety of insect pests and play an important role in agricultural crops controlling insect pest management. This kind of biopesticide has many advantages and alternative to chemical insecticides, highly specific, safe, and environmentally sustainable. Pest problems are an almost inevitable part of agriculture. They occur largely because agricultural systems are simplified and modifications of natural ecosystems. Viruses, bacteria are host specific and fungi generally have broader host range and can infect both underground and aboveground pests, soil-dwelling nature nematodes are more suitable for managing soil pests. Growing crops in monoculture provides concentrated food resource that allows pest populations to achieve higher densities in natural environments. Some of the most important problems occur when pests develop resistance to chemical pesticides. These cause highly significant damage to crops, there are also threats from emerging new strains of pests. Crops cultivation can make the physico-chemical environment more favourable for pest activity. Agricultural pests are reducing the yield and quality of produce by feeding on crops, transmitting diseases. Agricultural production significantly loss crop yields, suggest that improvements in pest management are significant forward for improving yields. Crop growers are under immense pressure to reduce the use of chemical pesticides without sacrificing yields, but at the same time manage of pests is becoming difficult due to pesticide resistance and the decreasing availability of products. Alternative methods are needed urgently. These need to be used as part of Integrated Pest Management safety and environmental impact.
Eucalyptus is an important source of cellulose and a widely cultivated plant. Biotechnology tools can save time spent in breeding and transcriptomic approaches generate a gene profile that allows the identification of candidates involved in processes of interest. RNA-seq is a commonly used technology for transcript analysis and it provides an overview of regulatory pathways. Here, we selected two contrasting Eucalyptus species for cold acclimatization and focused in responsive genes under cold condition aiming woody properties – lignin and cellulose. The number of differentially expressed genes identified in stem sections were 3.300 in Eucalyptus globulus and 1370 in Eucalyptus urograndis. We listed genes with expression higher than 10 times including NAC, MYB and DUF family members. The GO analysis indicates increased oxidative process for E. urograndis. This data can provide information for more detailed analyses for breeding, especially in perennial plants.
Afforestation is a main tool for preventing desertification and soil erosion in arid and semiarid regions of Iran. Large-scale afforestation, however, has poorly understood consequences for the future ecosystems in the term of ecosystems protection. The objective of the present study is to identify changes in soil properties following different intervals of planting of Ailanthus altissima (tree of heaven) in semiarid afforestation of Iran (Chitgar Forest Park, Tehran). For this purpose, sand, silt and clay ratios, bulk density, soil moisture, pH, electrical conductivity, phosphorus, potassium, magnesium, calcium, sodium, total soil N, and total carbon was measured. Our study highlighted the potential of the invasive trees by A. altissima, to alter soil properties along chronosequence. Almost all soil quality attributes showed a declining trend with stand age. A continuous decline in soil quality indicated that the present land management may not be sustainable. Therefore, an improved management practice is imperative to sustain soil quality and maintain long-term productivity of plantation forests. Thinning activity will be required to reduce the number of trees competing for the same nutrients especially in a older stand to protect forest soils.
Copyright © by EnPress Publisher. All rights reserved.