The effect of foliar treatment with brassinosteroid (BR) on gender distribution in flowers of walnut (Juglans regia L. cv. Chandler) was investigated. Grafted walnut saplings (‘Chandler’) on the wild walnut (Juglans regia L.) rootstock were planted into 70-liter pots with a soil: peat: perlite medium and grown in pots between 2016–2020. BRs (24-epibrassinolide; EBR and 22(S), 23(S)-homobrassinolide; HBR) were applied at a concentration of 1 mg L^–1 for four consecutive years at the time of flower differentiation. The experimental design was completely randomized with three replicates. The results show that BR applications could alter the sexual distribution of the walnut’s flower. BRs application significantly increased the number of total flowers and female flowers per tree. The number of female flowers was also increased by the season. The highest number of female flowers (20.9) was observed in the trees in 2020 and the application of 1 mg L^–1 of HBR. It was determined that the annual growth of the plant and the increase in the number of females and total flowers were positively related. The effect of BRs indicated that the response was BR-type specific.

In most studies on hydroclimatic variability and trend, the notion of change point detection analysis of time series data has not been considered. Understanding the system is crucial for managing water resources sustainably in the future since it denotes a change in the status quo. If this happened, it is difficult to distinguish the time series data’s rising or falling tendencies in various areas when we look at the trend analysis alone. This study’s primary goal was to describe, quantify, and confirm the homogeneity and change point detection of hydroclimatic variables, including mean annual, seasonal, and monthly rainfall, air temperature, and streamflow. The method was employed using the four-homogeneity test, i.e., Pettitt’s test, Buishand’s test, standard normal homogeneity test, and von Neumann ratio test at 5% significance level. In order to choose the homogenous stations, the test outputs were divided into three categories: “useful”, “doubtful”, and “suspect”. The results showed that most of the stations for annual rainfall and air temperature were homogenous. It is found that 68.8% and 56.2% of the air temperature and rainfall stations respectively, were classified as useful. Whereas, the streamflow stations were classified 100% as useful. Overall, the change point detection analyses timings were found at monthly, seasonal, and annual time scales. In the rainfall time series, no annual change points were detected. In the air temperature time series except at Edagahamus station, all stations experienced an increasing change point while the streamflow time series experienced a decreasing change point except at Agulai and Genfel hydro stations. While alterations in streamflow time series without a noticeable change in rainfall time series recommend the change is caused by variables besides rainfall. Most probably the observed abrupt alterations in streamflow could result from alterations in catchment characteristics like the subbasin’s land use and cover. These research findings offered important details on the homogeneity and change point detection of the research area’s air temperature, rainfall, and streamflow necessary for the planers, decision-makers, hydrologists, and engineers for a better water allocation strategy, impact assessment and trend analyses.

Facing the digital economy era, considerable attention is paid to the importance of understanding the fundamental impact on the information and development of blended teaching methods regarding the higher education. For this reason, the purpose of this study is to answer the challenges brought by the digital economy era, identify the effective teaching methods which would be used in English Correspondence course in the era of digital economy, aiming to form the patterns of learning, provide high motivation, strength and knowledge, and most importantly contribute to the complex competences of future working. For further research, it is expected to be able to prove that using the blended teaching methods will effectively improve students’ communication skills and learning efficiency, enhance students’ learning experience and critical thinking skills.

This study uses dynamic capability theory and a resource-based view to examine whether intellectual capital (human, relational, and structural capital) mediates entrepreneurial leadership and innovation success. Drawing on data from 422 senior-level employees working in Peruvian I.T. companies, the proposed relationships were analyzed using SmartPLS 4. Entrepreneurial leadership was found to foster employees’ innovative performance through the mediating role of human capital, relational capital, and structural capital. Practically, businesses often rely on innovation for survival and growth, so they should consider entrepreneurial leadership to create intellectual capital (human capital, relational capital and structural capital) for innovation performance. Businesses should provide entrepreneurial training that emphasizes role modeling intellectual capital and encourages employees to recognize and pursue entrepreneurial opportunities. With significantly limited research, the study contributes by investigating the interrelationship of entrepreneurial leadership, intellectual capital, and innovation performance. The study contributes to the Resource Based View and Dynamic Capability Theory by demonstrating how entrepreneurial leadership contributes to innovation performance through human capital, relational capital, and structural capital.

In this paper, we deal with one of the most urgent and relevant topics nowadays, i.e., water pollution. The problem is finding a valid candidate for the absorption and removal of different kinds of pollutants commonly found in water. There are already some indications about graphene oxide as a potential candidate. In the present work, we take a step forward to show how graphene nanoplatelets (rather than the oxide form of this material) are capable of decontaminating water. In this starting step, we use a specific substance as a model pollutant, i.e., acetonitrile, leaving for the future steps, to extend the analysis to additional types of pollutants. In addition to laboratory-produced graphene nanoplatelets, we already examined in the past; now we wish to consider also commercially available ones, so that the new results will not be bound to a laboratory (low technology readiness level) material, but will become interesting also from the industrial point of view, thanks to the scalability of the nanoplatelets production. For this aim, we compare the performance of two types of filters based on two classes of nanomaterials, i.e., those produced by microwave and ultrasound assisted exfoliation, already analyzed in our earlier works, with those commercially distributed by an Italian company, i.e., NANESA, http://www.nanesa.com/. The latter is an innovative SME involved in the production of graphene-based nanomaterials. We focus here in the graphene nanoplatelets, commercially available in industrial batches (GXNan grades). The present study leads to determine which filtering membrane, among the various types of commercial graphene considered, shows the greatest stability, and the lack of breakage of the membrane, concentrating on such accessory features, given that all types of graphene showed excellent adsorption properties.