Synthesis of macro-mesoporous Titania (Titanium dioxide-TiO₂) nanospheres was successfully achieved using a modified template-free methodology to incorporate macroporous channels into a mesoporous TiO₂ framework to form mixed macro-mesoporous TiO₂ spheres (MMPT), which were doped with carbon dots (C-dots) to form improved nanocomposites (C-dots@MMPT). Elemental composition, surface bonding and optical properties of these nanocomposites were characterized by X-ray diffraction (XRD), Fourier transforms infrared spectroscopy (FTIR) and ultraviolet-visible absorption spectroscopy (UV-VIS). Evaluation of photocatalytic activity for each (C-Dots@MMPT) sample was performed via degrading the Methylene Blue (MB) dye compared with bare samples (MMPT) under visible light irradiation using 300 Watt halogen lamp.

The effects of different storage temperatures (2, 4 and 8 ℃) and their corresponding optimal heat treatment conditions on the quality, physiological and biochemical indexes of Cucumber Fruits during storage were studied by using the quadratic regression orthogonal rotation combination design. The effects of different storage temperatures (2, 4 and 8 ℃) and their corresponding optimal heat treatment conditions on the chilling injury, hardness, weightlessness rate, polyphenol oxidase (PPO), catalase (CAT), peroxidase (POD), H₂O₂, super oxygen anion free radical (O^2-), ASA and GSH were determined. The results showed that heat treatment could inhibit chilling injury, while heat treatment combined with 4 ℃ low temperature storage could effectively inhibit the decline of fruit hardness and weight loss rate, delay the increase of peroxidase (POD) and polyphenol oxidase (PPO) activities, inhibit the increase of H₂O₂ and superoxide anion free radical O^2- and significantly inhibit the browning of cucumber, delay the decline of ascorbic acid and maintain the content of GSH, it was beneficial to adjust the balance of active oxygen system. The results showed that under the storage condition of 4 ℃, the hot water treatment condition of cucumber was 39.4 ℃ and 24.3 min, which could delay the senescence of cucumber fruit and better maintain the quality of cucumber fruit.

This paper assesses South Africa’s massive infrastructure drive to revive growth and increase employment. After years of stagnant growth, this is now facing a deep economic crisis, exacerbated by the COVID-19 pandemic. This drive also comes after years of weak infrastructure investment, widening the infrastructure deficit. The plan outlines a R1 trillion investment drive, primarily from the private sector through the Infrastructure Fund over the next 10 years (Government of South Africa, 2020). This paper argues that while infrastructure development in South Africa is much-needed, the emphasis on de-risking for private sector buy-in overshadows the key role the state must play in leading on structurally transforming the economy.

In most studies on hydroclimatic variability and trend, the notion of change point detection analysis of time series data has not been considered. Understanding the system is crucial for managing water resources sustainably in the future since it denotes a change in the status quo. If this happened, it is difficult to distinguish the time series data’s rising or falling tendencies in various areas when we look at the trend analysis alone. This study’s primary goal was to describe, quantify, and confirm the homogeneity and change point detection of hydroclimatic variables, including mean annual, seasonal, and monthly rainfall, air temperature, and streamflow. The method was employed using the four-homogeneity test, i.e., Pettitt’s test, Buishand’s test, standard normal homogeneity test, and von Neumann ratio test at 5% significance level. In order to choose the homogenous stations, the test outputs were divided into three categories: “useful”, “doubtful”, and “suspect”. The results showed that most of the stations for annual rainfall and air temperature were homogenous. It is found that 68.8% and 56.2% of the air temperature and rainfall stations respectively, were classified as useful. Whereas, the streamflow stations were classified 100% as useful. Overall, the change point detection analyses timings were found at monthly, seasonal, and annual time scales. In the rainfall time series, no annual change points were detected. In the air temperature time series except at Edagahamus station, all stations experienced an increasing change point while the streamflow time series experienced a decreasing change point except at Agulai and Genfel hydro stations. While alterations in streamflow time series without a noticeable change in rainfall time series recommend the change is caused by variables besides rainfall. Most probably the observed abrupt alterations in streamflow could result from alterations in catchment characteristics like the subbasin’s land use and cover. These research findings offered important details on the homogeneity and change point detection of the research area’s air temperature, rainfall, and streamflow necessary for the planers, decision-makers, hydrologists, and engineers for a better water allocation strategy, impact assessment and trend analyses.

The objective of this study is to examine the extent of awareness, intention, and behavior among university students in relation to green marketing. It is recognized that the present cohort of students, as well as future generations, will have a substantial impact on shaping the course of the world. The respondents for this study consisted of university students, and the collected data was subsequently analyzed using SPSS (Statistical Package for Social Sciences) 25 in order to test the stated hypothesis. University students exhibit a comprehensive understanding of green marketing and a conscious inclination toward embracing favorable intentions and behaviors in relation to this domain. The results of this study suggest that there exists a statistically significant and positive correlation between individuals’ level of green awareness and their intention to participate in environmentally friendly consumer practices. Furthermore, it has been observed that the intention of consumers to engage in green practices has a noteworthy influence on their subsequent behavior in terms of adopting environmentally friendly behaviors. The findings obtained from studies on green marketing are of utmost importance in offering valuable guidance and orientation toward a future characterized by heightened environmental awareness and sustainability. The novelty of this study is to provide a lucid comprehension of students’ perceptions about green marketing. Several factors can potentially impact the intention and behavior of environmentally conscious consumers, including personal values, social norms, and economic factors. Additional research is necessary in order to obtain a more thorough comprehension of the complexity of these variables, and how they interact to impact consumer behavior.