Objective: to achieve accurately and rapidly the mapping of agricultural land use and crop distribution at the township scale. Methods: this study, based on specific methods, such as, time-series remote sensing index threshold classification and maximum likelihood, classifies each land use type and extracts crop spatial information, under the guidance of Sentinel-2A remote sensing images, to carry out agricultural land use mapping at township scale. And the mapping concerned will be verified by comparing with an agricultural spatial information map of a 0.5 m resolution, which is based on WorldVieW-2 fused images. Results: (1) the area accuracy of grain and oil crop land, vegetable land, agricultural facilities land and garden land is fairly good, with 92.93%, 98.98%, 95.71% and 95.14% respectively, and within 8% variation from actual area; (2) the spatial information of plot boundary, farmland road network, and canal network produced by OSM road data and historical high-resolution images was overlayed with the classification results of Sentinel-2A multi-spectral image for mapping, which can improve the accuracy of plot boundary information of classification results for the image with 10 m resolution. Conclusions: the use of multi-source information fusion method, agricultural land use and crop distribution space big data produced by Sentinel-2A optical image, can effectively improve the accuracy and timeliness of land use mapping at the township scale, to provide technical reference for the application of remote sensing big data to carry out agricultural landscape analysis at the township scale, optimization and adjustment of agricultural structure, etc.

The structure, thermodynamic stability, ionization potential (IP) and electron affinity (EA) energy level difference (E_g) and tension of lowest unoccupied orbit (LUMO) and highest occupied orbit (HOMO) of armchair single wall carbon nanotubes (C-NTs), BN hybrid carbon nanotubes (BC₂N-NTs) and all BN nanotubes (BN-NTs) were systematically studied with AM1 method in this paper. Calculation results show that when n value is constant, (n, n) C-NTs (n = 3,4,5,6) has the largest diameter and BN-NTs has the smallest diameter; (n, n) the values of E_g (HOMO-LUMO) and n of C-NTs and BC₂N-NTs are related; POAV analysis shows that different hybrid atoms have different contributions to the hybrid mode of nanotube atoms and the tension of nanotubes.

This paper contributes to a long-standing debate in development practice: under what conditions can externally established participatory groups engage in the collective management of services beyond the life of a project? Using 10 years of panel data on water point functionality from Indonesia’s rural water program, the Program for Community-Based Water Supply and Sanitation, the paper explored the determinants of subnational variation in infrastructure sustainability. It then investigated positive and negative deviance cases to answer why some communities successfully engaged in system management despite being located in difficult conditions as per quantitative findings and vice versa. The findings show that differences in the implementation of community participation, driven by local social relations between frontline service providers, that is, village authorities and water user groups, explain sustainable management. This initial condition of state-society relations influences how the project is initiated, kicking off negative or positive reinforcing pathways, leading to community collective action or exit. The paper concludes that the relationships between frontline government representatives and community actors are important and are an underexamined aspect of the ability of external projects to generate successful community-led management of public goods.

Due to its physicochemical properties, nanoparticles titanium dioxide (nTiO₂) is being put into mass production and widespread applications, which inevitably results in their increasing exposure to the water body. After it entering the water body, the chemical properties of nTiO₂ can be influenced by ion compositions, ion strength and pH, which affects their ecological risk. Excess of ammonium (NH₄⁺) fertilizer has contaminated soil and water environments. In this paper, the Zeta potentials and hydrodynamic radius of nTiO₂ were studied in NH₄⁺ solution compared to those in Na⁺ solution. In addition, the sedimentation rate of nTiO₂ was also investigated. The experiment results show that high pH inhibits the sedimentation of nTiO₂. Moreover, NH₄⁺ increases the stability of nTiO₂ more than Na⁺ at the same IS, which was attributed the more negative Zeta potentials and the smaller hydraulic radius. Our results provide a theoretical basis for evaluating the ecological risk of nTiO₂ in aqueous solution containing NH₄⁺.

Ce⁴⁺-doped nanometer ZnO powder was synthesized by so-l gel method. The microstructures and properties of the samples were characterized through XRD, UV-Vis and FTIR. The results indicated that the Ce⁴⁺ was successfully incorporated into ZnO, and the diameter of the nanometer was about 10.7nm. It induced the redshifting in the UV-Vis spectra. The photocatalytic activity of the samples was investigated using methylene blue (MB) as the model reaction under irradiation with ultraviolet light. The results showed that the doping of Ce⁴⁺ could increase the photocatalytic activities of ZnO nanopowders and that the best molar ratio of Ce⁴⁺ was n(Ce)/n(Zn) = 0.05, that the surfactant was sodium dodecyl sulfate, and that the nanometer ZnO was calcinated at 550 ℃ for 3 hours. Meanwhile, it inspected the effect of photocatalytic efficiency through the pH of MB, the amount of catalyst, and illumination time. The experimental results revealed that the initial mass concentration of MB was 10 mg/L, that the pH value was 7-8, that the dosage of Ce⁴⁺/ZnO photo-catalyst was 5 g/L, that the UV-irradiation time was 2 h, and that the removal rate of MB reached above 85%. Under the optimized conditions, the degradation rate of real dye wastewater was up to 87.67% and the removal efficiency of COD was 63.5%.