The tunable conduction of coumarin-based composites has attracted considerable attention in a wide range of applications due to their unique chemical structures and fascinating properties. The incorporation of graphene oxide (GO) further enhances coumarin properties, including strong fluorescence, reversible photodimerization, and good thermal stability, expanding their potential use in advanced technological applications. This review describes the developmental evolution from GO, GO-polymer, and coumarin-based polymer to the coumarin-GO composite, concerning their synthesis, characterization, unique properties, and wide applications. We especially highlight the outstanding progress in the synthesis and structural characteristics along with their physical and chemical properties. Therefore, understanding their structure-property relations is very important to acquire scientific and technological information for developing the advanced materials with interesting performance in optoelectronic and energy applications as well as in the biomedical field. Given the expertise of influenced factors (e.g., dispersion quality, functionalization, and loading level) on the overall extent of enhancement, future research directions include optimizing coumarin-GO composites by varying the nanofiller types and coumarin compositions, which could significantly promote the development of next-generation polymer composites for specific applications.
Land use changes have been demonstrated to exert a significant influence on urban planning and sustainable development, particularly in regions undergoing rapid urbanization. Tehran Province, as the political and economic capital of Iran, has undergone substantial growth in recent decades. The present study employs sophisticated Geographic Information System (GIS) instruments and the Google Earth Engine (GEE) platform to comprehensively track and analyze land use change over the past two decades. A comprehensive analysis of Landsat images of the Tehran metropolitan area from 2003 to 2023 has yielded significant insights into the patterns of land use change. The methodology encompasses the utilization of GIS, GEE, and TerrSet techniques for image classification, accuracy assessment, and change detection. The Kappa coefficients for the maps obtained for 2016 and 2023 were 0.82 and 0.87 for four classes: built-up, vegetation cover, barren land, and water bodies. The findings suggest that, over the past two decades, Tehran Province has undergone a substantial decline in ecological and vegetative areas, amounting to 2.4% (458.3 km2). Concurrently, the urban area and the barren lands have expanded by 287.5 and 125.5 km2, respectively. The increase in water bodies during this period is likely attributable to the reduction of vegetation cover and dam construction in the region. The present study demonstrates that remote sensing and GIS are excellent tools for monitoring environmental and sustainable urban development in areas experiencing rapid urbanization and land use changes.
Quantum dot can be seen as an amazing nanotechnological discovery, including inorganic semiconducting nanodots as well as carbon nanodots, like graphene quantum dots. Unlike pristine graphene nanosheet having two dimensional nanostructure, graphene quantum dot is a zero dimensional nanoentity having superior aspect ratio, surface properties, edge effects, and quantum confinement characters. To enhance valuable physical properties and potential prospects of graphene quantum dots, various high-performance nanocomposite nanostructures have been developed using polymeric matrices. In this concern, noteworthy combinations of graphene quantum dots have been reported for a number of thermoplastic polymers, like polystyrene, polyurethane, poly(vinylidene fluoride), poly(methyl methacrylate), poly(vinyl alcohol), and so on. Due to nanostructural compatibility, dispersal, and interfacial aspects, thermoplastics/graphene quantum dot nanocomposites depicted unique microstructure and technically reliable electrical/thermal conductivity, mechanical/heat strength, and countless other physical properties. Precisely speaking, thermoplastic polymer/graphene quantum dot nanocomposites have been reported in the literature for momentous applications in electromagnetic interference shielding, memory devices, florescent diodes, solar cells photocatalysts for environmental remediation, florescent sensors, antibacterial, and bioimaging. To the point, this review article offers an all inclusive and valuable literature compilation of thermoplastic polymer/graphene quantum dot nanocomposites (including design, property, and applied aspects) for field scientists/researchers to carry out future investigations on further novel designs and valued property-performance attributes.
Photovoltaic systems have shown significant attention in energy systems due to the recent machine learning approach to addressing photovoltaic technical failures and energy crises. A precise power production analysis is utilized for failure identification and detection. Therefore, detecting faults in photovoltaic systems produces a considerable challenge, as it needs to determine the fault type and location rapidly and economically while ensuring continuous system operation. Thus, applying an effective fault detection system becomes necessary to moderate damages caused by faulty photovoltaic devices and protect the system against possible losses. The contribution of this study is in two folds: firstly, the paper presents several categories of photovoltaic systems faults in literature, including line-to-line, degradation, partial shading effect, open/close circuits and bypass diode faults and explores fault discovery approaches with specific importance on detecting intricate faults earlier unexplored to address this issue; secondly, VOSviewer software is presented to assess and review the utilization of machine learning within the solar photovoltaic system sector. To achieve the aims, 2258 articles retrieved from Scopus, Google Scholar, and ScienceDirect were examined across different machine learning and energy-related keywords from 1990 to the most recent research papers on 14 January 2025. The results emphasise the efficiency of the established methods in attaining fault detection with a high accuracy of over 98%. It is also observed that considering their effortlessness and performance accuracy, artificial neural networks are the most promising technique in finding a central photovoltaic system fault detection. In this regard, an extensive application of machine learning to solar photovoltaic systems could thus clinch a quicker route through sustainable energy production.
Cysteine is one of the body’s essential amino acids to build proteins. For the early diagnosis of a number of diseases and biological issues, L-cysteine (L-Cys) is essential. Our study presents an electrochemical sensor that detects L-cysteine by immobilizing the horseradish peroxidase (HRP) enzyme on a reduced graphene oxide (GCE) modified glassy carbon electrode. The morphologies and chemical compositions of synthesized materials were examined using Fourier transform infrared spectroscopy (FTIR) and field-emission scanning electron microscopy (FESEM). The modified electrode’s electrochemical behavior was investigated using cyclic voltammetry (CV). Cyclic voltammetry demonstrated HRP/rGO/GCE has better electrocatalytic activity than bare GCE in the oxidation of L-cysteine oxidation in a solution of acetate buffer. The electrochemical sensor had a broad linear range of 0 µM to 1 mM, a 0.32 µM detection limit, and a sensitivity of 6.08 μA μM−1 cm−2. The developed sensor was successfully used for the L-cysteine detection in a real blood sample with good results.
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