In this review are developed insights from the current research work to develop the concept of functional materials. This is understood as real modified substrates for varied applications. So, functional and modified substrates focused on nanoarchitectures, microcapsules, and devices for new nanotechnologies highlighting life sciences applications were revised. In this context, different types of concepts to proofs of concepts of new materials are shown to develop desired functions. Thus, it was shown that varied chemicals, emitters, pharmacophores, and controlled nano-chemistry were used for the design of nanoplatforms to further increase the sizes of materials. In this regard, the prototyping of materials was discussed, affording how to afford the challenge in the design and fabrication of new materials. Thus, the concept of optical active materials and the generation of a targeted signal through the substrate were developed. Moreover, advanced concepts were introduced, such as the multimodal energy approach by tuning optical coupling from molecules to the nanoscale within complex matter composites. These approaches were based on the confinement of specific optical matter, considering molecular spectroscopics and nano-optics, from where the new concept nominated as metamaterials was generated. In this manner, fundamental and applied research by the design of hierarchical bottom-up materials, controlling molecules towards nanoplatforms and modified substrates, was proposed. Therefore, varied accurate length scales and dimensions were controlled. Finally, it showed proofs of concepts and applications of implantable, portable, and wearable devices from cutting-edge knowledge to the next generation of devices and miniaturized instrumentation.
In this paper, we deal with one of the most urgent and relevant topics nowadays, i.e., water pollution. The problem is finding a valid candidate for the absorption and removal of different kinds of pollutants commonly found in water. There are already some indications about graphene oxide as a potential candidate. In the present work, we take a step forward to show how graphene nanoplatelets (rather than the oxide form of this material) are capable of decontaminating water. In this starting step, we use a specific substance as a model pollutant, i.e., acetonitrile, leaving for the future steps, to extend the analysis to additional types of pollutants. In addition to laboratory-produced graphene nanoplatelets, we already examined in the past; now we wish to consider also commercially available ones, so that the new results will not be bound to a laboratory (low technology readiness level) material, but will become interesting also from the industrial point of view, thanks to the scalability of the nanoplatelets production. For this aim, we compare the performance of two types of filters based on two classes of nanomaterials, i.e., those produced by microwave and ultrasound assisted exfoliation, already analyzed in our earlier works, with those commercially distributed by an Italian company, i.e., NANESA, http://www.nanesa.com/. The latter is an innovative SME involved in the production of graphene-based nanomaterials. We focus here in the graphene nanoplatelets, commercially available in industrial batches (GXNan grades). The present study leads to determine which filtering membrane, among the various types of commercial graphene considered, shows the greatest stability, and the lack of breakage of the membrane, concentrating on such accessory features, given that all types of graphene showed excellent adsorption properties.
This paper aims to explain the administrative and the Environmental, Social and Governance (ESG) of the Indonesian Spaceport Project in Biak, Papua, Indonesia, under the Public-Private Partnerships (PPP) scheme, particularly from the protest to fear of environmental damage and traditional rights. This paper analyzes the factors that cause the local society’s reluctance to accept the development of Indonesia’s very first commercial spaceport. This paper uses a doctrinal methodology, which examines changes in the trend of ESG in implementing PPP projects. The method used is a qualitative systematic review of national and international studies. This paper finds that the lack of legal certainty for administrative and ESG as the main factor contributing to the pitfall of the PPP project in Biak Papua. No clear Government Contracting Agency (GCA), plus the fact that the Indonesian government puts too much weight on business consideration in PPP while Papuan people need more ESG, especially considering the historical conflict in the region, has been the epicenter of the problem. Given the ESG-PPP regulatory failure of spaceport development in Biak, more focused studies using comparative study methodology are needed to propose a more robust and customized ESG in PPP regulations in a politically and historically sensitive area. The authors forward a regulatory reform to balance administration, ESG, and business considerations in PPP projects for a spaceport.
Shore line change is considered as one of the most dynamic processes, which were mapped along the coast of Tiruvallur district by using topographic maps of 1976 and multi-temporal satellite images. The satellite images pertaining to 1988, 1991, 2006, 2010, 2013 and 2016 were used to extract the shorelines. It is important to map and monitor the HTL (High Tide Line) at frequent time intervals as the shoreline was demarcated by using visual interpretation technique from satellite images and topographic maps. Followed by this, an overlay analysis was performed to calculate areas of erosion and accretion in the study area. The results revealed that the coast of Tiruvallur district lost 603 ha and gained 630 ha due to erosion and accretion respectively. It was confirmed after the ground truth survey carried out in the study area. The high accretion of 178 ha was found nearby Pulicat Lake and low accretion of 19 ha was seen between Pulicat Lake and Kattupali Port. The high erosion area was found along the Pulicat Lake, Kattupali and Ennore ports, and Ennore creek mouth and southern Ennore such as Periya Kuppam, Chinna Kuppam, Kasi Koil Kuppam, and Thyagarajapuram. It may be concluded that the coastal erosion and accretion in the study area were mainly caused by anthropogenic and natural factors, which altered the coastal environment.
When power is exercised, it results in political behavior in organizations. Excessively held organizational politics can hurt an organization and its members though some consider wisely used political behavior as positive. This study was conducted at Wolaita Sodo Polytechnic College (WSPTC) to investigate the effect of power and political dynamism on employee job satisfaction. Cross-sectional survey design was used to collect data from stratified, randomly selected 146 informants. The Rahim Leader Power Inventory (RLPI), Interpersonal Power Inventory (IPI), Perception of Organizational Politics (POP), and Minnesota Satisfaction Questionnaire (MSQ) were employed to collect data. Descriptive and inferential statistical analyses were made using statistical packages (SPSS version 23). The findings revealed that when managers legitimate, coercive, and reward power bases are higher, then organizational politics becomes higher. Power concentration at higher positions results in increased organizational politics than when it was shared. Regression analysis uncovered that 47% (R-squared 0.468) of variations in job satisfaction were explained by POP and power dynamics. Hence, it is recommended that having power sharing, empowering subordinates, and moderate political maneuvering in the use of power and politics will be helpful in maintaining constructive relationships and job satisfaction.
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