In view of the large energy consumption of the regeneration process in the chemical absorption decarburization process, on the basis of the enrichment classification flow process, the nanoscale ceramic film is used as a new heat exchanger between the enriched liquid and the regeneration gas. The porous ceramic film is capable of coupling thermal-mass transfer to effectively recover part of the water vapor and the heat carried in the regeneration gas, so as to reduce the regenerative energy consumption of the system. The effects of parameters such as regeneration temperature, flow rate, molar fraction of water vapor, and MEA enrichment temperature, flow rate, and MEA concentration of shunt on the hydrothermal recovery effect of ceramic membranes of different pore sizes and lengths were studied by using the heat recovery flux and water recovery rate as the indicators. The results show that the hydrothermal recovery performance of the ceramic membrane increases with the increase of MEA enrichment flow, but decreases significantly with the increase of the enrichment temperature. At the same time, with the increase of regenerative gas velocity and the molar fraction of water vapor in the regenerative gas, the heat recovery flux will increase. The heat recovery performance of the 10 nm ceramic membrane is better than that of the 20 nm ceramic membrane.
The properties of the beta batteries are compared, which are made on the basis of the different β-isotopes with beta decay. Tritium and Ni-63 make it possible to make β-sources of high activity, without harmful associated emissions, with low self-absorption, emitting high-energy β-electrons that penetrate deep into the semiconductor and generate a large number of electron-hole pairs. The efficiency of beta batteries needs to be analyzed based on the real energy distribution of β-electrons. It makes possible to obtain the real value of the energy absorbed inside the β-source, correctly estimate the amount of self-absorption of the β-electrons and part of the β-electronsthere is a penetrate into the semiconductor, the number of electrons and holes that are generated in the semiconductor, and the magnitude of the idling voltage. Formulas for these quantities are calculated in this paper.
Magnetic graphene oxide nanocomposites (M-GO) were successfully synthesized by partial reduction co-precipitation method and used for removal of Sr(II) and Cs(I) ions from aqueous solutions. The structures and properties of the M-GO was investigated by X-ray diffraction, Fourier transformed infrared spectroscopy, X-ray photoelectron spectroscopy, transmission electron microscopy, scanning electron microscopy, vibrating sample magnetometer (VSM) and N2-BET measurements. It is found that M-GO has 2.103 mg/g and 142.070 mg/g adsorption capacities for Sr(II) and Cs(I) ions, respectively. The adsorption isotherm matches well with the Freundlich for Sr(II) and Dubinin–Radushkevich model for Cs(I) and kinetic analysis suggests that the adsorption process is pseudo-second-ordered.
Due to the short cost-effective heat transportation distance, the existing geothermal heating technologies cannot be used to develop deep hydrothermal-type geothermal fields situated far away from urban areas. To solve the problem, a new multi-energy source coupling a low-temperature sustainable central heating system with a multifunctional relay energy station is put forward. As for the proposed central heating system, a compression heat pump integrated with a heat exchanger in the heating substation and a gas-fired water/lithium bromide single-effect absorption heat pump in the multifunctional relay energy station are used to lower the return temperature of the primary network step by step. The proposed central heating system is analyzed using thermodynamics and economics, and matching relationships between the design temperature of the return water and the main line length of the primary network are discussed. The studied results indicate that, as for the proposed central heating system, the cost-effective main line length of the primary network can approach 33.8 km, and the optimal design return temperature of the primary network is 23 ℃. Besides, the annual coefficient of performance and annual energy efficiency of the proposed central heating system are about 3.01 and 42.7%, respectively.
This study investigates the performance assessment of methanol and water as working fluid in a solar-powered vapour absorption refrigeration system. This research clarifies the system’s performance across a spectrum of operating conditions. Furthermore, the HAP software was utilized to determine and scrutinize the cooling load, facilitating a comparative analysis between software-based results and theoretical calculations. To empirically substantiate the findings, this research investigates methanol-water as a superior refrigerant compared to traditional ammonia- water and LiBr-water systems. Through experimental analysis and its comparison with previous research, the methanol-water refrigeration system demonstrated higher cooling efficiency and better environmental compatibility. The system’s performance was evaluated under varying conditions, showing that methanol-water has a 1% higher coefficient of performance (COP) compared to ammonia-water systems, proving its superior effectiveness in solar-powered applications. This empirical model acts as a pivotal tool for understanding the dynamic relationship between methanol concentration (40%, 50%, 60%) and system performance. The results show that temperature of the evaporator (5–15 ℃), condenser (30 ℃–50 ℃), and absorber (25 ℃–50 ℃) are constant, the coefficient of performance (COP) increases with increase in generator temperature. Furthermore, increasing the evaporator temperature while keeping constant temperatures for the generator (70 ℃–100 ℃), condenser, and absorber improves the COP. The resulting data provides profound insights into optimizing refrigerant concentrations for improved efficiency.
The porous carbon/Ni nanoparticle composite was prepared by a freeze-drying method using NaCl as the template. It was applied in the effect of the concentration, adsorption time, and temperature of adsorption on the adsorption behavior. The kinetic model and the adsorption isothermic fitting results show that the adsorption behavior fits with the pseudo-secondary dynamics and the Langmuir isothermal model, indicating that the adsorption process is monolayer adsorption. Thermodynamic results indicate that the adsorption process is spontaneous physicochemical adsorption. The fitting showed that the porous carbon/Ni nanoparticle composites reach 217.17 mg·g-1, at 313 K indicates good adsorption for Congo red.
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