In this study, robust and defect-free thin film composite (TFC) forward osmosis (FO) membranes have been successfully fabricated using ceramic hollow fibers as the substrate. Polydopamine (PDA) coating under controlled conditions is effective in reducing the surface pores of the substrate and making the substrate smooth enough for interfacial polymerization. The pure water permeability (A), solute permeability (B), and structural parameter (S) of the resultant FO membrane are 0.854 L·m–2·h−1·bar−1 (LMH/Bar), 0.186 L·m–2·h−1 (LMH), and 1720 µm, respectively. The water flux and reverse draw solute flux are measured using NaCl and proprietary ferric sodium citrate (FeNaCA) draw solutions at low and high osmotic pressure ranges. As the osmotic pressure increases, a higher water flux is obtained, but its increase is not directly proportional to the increase in the osmotic pressure. At the membrane surface, the effect of dilutive concentration polarization is much less serious for FeNaCA-draw solutions. At an osmotic pressure of 89.6 bar, the developed TFC membrane generates water fluxes of 11.5 and 30.0 LMH using NaCl and synthesized FeNaCA draw solutions. The corresponding reverse draw solute flux is 7.0 g·m–2·h−1 (gMH) for NaCl draw solution, but it is not detectable for FeNaCA draw solution. This means that the developed TFC FO membranes are defect-free and their surface pores are at the molecular level. The performance of the developed TFC FO membranes is also demonstrated for the enrichment of BSA protein.
Heat conduction theory stipulates that two thermo-physical properties of materials: the thermal conductivity “k” and the thermal diffusivity “α” influence the temperature evolution in regular and irregular bodies as a response to various cooling/heating conditions. The traditional statement involving the two thermo-physical properties is examined at length in the present study for the case of a semi-infinite region. The primary objective of the present study is to investigate the influence of the less known thermo-physical property called the thermal effusivity “e” on the incipient surface temperature rise in a semi-infinite body affected by uniform surface heat flux. The secondary objective of the study is to identify a key figure of merit named the dimensionless threshold time that separates the incipient temperature elevation in a semi-infinite region from the incipient temperature elevation in a large wall of finite thickness under the same uniform surface heat flux. The outcome of the methodical analysis suggests that the accurate estimate for the dimensionless threshold time τth in the semi-infinite region should be 0.10.
Forest is the main carbon sink of terrestrial ecosystem. Due to the unique growth characteristics of plants, the response of their growth status and physiological activities to climate change will affect the carbon cycle process of forest ecosystem. Based on the local scale CO2 flux and temperature observation data recorded by the FLUXNET registration site and Harvard Forest FLUX observation tower from 2000 to 2012, combined with the phenological model, this paper analyzes the impact of temperature changes on CO2 flux in temperate forest ecosystems. The results show that: (1) the maximum NEE in 2000–2012 was 298.13 g·m-2·a-1, which occurred in 2010. Except in the 2010 and 2011, the annual NEE in other years was negative. (2) NEE, GPP, temperature and phenology models have good fitting effects (R2 > 0.8), which shows that the stable period of photosynthesis in temperate mixed forest ecosystem is mainly concentrated in summer, and vegetation growth is the dominant factor of carbon cycle in temperate mixed forest ecosystem. (3) The linear fitting results of the change time points of air temperature (maximum point, minimum point and 0 point date) and the change time points of NEE and GPP (maximum point, minimum point and 0 point date) show that there is a significant positive correlation between air temperature and CO2 flux (P < 0.01), and the change of air temperature affects the carbon cycle process of temperate mixed forest ecosystem.
Luxembourg institutions have the opportunity to reconcile environmental goals with financial stability by implementing Green Fintech solutions, as the banking sector increasingly recognizes the importance of sustainability. This study employs a quantitative approach and analyzes data collected from 150 participants working in the banking industry of Luxembourg. The research aims to assess the consequences of adopting Green Fintech on sustainable development. Banking institutions can boost their financial resilience and mitigate climate-related risks by adopting Green Fintech, which improves their sustainability. The paper emphasizes the importance of Green Fintech in the Luxembourg banking sector for advancing sustainable development goals. To effectively address the increasingly complex environmental concerns, it is crucial to embrace innovative Fintechs.
The major objective of this research paper is to assess the management effectiveness of Sheikh Badin National Park District Dera Ismail Khan Khyber Pakhtunkhwa, Pakistan with respect to tourist’s satisfaction. A sample size of 389 respondents (local community, wildlife staff, tourists) were selected through simple random sampling to conclude respondents’ attitude towards phenomenon investigated through three-level Likert scale as a measurement tool. Association between a dependent variable (management effectiveness) was assessed on the independent variables (tourist satisfaction) through a chi-square test. Association of management effectiveness was highly significant with tourists satisfaction from promos of park (p = 0.000), access to information (p = 0.000), roads network (p = 0.000), residential facilities (p = 0.000), trained guides (p = 0.000), safety from crimes and criminals (p = 0.000), provision of health and security services (p = 0.000), overall satisfaction of tourists (p = 0.000), recommendation of SBNP to other tourists (p = 0.000) and revisit intentions of tourists (p = 0.000). Improvement in security measures, better advertisement and improvement in park infrastructure were major recommendations considering the study.
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