In order to maximize the potential energy utilization of agricultural and forestry waste and sludge, the experimental research on co-pyrolysis was carried out for two kinds of sludge (urban industrial sludge, paper sludge) and a typical biomass straw. The results show that adding biomass can effectively improve sludge pyrolysis characteristics; biomass straw and sludge, there are complex interactive effects between components in the co-pyrolysis process, and the characteristic parameters show nonlinear changes. When industrial sludge is mixed with straw, with the increase of straw content, the initial temperature of pyrolysis gradually decreases, the termination temperature increases, the peak of pyrolysis reaction rate and the corresponding temperature gradually increase, and the pyrolysis index gradually increases; when paper sludge is mixed with straw, with the increase of straw content, the initial temperature of pyrolysis gradually decreases, the termination temperature increases, the peak of pyrolysis reaction rate gradually increases, while the peak corresponding temperature gradually decreases, and the pyrolysis index gradually decreases. Combined with characteristic parameters and reaction kinetics analysis, it is suggested that the straw mixing proportion should be controlled at about 25% during the co-pyrolysis of industrial sludge and straw. During the co-pyrolysis of paper sludge and straw, it is suggested to control the straw blending ratio at about 75%.
Photocatalysis, an innovative technology, holds promise for addressing industrial pollution issues across aqueous solutions, surfaces, and gaseous effluents. The efficiency of photodegradation is notably influenced by light intensity and duration, underscoring the importance of optimizing these parameters. Furthermore, temperature and pH have a significant impact on pollutant speciation, surface chemistry, and reaction kinetics; therefore, process optimization must consider these factors. Photocatalytic degradation is an effective method for treating water in environmental remediation, providing a flexible and eco-friendly way to eliminate organic contaminants from wastewater. Selectivity in photocatalytic degradation is achieved by a multidisciplinary approach that includes reaction optimization, catalyst design, and profound awareness of chemical processes. To create efficient and environmentally responsible methods for pollution removal and environmental remediation, researchers are working to improve these components.
Research into electro-conductive textiles based on conductive polymers like polypyrrole has increased in recent years due to their high potential applications in various fields. Conductive polymers behave like insulators in their neutral states, with typical electrical conductivity in the range 10–10 to 10–25 Scm–1. These neutral polymers can be converted into semi-conductive or conductive states with conductivities ranging from 1 Scm–1 to 10–4 Scm–1 through chemical or electro-chemical redox reactions. By applying these polymers to a textile surface, we can obtain novel composites that are strong, flexible, lightweight, and highly electroconductive. These textile composites are suitable for applications such as heating pads, sensors, corrosion-protecting materials, actuators, electrochromic devices, EMI shielding, etc. The methods of application of conductive polymers onto the textile surface, such as in-situ chemical, in-situ electrochemical, in-situ vapor phase, in-situ polymerization in a supercritical fluid, and solution coating processes, are described here briefly. The merits and demerits of these methods are mentioned here. The reaction mechanisms of chemical and electrochemical polymerization proposed by the different researchers are described. Different factors affecting the kinetics of chemical and electrochemical polymerization are accounted for. The influence of textile materials on the kinetics of chemical polymerization is reviewed and reported.
The present article reports the applications of Caputo-Fabrizio time-fractional derivatives. This article generalizes the idea of unsteady MHD free convective flow in a Walters.-B fluid with heat and mass transfer study over an exponential isothermal vertical plate embedded in a porous medium. The governing equations are converted into dimensionless form and extended to fractional model. The generalized Walters-B fluid model has been solved analytically using the Laplace transform technique. From the general solutions we reduce limiting solutions when to the similar motion for Newtonian fluid. The corresponding expressions for and Nusselt and Sherwood numbers are also assessed. Numerical results for velocity, temperature and concentration are demonstrated graphically for various factors of interest and discussed. As a result, we have plotted the influence of fractional parameter on fluid flow and drawn comparison between fractional Walters’-B and fractional Newtonian fluid and found that fractional Newtonian fluid is faster than fractional Walters’-B fluids.
Energy shortages and environmental damage have become serious problems facing the society today. Biomass can be a renewable energy source, which large-scale development and utilization are of great significance to industry and social life. Biomass pyrolysis technology can achieve effective utilization of biomass energy. It is necessary to optimize the pyrolysis reaction technology and device for realize the industrialization and large-scale production of biomass energy.
This research paper explores the influence of first-order chemical reactions on the sustainable properties of electrically conducting magnetohydrodynamic (MHD) fluids in a vertical channel with the unique characteristics of Jeffrey fluid flow. The mathematical model of MHD flow with Jeffrey fluid and chemical reaction incorporates the impacts of viscous dissipation, Joule heating, and a non-Newtonian fluid model with viscoelastic properties in the flow regions. The governing equations of the flow field were solved using the finite difference method, and the impacts of flow parameters on the flow characteristics were discussed numerically using a graphical representation. It’s revealed that increasing the Jeffrey parameter results in a decline in the velocity field profiles. Also, species concentration field profiles decline with higher values of the destruction chemical reaction parameter. The findings of this study have significant implications for various engineering applications, including energy generation, aerospace engineering, and material processing. Additionally, the inclusion of Jeffrey’s fluid flow introduces a viscoelastic component, enhancing the complexity of the fluid dynamics.
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