Water splitting has gained significant attention as a means to produce clean and sustainable hydrogen fuel through the electrochemical or photoelectrochemical decomposition of water. Efficient and cost-effective water splitting requires the development of highly active and stable catalysts for the oxygen evolution reaction (OER) and hydrogen evolution reaction (HER). Carbon nanomaterials, including carbon nanotubes, graphene, and carbon nanofibers, etc., have emerged as promising candidates for catalyzing these reactions due to their unique properties, such as high surface area, excellent electrical conductivity, and chemical stability. This review article provides an overview of recent advancements in the utilization of carbon nanomaterials as catalysts or catalyst supports for the OER and HER in water splitting. It discusses various strategies employed to enhance the catalytic activity and stability of carbon nanomaterials, such as surface functionalization, hybridization with other active materials, and optimization of nanostructure and morphology. The influence of carbon nanomaterial properties, such as defect density, doping, and surface chemistry, on electrochemical performance is also explored. Furthermore, the article highlights the challenges and opportunities in the field, including scalability, long-term stability, and integration of carbon nanomaterials into practical water splitting devices. Overall, carbon nanomaterials show great potential for advancing the field of water splitting and enabling the realization of efficient and sustainable hydrogen production.
Carbon-based hollow structured nanomaterials have become one of the hot areas for research and development of hollow structured nanomaterials due to their unique structure, excellent physicochemical properties and promising applications. The design and synthesis of novel carbon-based hollow structured nanomaterials are of great scientific significance and wide application value. The recent research on the synthesis, structure and functionalization of carbon-based hollow structured nanomaterials and their related applications are reviewed. The basic synthetic strategies of carbon-based hollow structure nanomaterials are briefly introduced, and the structural design, material functionalization and main applications of carbon-based hollow structure nanomaterials are described in detail. Finally, the current challenges and opportunities in the synthesis and application of carbon-based hollow structured nanomaterials are discussed.
Species of the Moraceae family are of great economic, medicinal and ecological importance in Amazonia. However, there are few studies on their diversity and population dynamics in residual forests. The objective was to determine the composition, structure and ecological importance of Moraceae in a residual forest. The applied method was descriptive and consisted of establishing 16 plots of 20 m × 50 m (0.10 ha), in a residual forest of the Alexánder von Humboldt substation of the National Institute of Agrarian Innovation-INIA, Pucallpa, department of Ucayali, where individuals of arboreal or hemi-epiphytic habit, with DBH ≥ 2.50 cm, were evaluated. The floristic composition was represented by 33 species, distributed in 12 genera; five species not recorded for Ucayali were found. Structurally, the family was represented by 138 individuals/ha with a horizontal distribution similar to an irregular inverted “J”. However, there were different horizontal structures among species. It was determined that 85% of the species were in diameter class I (2.50 to 9.99 cm), being the most abundant Pseudolmedia laevis (Ruiz & Pav.) J.F. Macbr. (41.88 individuals/ha); and the most dominant were Brosimum utile (Kunth) Oken (1.71 m2∕ha) and Brosimum alicastrum subsp. bolivarense (Pittier) C.C.Berg (0.90 m2/ha). Likewise, P. laevis and B. utile were the most ecologically important. The information from the present research will allow the establishment of a baseline, which can be used to propose the management of Moraceae in residual forests in the same study area.
This work was carried out with the purpose of generating ecological and silvicultural information oriented to sustainable management. The horizontal structure was evaluated using the importance value index of Curtis and Macintosh, the vertical structure using Finol’s methodology. Through the sociological position index, the percentage natural regeneration and the extended importance value index were estimated in order to infer the permanence of the forest ecosystem. The floristic composition was represented by species of the families Anacardiaceae, Apocynaceae, Fabaceae, Santalaceae, Rhamnaceae, Sapotaceae, Simarubaceae, Ulmaceae, Zygophyllaceae, Capparidaceae, Borraginaceae and Achatocarpaceae. In the horizontal structure, the species with the highest rank was Acacia praecox, followed in order of importance by Schinopsis balansae, Aspidosperma quebracho blanco and Prosopis kuntzei. According to sociological position, Acacia praecox was the most representative species, followed by Patagonula americana, Schinus longifolius, Proposis kuntzei and Aspidosperma quebracho blanco. The species with the best regeneration values were Achatocarpus nigricans and Acacia praecox in the shrub layer and Patagonula americana in the tree layer. The extended importance index consolidated the category of Acacia praecox in the community and gave a better category to Schinopsis balansae, Aspidosperma quebracho blanco, Prosopis kuntzei and Patagonula americana.
The electron/hole transport layer can promote charge transfer and improve device performance, which is used in perovskite solar cells. The nanoarray structure transport layers can not only further promote carrier transport but also reduce recombination. It also has a great potential in enhancing perovskite light absorption, improving device stability and inhibiting the crack nucleation of different structure layers in perovskite solar cells. This paper reviewed the research progress of perovskite solar cells with different nanoarray structure transport layers. The challenges and development directions of perovskite solar cells based on nanoarray structure transport layers are also summarized and prospected.
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