Zero-valent iron is a moderately reducing reagent that is both non-toxic and affordable. In the present work, iron nanoparticles were synthesized using bitter guard leaf extract (Momordica charantia L.) (BGL-Fe NP). Using leaf samples from bitter protectant extract, iron nanoparticles were synthesized with secondary metabolites such as flavonoids and polyphenols acting as capping and reducing agents. Polyphenols reduce Fe²⁺/Fe³⁺ to nanovalent iron or iron nanoparticles. Iron nanoparticles were synthesized by reducing iron chloride as a precursor with bitter protective leaf extract in an alkaline environment. The obtained BGL-Fe NPs were calcined for 4 h at various temperatures of 400 °C, 500 °C, and 600 °C. The obtained samples were coded as BGL-Fe NPs-4, BGL-Fe NPs-5, and BGL-Fe NPs-6, respectively. The synthesized BGL-Fe NPs were systematically characterized by XRD, SEM, FTIR, UV-Vis and TG-DTA analysis. The obtained BGL-Fe NPs were then used as an adsorbent to remove the aqueous solution of basic methylene blue (MB) dye. MB concentration was monitored using UV-Vis spectroscopy.

Beta macrocarpa, Guss is an interesting species showing very low germination rates. The leading objectives of this work were to investigate the dormancy mechanism and to find methods to break dormancy in order to achieve rapid, uniform and high germination. Macro and micro-morphologic analyses were performed by stereo microscopy and scanning electron microscopy showed two fruit coats. The yellow external coat or persistent perianth coat (PPC) was accrescent with 5 erect segments contiguous to the operculum of the seed capsule. This coat forms spongy layers (50 to 300 µm thick) that could be eliminated manually. The narrow internal coat or pericarp or achene coat (AC) forms woody joined seed capsules, each presenting a pressed operculum that cannot be manually opened. This coat was not adherent to seeds and was composed of compressed cells (50 to 200 µm thick) which form pockets for salt cristal. Seeds were lentiform (1 to 2 mm diameter and 0.5 to 0.8 mm thick) and highly fragile. The embryo was whitish surrounded peripherally by the perisperm with two highly developed cotyledons and radical. Polyphenol concentrations in both coats showed that after 4 months of collection, total polyphenol concentrations were 4-fold higher in the pericarp than in the persistent perianth. However, after one year, this parameter decreases significantly in the pericarp, whereas, it increases to a larger extent in the perianth. Different germination tests indicated that the pericarp provides a chemical and a physical resistance to seed germination during the first 4 months of the experiment after collection. The chemical dormancy was released to higher levels of total polyphenol compounds that inhibited seed germination and seedling growth. However, the physical dormancy was associated with the hardness of this intern coat which caused a mechanical resistance to radicle emergence. After one year of storage, total polyphenol pericarp concentration decreased notably, and chemical resistance disappeared, whereas the physical one persisted. Consequently, one year of storage pericarp removal is sufficient to break this exogenous dormancy.

This paper aims to explore the practice and effect of integrating ideological and politics in higher vocational mathematics education. Through the review of relevant literature and the analysis of practical cases, this study analyzes the necessity and feasibility of integrating ideological and political education into higher vocational mathematics teaching, as well as the promoting effect of students' ideological and political education. At the same time, it also discusses how to effectively combine the curriculum thinking and politics with higher vocational mathematics teaching, as well as the strategies and methods to achieve positive results, in order to provide some reference for the majority of higher vocational mathematics teachers.

The design of effective flood risk mitigation strategies and their subsequent implementation is crucial for sustainable development in mountain areas. The assessment of the dynamic evolution of flood risk is the pillar of any subsequent planning process that is targeted at a reduction of the expected adverse consequences of the hazard impact. This study focuses on riverbed cities, aiming to analyze flood occurrences and their influencing factors. Through an extensive literature review, five key criteria commonly associated with flood events were identified: slope height, distance from rivers, topographic index, and runoff height. Utilizing the network analysis process within Super Decision software, these factors were weighted, and a final flood risk map was generated using the simple weighted sum method. 75% of the data was used for training, and 25% of it was used for testing. Additionally, vegetation changes were assessed using Landsat imagery from 2000 and 2022 and the normalized difference vegetation index (NDVI). The focus of this research is Qirokarzin city as a case study of riverbed cities, situated in Fars province, with Qir city serving as its central hub. Key rivers in Qirokarzin city include the Qara Aghaj River, traversing the plain from north to south; the primary Mubarak Abad River, originating from the east; and the Dutulghaz River, which enters the eastern part of the plain from the southwest of Qir, contributing to plain nourishment during flood events. The innovation of this paper is that along with the objective to produce a reliable delineation of hazard zones, a functional distinction between the loading and the response system (LS and RS, respectively) is made. Results indicate the topographic index as the most influential criterion, delineating Qirokarzin city into five flood risk zones: very low, low, moderate, high, and very high. Notably, a substantial portion of Qirokarzin city (1849.8 square kilometers, 8.54% of the area) falls within high- to very-high flood risk zones. Weighting analysis reveals that the topographic humidity index and runoff height are the most influential criteria, with weights of 0.27 and 0.229, respectively. Conversely, the height criterion carries the least weight at 0.122. Notably, 46.7% of the study area exhibits high flood intensity, potentially attributed to variations in elevation and runoff height. Flood potential findings show that the middle class covers 32.3%, indicating moderate flood risk due to changes in elevation and runoff height. The low-level risk is observed sporadically from the east to the west of the study area, comprising 12.4%. Analysis of vegetation changes revealed a significant decline in forest and pasture cover despite agricultural and horticultural development, exacerbating flood susceptibility.