In this paper, a classification of low-dimensional nanomaterials is given, and new type of these nanomaterials — subnanophase coatings are proposed. Experimental results on the formation of a wetting layer of a transition metal on a silicon substrate by physical deposition in vacuum and results of this layer identification by the EELS method are given. Based on these results, a new approach to the formation of subnanophase coatings has been proposed by creation of an interface stresses structuring WL. The possible properties and application prospects of subnanophase coatings are considered.
Based on the population change data of 2005–2009, 2010–2014, 2015–2019 and 2005–2019, the shrinking cities in Northeast China are determined to analyze their spatial distribution pattern. And the influencing factors and effects of shrinking cities in Northeast China are explored by using multiple linear regression method and random forest regression method. The results show that: 1) In space, the shrinking cities in Northeast China are mainly distributed in the “land edge” areas represented by Changbai Mountain, Sanjiang Plain, Xiaoxing’an Mountain and Daxing’an Mountain. In terms of time, the contraction center shows an obvious trend of moving northward, while the opposite expansion center shows a trend of moving southward, and the shrinking cities gather further; 2) in the study of influencing factors, the results of multiple linear regression and random forest regression show that socio-economic factors play a major role in the formation of shrinking cities; 3) the precision of random forest regression is higher than that of multiple linear regression. The results show that per capita GDP has the greatest impact on the contraction intensity, followed by the unemployment rate, science and education expenses and the average wage of on-the-job workers. Among the four influencing factors, only the unemployment rate promotes the contraction, and the other three influencing factors inhibit the formation of shrinking cities to various degrees.
Important modifications are occurring in temperate forests due to climate change; in polar latitudes their distribution area is increasing, while in tropical latitudes it is decreasing due to temperature increase and droughts. One of the biotic regulators of temperate forests are the debarking insects that cause the mortality of certain trees. These insects have increased in number, favored by climate change, and the consequences on forests have not been long in coming. In recent times in the northern hemisphere, the massive mortality of conifers due to the negative synergy between climate change and debarking insects has been evident. In Mexico, we have also experienced infestations by bark stripping insects never seen before; therefore, we are trying to understand the interactions between climate change, forest health and bark stripping insects, to detect the areas with greater susceptibility to attack by these insects and propose management measures to reduce the effects.
The analysis of the accumulation and export of nutrients by the cowpea crop is fundamental for a more sustainable fertilization program, because the definition of the doses of organic fertilizers based only on the estimated maximum yield does not guarantee the maintenance of soil fertility. The objective of this study was to evaluate the effect of fertilization with chicken manure on the productivity, accumulation and exportation of nutrients by the pods of cowpea. A randomized block design was used, with five doses of chicken manure (0; 5; 10; 20 and 40 t ha-1) and four repetitions. The highest levels of P and Mg were found in the leaves with the application of 40 t ha-1 of manure. The maximum pod length was 14.47 cm, estimated with the dose of 33.33 t ha-1 of manure. The highest values of diameter, number of pods per plant and pod productivity were observed at the highest dose of manure applied. In relative terms, that is, total exported in relation to the total extracted by the aerial part, phosphorus is the nutrient most exported by the pods, on average 58%, followed by N (55%), K (43%), Mg (40%), S (38%) and Ca (17%). At the highest dose, although Ca accumulation occurred in large quantities (31.3 kg ha-1), only 13% of it was exported by the pods. Fertilizing cowpea with chicken manure supplied essential nutrients and increased pod yield from 7.2 (no fertilization) to 16.3 t ha-1 (fertilization with 40 t ha-1 of chicken manure). The plant remains of the cowpea constitute an important source of nutrients, being obtained at the highest dose of manure applied (40 t ha-1) the following amounts of macronutrients (kg ha-1): N (51.4); P (5.1); K (27.6); Ca (27.1); Mg (8.2); S (5.1), which may return to the soil, with the incorporation of the plants.
Adsorption is a widely used method for the treatment of dissolved contaminants. Various agro-industrial wastes have been explored as potential adsorbents, showing high efficiency in dye removal. Each adsorbate-adsorbent pair needs kinetic, and equilibrium models to scale up this process. In this work, the equilibrium, kinetics and thermodynamics of the corn Tuza-Red 40 system were evaluated under batch system at ph = 2.0 at temperatures of 25, 40, and 55 °C. The Langmuir, Freundlich and Temkin models were selected for the isotherm representation, while the Lagergren, Ho, and Elovich equations for the kinetics of the process. The Freundlich model presented the best fit to the isotherms, the adsorption kinetics was best described by the Ho equation, and the values for Gibbs free energy and entropy indicated the spontaneity and feasibility of the process.
One functional class is described in terms of one-sided modulus of continuity and the modulus of positive (negative) variation on which there
is a uniform convergence of the truncated cardinal Whittaker functions.
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