The article aims at developing an efficient and stable catalysts for simultaneous hydrogenation of o-chloronitrobenzene to o-chloroaniline and 1,4-butanediol dehydrogenation to γ-butyrolactone. A series of CoO-Cu-MgO catalysts, composed of 10 wt% of copper, various amount of cobalt loadings (1, 5 and 10 wt%) and remaining of MgO were developed by co-precipitation followed by thermal treatment. o-Chloroaniline and γ-butyrolactone were the main products with high yield of 85% and 90%, respectively. The advantage of the coupling process is that the hydrogenation reaction was conducted without external hydrogen, demonstrating minimize the hydrogen consumption known as hydrogen economy route. From N2O characterization results, the high activity of 5CoO-10Cu-MgO was found that it has high amount of Cu species (Cu0/Cu+1) which govern the stable activity and selectivity on time on stream study in presence of cobalt in Cu-MgO.
An alternative for sustainable management in the cultivation of Capsicum annuum L. has focused on the use of plant growth promoting rhizobacteria (PGPR) and arbuscular mycorrhizal fungi (AMF). This research selected PGPRPGPR and AMF based on their effect on Bell Pepper and Jalapeño bell pepper plants. Five bacterial strains isolated from different localities in the state of Mexico (P61 [Pseudomonas tolaasii], A46 [P. tolaasii], R44 [Bacillus pumilus], BSP1.1 [Paenibacillus sp.] and OLs-Sf5 [Pseudomonas sp.]) and 3 AMF treatments (H1 [consortium isolated from Chile rhizosphere in the state of Puebla], H2 [Rhizophagus intraradices] and H3 [consortium isolated from lemon rhizosphere from the state of Tabasco]). In addition, a fertilized treatment (Steiner solution 25%) and an absolute control were included. Jalapeño bell pepper “Caloro” and Bell Pepper “California Wonder” seedlings were inoculated with AMF at sowing and with CPB 15 days after emergence, and grown under controlled environment chamber conditions. In Jalapeño bell pepper, the best bacterial strain was P61 and the best AMF treatment was H1; in Bell Pepper the best strain was R44 and the best AMF were H3 and H1. These microorganisms increased the growth of jalapeño bell pepper and Bell Pepper seedlings compared to the unfertilized control. Likewise, P61 and R44 positively benefited the photosynthetic capacity of PSII.
This paper proposes a floating-interest-rate infrastructure bond, where the interest of a government bond is paid to investors during the period of construction and the early period of operation. Unlike the usual government bond, which provides a fixed interest rate, the proposed floating-interest-rate infrastructure bond pays a floating interest, the rate of which depends on spillover tax revenues. Effective infrastructure projects have a positive effect on the economic growth of a region, known as the spillover effect. When user charges and the return from spillover tax revenues are below the fixed rate of the government bond, the interest rate will equal to the fixed rate of the government bond. In this case, investors in the infrastructure will receive interest on the government bond at the minimum rate. As the spillover effect of the infrastructure increases, the rate of return for infrastructure investment will become greater than the fixed rate of the government bond. The success of the floating-interest-rate infrastructure bond depends on the spillover effect and on transparency and accountability. Policy recommendations are provided in this paper on how to increase the spillover effect and improve transparency and accountability.
The porous carbon/Ni nanoparticle composite was prepared by a freeze-drying method using NaCl as the template. It was applied in the effect of the concentration, adsorption time, and temperature of adsorption on the adsorption behavior. The kinetic model and the adsorption isothermic fitting results show that the adsorption behavior fits with the pseudo-secondary dynamics and the Langmuir isothermal model, indicating that the adsorption process is monolayer adsorption. Thermodynamic results indicate that the adsorption process is spontaneous physicochemical adsorption. The fitting showed that the porous carbon/Ni nanoparticle composites reach 217.17 mg·g-1, at 313 K indicates good adsorption for Congo red.
In this paper, a new compound health drink of aloe and balsam pear was developed by using high-quality aloe and balsam pear as main raw materials and white granulated sugar and citric acid as auxiliary materials. The effects of the addition of aloe juice, balsam pear juice, white granulated sugar and citric acid on the sensory quality of the beverage were investigated and analyzed. On this basis, the orthogonal test was conducted to determine the best formula for the beverage. The results showed that the order of the factors affecting the quality of the finished product was the addition of aloe juice > white granulated sugar > citric acid > balsam pear juice; the optimal formula is 24% aloe juice, 10% balsam pear juice, 7% white granulated sugar and 0.09% citric acid and the resulting beverage was bright in color, sweet and sour with good flavor, and its physical, chemical and health indicators meet the national standards.
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