Nanoporous nickel has been prepared by electrodeposition using non-ionic surfactant based liquid crystalline template under optimized processing conditions. Physicochemical properties of nanoporous nickel are systematically characterized through XRD, SEM and AFM analyses. Comparison of electrocatalytic activity of nanoporous nickel with smooth nickel was interrogated using cyclic voltammetry (CV), chronoamperometry (CA) and electrochemical impedance spectroscopy (EIS) analyses. Distinctly enhanced electrocatalytic activity with improved surface poisoning resistance related to nanoporous nickel electrode towards methanol oxidation stems from unique nanoporous morphology. This nanoporous morphology with high surface to volume ratio is highly beneficial to promote active catalytic centers to offer readily accessible Pt catalytic sites for MOR, through facilitating mass and electron transports.
The changes the magnetic flux generated (electric, magnetic and electromagnetic waves) on the surface of earth due to sudden changes is a matter of discussion. These emissions occur along the fault line generated due to geological and tectonic processes. When sudden changes occur in the environment due to seismic and atmospheric variations, these sensing was observed by creatures and human bodies because the animals and trees adopt the abnormal signals and change the behavior. We have analyzed the changing behavior of recorded signal by live sensors (i.e., banyan tree). So we use the deep-rooted and long-aged banyan tree. The root of banyan tree (long-aged) has been working as a live sensor to record the geological and environmental changes. We record the low frequency signals propagated through solar-terrestrial environment which directly affect the root system of the banyan tree and changes that have been observed by live sensors. Then, very low frequency (VLF) signal may propagate to the earth-ionosphere waveguide. We have also analyzed the different parameters of live cells which is inbuilt in latex of the tree, so we record the dielectric parameters of green stem latex and found some parameters i.e., dielectric constant (ε) and dielectric loss (ε’) of various trees to verify these natural hazards and found good correlation. Therefore, we can say by regularly monitoring the bio-potential signal and dielectric properties of banyan tree and we are able to find the precursory signature of seismic hazards and environmental changes.
Dust is one of the atmospheric pollutants that have adverse environmental effects and consequences. Dust fall contains particles of 100 microns or even smaller ones, which fall from the atmosphere onto the earth surface. The aim of this study is to determine the concentration of lead in dust fall samples in order to study the pollution level of this element in Zahedan, Sistan and Baluchistan Province, Iran. Therefore, sampling was carried out using 30 marble dust collectors (MDCO) for 3 months in the spring of 2015 to investigate the quantitative variation and spatial analysis of lead content in dust fall. These dust collectors were placed at 30 stations on the building roofs with a height of approximately 1.5 meters across the city. According to the results, the mean lead concentration in the spring was 90.16 mg/kg. In addition, the zoning map of lead content shows that the lowest level of lead was measured at Imam Khomeini station while the highest amount of lead appeared in Mostafa Khomeini station.
Flower-visiting insects may be pollinators or, conversely, unrelated to the reproductive process of plants. Interactions between pollinating and non-pollinating flower visitors can negatively influence pollen transfer. Little is known about the effects of bee visits on pollination of squash (Cucurbita spp.) flowers and their interactions with the presence of other floral visitors. The study was conducted at the Facultad de Ciencias Agrarias (Universidad Nacional de Rosario) in the south of Santa Fe (Argentina) and evaluated the effect of the presence of non-pollinating floral visitors on bee foraging in the flowers of two cultivated squash species. Flower sex and squash species C. maxima and C. moschata were included as variables. A total of 937 visitors were recorded in 403 flowers. Bees of the tribes Eucerini and Apini were the most abundant pollinators with an average of 2.3 individuals per flower during 10 minutes of observation. Diptera, flower sex and squash species did not influence the number of bee visits, whereas the prolonged stay of coleoptera and formicids negatively affected the presence of bees on both squash species. The presence of coleoptera reduced bee visits by 38%, while in the presence of ants, bees did not visit the flowers. The theft of nectar and pollen by non-pollinating floral visitors could have a negative effect on the reproductive success of squash.
Due to its physicochemical properties, nanoparticles titanium dioxide (nTiO2) is being put into mass production and widespread applications, which inevitably results in their increasing exposure to the water body. After it entering the water body, the chemical properties of nTiO2 can be influenced by ion compositions, ion strength and pH, which affects their ecological risk. Excess of ammonium (NH4+) fertilizer has contaminated soil and water environments. In this paper, the Zeta potentials and hydrodynamic radius of nTiO2 were studied in NH4+ solution compared to those in Na+ solution. In addition, the sedimentation rate of nTiO2 was also investigated. The experiment results show that high pH inhibits the sedimentation of nTiO2. Moreover, NH4+ increases the stability of nTiO2 more than Na+ at the same IS, which was attributed the more negative Zeta potentials and the smaller hydraulic radius. Our results provide a theoretical basis for evaluating the ecological risk of nTiO2 in aqueous solution containing NH4+.
We reviewed the research on super-hydrophobic materials. Firstly, we introduced the basic principles of super-hydrophobic materials, including the Young equation, Wenzel model, and Cassie model. Then, we summarized the main preparation methods and research results of super-hydrophobic materials, such as the template method, soft etching method, electrospinning method, and sol-gel method. Among them, the electrospinning method that has developed in recent years is a new technology for preparing micro/nanofibers. Finally, the applications of super-hydrophobic materials in the field of coatings, fabric and filter material, anti-fogging, and antibacterial were introduced, and the problems existing in the preparation of super-hydrophobic materials were pointed out, such as unavailable industrialized production, high cost, and poor durability of the materials. Therefore, it is necessary to make a further study on the application of the materials in the selection, preparation, and post-treatment.
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