Synthesis of macro-mesoporous Titania (Titanium dioxide-TiO₂) nanospheres was successfully achieved using a modified template-free methodology to incorporate macroporous channels into a mesoporous TiO₂ framework to form mixed macro-mesoporous TiO₂ spheres (MMPT), which were doped with carbon dots (C-dots) to form improved nanocomposites (C-dots@MMPT). Elemental composition, surface bonding and optical properties of these nanocomposites were characterized by X-ray diffraction (XRD), Fourier transforms infrared spectroscopy (FTIR) and ultraviolet-visible absorption spectroscopy (UV-VIS). Evaluation of photocatalytic activity for each (C-Dots@MMPT) sample was performed via degrading the Methylene Blue (MB) dye compared with bare samples (MMPT) under visible light irradiation using 300 Watt halogen lamp.

We report a method for effectively and homogeneously incorporating carbon nanotubes (CNTs) in the form of double-wall (DWCNTs) and multi-wall (MWCNTs) structures into commercial paints without the use of additives, surfactants, or chemical processes. The process involves the physical mixing of the nanotubes and polymers using the cavitation energy of an ultrasonic bath. It is a simple, fast method that allows for uniform distribution of carbon nanotube bundles within the polymer for direct application. Due to the hydrophobic properties of the carbon nanotubes as grown, we used paint samples containing 0.3% by mass of both types of CNTs and observed an improvement in waterproofing through wettability and water absorption through immersion tests on the samples. Different solvents such as water, formaldehyde, and glycerin were used, and the results showed an increase in paint impermeability of 30% and 25% with the introduction of DWCNTs and MWCNTs, respectively. This indicates a promising, economically viable, and revolutionary method for applying nanotechnology in the polymer industry.

Brunei Darussalam is a small Sultanate country with diverse forest cover. One of them would be Mangrove Forest. As it has four main administrative districts, Temburong would be the chosen case study area. The methods of collecting data for this article are by collecting secondary data from official websites and the map in this article (Figure 1) are showing the forest cover in Brunei Darussalam as of 2020. The aim of this article is to explain the mangrove forest especially at the Temburong District. As for the objectives, it would to be able to show the different types of forests in Temburong, hoping in ability to explain the different subtypes of mangroves forest and to explain in general the green jewel of Brunei Darussalam. Temburong has become the second highest tree coverage in Brunei Darussalam of 124 kha as of 2010, while the mangrove forest covering about 66% of total mangrove forest of 12,164 km² out of 18,418 hectares. Mangrove forest has seven subtypes: Bakau species, Nyireh bunga, Linggadai, Nipah, Nipah-Dungun, Pedada and Nibong. Selirong Forest Reserve and Labu Forest Reserve are the two-mangrove forest reserves in Brunei Darussalam at Temburong District. Forest cover in Brunei Darussalam are 3800 hectares as of 2020 and has lost its tree coverage of 1.17 kha and one of the reasons would be forest fire and the tree cover loss due to fire is around 197 ha and the district that has lost its tree cover mostly was at Belait District of total 13.4 kha between the year 2001 until 2022.

Quartz sand was used as bed material in a small fluidized bed reactor with 1 kg/h feed. Corn straw powder with particle size of 20–40 mesh, 40–60 mesh, 60–80 mesh and 80–120 mesh was used as raw material for rapid pyrolysis at reaction temperatures of 400 °C, 450 °C, 500 °C and 550 °C. The bio-oil obtained after liquefaction of pyrolysis gas was analyzed. The variation trend of bio-oil composition in pyrolysis of corn straw powder with different reaction temperatures and raw material sizes was compared. The results show that: (1) the content of 3-hydroxyl-2-phenyl-2-acrylic acid in bio-oil increases with the decrease of raw material particle size, but it is less at 450 °C; (2) with the increase of reaction temperature, the content of hydroxyacetaldehyde in bio-oil increases at first and then decreases: the content of hydroxyacetaldehyde in bio-oil is the highest at 500 °C when the particle size is 20–40 mesh, and the highest at 450 °C with the other three particle sizes. Compared with other particle sizes, raw material with the particle size of 60–80 mesh is not conducive to the formation of aldehyde compounds; (3) the reaction temperature of 500 °C and the particle size of 60–80 mesh of raw materials are more conducive to the formation of phenolic compounds in bio-oil; (4) the ester compounds with particle size of 20–40 mesh in bio-oil is 20% higher than that of other particle sizes; (5) the reaction temperature and the particle size of raw materials had no significant effect on the formation of ketones, alcohols and alkane compounds in bio-oils.

Developing Asia’s infrastructure gap results from both inadequate public resources and a lack of effective channels to mobilize private resources toward desired outcomes. The public-private partnership (PPP) mechanism has evolved to fill the infrastructure gap. However, PPP projects are often at risk of becoming distressed, or worst, being terminated because of the long-term nature of contracts and the many different stakeholders involved. This paper applies survival-time hazard analysis to estimate how project-related, macroeconomic, and institutional factors affect the hazard rate of the projects. Empirical results show that government’s provision of guarantees, involvement of multilateral development banks, and existence of a dedicated PPP unit are important for a project’s success. Privately initiated proposals should be regulated and undergo competitive bidding to reduce the hazard rate of the project and the corresponding burden to the government. Economic growth leads to successful project outcomes. Improved legal and institutional environment can ensure PPP success.

Learning from experience to improve future infrastructure public-private partnerships is a focal issue for policy makers, financiers, implementers, and private sector stakeholders. An extensive body of case studies and “lessons learned” aims to improve the likelihood of success and attempts to avoid future contract failures across sectors and geographies. This paper examines whether countries do, indeed, learn from experience to improve the probability of success of public-private partnerships at the national level. The purview of the paper is not to diagnose learning across all aspects of public-private partnerships globally, but rather to focus on whether experience has an effect on the most extreme cases of public-private partnership contract failure, premature contract cancellation. The analysis utilizes mixed-effects probit regression combined with spline models to test empirically whether general public-private partnership experience has an impact on reducing the chances of contract cancellation for future projects. The results confirm what the market intuitively knows, that is, that public-private partnership experience reduces the likelihood of contract cancellation. But the results also provide a perhaps less intuitive finding: the benefits of learning are typically concentrated in the first few public-private partnership deals. Moreover, the results show that the probability of cancellation varies across sectors and suggests the relative complexity of water public-private partnerships compared with energy and transport projects. An estimated $1.5 billion per year could have been saved with interventions and support to reduce cancellations in less experienced countries (those with fewer than 23 prior public-private partnerships).