All ophiolite associations mark epochs of active tectonic movements, which lead to significant petrological processes and modification of the relief of the Earth's crust. Here we present a geological-petrographical characterization of one ophiolitic associations composed of: a) serpentinites; b) amphibolites-metamorphosed volcanic rocks and tuffs; c) metagabbros and metagabbrodiabases, placed among the Proterozoic metamorphic complex in the Rhodope Massif of Bulgaria on the Balkan Peninsula, South-Eastern Europе. The goal is to clarify the paleogeographical and geological setting during its creation. The methods of lithostratigraphic profiling and correlations on the database of geological field mapping were used, supplemented by microscopic, geochemical and isotopic studies of numerous rock samples. The summarized results confirm a certain stratigraphic level of the Ophiolite Association among the metamorphic complex and a complicated and protracted heterogenetic development, which is typical for the ophiolite associations created in eras of closing oceans, opposite movement of tectonic plates, subduction-obduction environment with appearance of autochthonous Neoproterozoic magmatism. Obducted fragments of serpentinites mark an old erosional continental surface, subsequently covered by transgressively deposited pelitic-carbonate sediments. The general conclusion of our study confirms the concept that the metamorphic complex of the Rhodope Massif represents a unified stratigraphic system consisting of two petrographic groups of different ages, with which we oppose the idea of a trust construction, launched by a group of geologists.

Gender inequality is a structural social problem, associated with history, culture, education, religion and politics, this difficulty occurs in all social institutions due to the heterogeneity of the structure in the sexual division of labor, socioeconomic inequality, inclusion and inequity in participation in the public space between men and women. Public policies and attitudes towards gender equality in Peruvian university students were analyzed according to socio-academic variables. A descriptive-comparative study, with a quantitative approach, and not experimental cross-sectional, involved 776 university students from a public and a private university in Peru, intentionally selected. Adaptive attitudes (57.9%) were found to tend to be sexist; Likewise, in the study dimensions, the same trend was found in the sociocultural and relational levels, while in the personal dimension students develop sexist attitudes (62.4%). It is concluded, attitudes towards gender equality are sexist reproduction that is influenced by the sociocultural environment of the family, this situation occurs to a greater extent in men, while female students present attitudes of equality in greater intensity to seek equity in the distribution of roles.

The intermittent flow cold storage heat exchanger is one of the most important components of the pulse tube expansion refrigerator based on the reverse Brayton cycle. In the experimental system, the volume and heat transfer of the helical tube play a decisive role in the stable operation of the whole experimental system. However, there are few studies on heat transfer in a helical tube under helium working medium and intermittent flow conditions. In this paper, a process and method for calculating the volume of a helical tube are proposed based on the gas vessel dynamics model. Subsequently, a three-dimensional simulation model of the helical tube was established to analyze the heat transfer process of cryogenic helium within the tube. The simulations revealed that the temperature of helium in the tube decreases to the wall temperature and does not change when the helical angle exceeds 720°. Moreover, within the mass flow rate range of 1.6 g/s to 3.2 g/s, an increase in the mass flow rate was found to enhance the heat transfer performance of the helical tube. This study provides a reference for the selection and application of a helical tube under intermittent flow conditions and also contributes to the experimental research of inter-wall heat exchanger and pulse tube expansion refrigerators.

In Emerging economies, MNCs (Multinational corporations) encounter several issues while devising Strategies to penetrate foreign markets, examining these SMEs’ performance in present times and assessing their internationalisation process is crucial. The purpose of this research is to investigate how international entrepreneurial orientation affects SMEs’ international performance during internationalization, as well as how organizational culture in the Kingdom influences the international performance of these MNCs. To attain this objective (n = 206) MNCs in the Kingdom have adopted internationalisation strategies. Questionnaires were administered as part of a survey approach for this study. To forecast and estimate relationships, partial least squares structural equation modelling (PLS-SEM) was employed. This study indicates that improving internationalization performance, mainly through active participation in foreign markets, is one of the SMEs’ strategies during the internationalization process. The empirical findings demonstrate that international entrepreneurial orientation influences the internationalisation performance of SMEs largely influenced by organisational culture. Previous research shows that the success of SMEs’ internationalization, however, is not directly impacted by their international entrepreneurial orientation. This study supports the significance of organisational culture during internationalisation. This study offers insightful information that motivates policymakers and owner-managers in developing nations, especially in KSA, to build organizational cultures and dynamic capacities that meet the demands of globalization in today’s business scenario.

The experiments were carried out to validate an analytical method and to examine the impact of various decontaminating solutions on the removal of acephate residues from okra. Acephate analysis was performed using HPLC-UV, and sample extraction was done using the QuEChERS method. Method validation encompassed assessing specificity, linearity, precision, accuracy, as well as limits of detection (LOD) and quantification (LOQ). The method exhibited excellent linearity with R² values ≥ 0.99. LOD and LOQ were determined at 0.5 µg mL⁻¹ and 2 µg mL⁻¹, respectively. The results indicated average recoveries ranging from 80.2% to 83.3% with a % RSD below 5%. The decontamination procedures include rinsing with running tap water, soaking in lukewarm water, 2% CH₃COOH, 1% NaCl, 5% NaHCO₃, 0.01% KMnO₄, and in commercially available decontamination products such as nimwash, veggie clean, and arka herbiwash for a duration 10 minutes. Among all the treatments, soaking in nimwash solution showed remarkable effectiveness (96.75% removal), followed by veggie clean (94.97% removal) and arka herbiwash (95.80% removal). Washing okra samples in running tap water was found to be the least effective compared to other treatments.