This report deals synthesis of CuInGa (CIG) nano materials along with doctor blade and spin coated thin films selenization and their physical properties. The doctor blade and spin coated CIGS/SLG thin films thicknesses are obtained ̴ 2 μm and ̴ 2.95 μm. Raman spectroscopy of these thin films leads the chalcopyrite phase formation by exhibiting the peak at wave number 171 cm-1. The well developed grain growths of spin coated thin film are appeared in the surface morphology. While the grain growths developments in doctoral blade coated thin film is rather hard and fuzzy. EDS measurement recognised the existence of the compositional ratio presence of the alloying elements Cu, In. Ga and Se. The doctor blade and spin coated CIGS/SLG thin films are exhibited the UV- Visible transmission peak in the wave length range 240 nm 320 nm. The optical energy band gaps for the doctor blade and spin coated CIGS thin films are obtained 1.41eV and 1.5 eV.
A novel composite material based on polymers (polyvinyl alcohol, polyvinyl butyral) and liquid crystal (4-n-pentyl-4’-cyanobiphenyl) has been developed and studied. Configuration transformations of point defects in nematic droplets under the influence of an electric field, caused by localized changes in the concentration of NLC within the polymer matrix, have been discovered and analyzed. The boundary conditions necessary for achieving a nematic structure with homogeneous alignment of the director both within the droplet and at its surface have been established, optimizing the anisotropy of light transmission in polymer-dispersed liquid crystal (PDLC) films. Additionally, polarization effects inside nematic droplets under the application of an electric field have been identified.
Alginate-silver nanocomposites in the form of spherical beads and films were prepared using a green approach by using the aqueous extract of Ajwa date seeds. The nanocomposites were fabricated by in situ reduction and gelation by ionotropic crosslinking using calcium ions in solution. The rich phytochemicals of the date seed extract played a dual role as a reducing and stabilizing agent in the synthesis of silver nanoparticles. The formation of silver nanoparticles was studied using UV-Vis absorption spectroscopy, and a distinct surface plasmon resonance peak at 421 nm characteristic of silver nanoparticles confirmed the green synthesis of silver nanoparticles. The morphology of the nanocomposite beads and film was compact, with an even distribution of silver nanoclusters. The catalytic property of the nanocomposite beads was evaluated for the degradation of 2-nitrophenol in the presence of sodium borohydride. The degradation followed pseudo-first-order kinetics with a rate constant of 1.40 × 10−3 s−1 at 23 ℃ and an activation energy of 18.45 kJ mol−1. The thermodynamic parameters, such as changes in enthalpy and entropy, were evaluated to be 15.22 kJ mol−1 and −197.50 J mol−1 K−1, respectively. The nanocomposite exhibited properties against three clinically important pathogens (gram-positive and gram-negative bacteria).
In this study, the effect of porogenic solvents on pore size distribution of the polycaprolactone (PCL) thin films was investigated. Five thin PCL films were prepared using the solvent-casting method. Chloroform, Methylene Chloride (MC) and three different compositions of MC/ Dimethylformamide (DMF) (80/20, 50/50 and 20/80) were used as solvents. Scanning Electron Microscopy (SEM) investigations were employed to study morphology and consequently the pore size distribution of the prepared films. The PCL films made by chloroform and MC as a solvent were completely non-porous. Whereas the other films (made by a combination of MC and DMF) showed both uni-modal and bi-modal pore size distributions.
Nanotechnology is recognized as one of the high and new technologies in the 21st century. Carbon nanotubes have been widely used in molecular sieve, drug transport and seawater desalination due to their unique mechanical, electrical, optical and other excellent properties. As the main representative of carbon nanotube macroscopic materials, carbon nanotube film not only retains the microscopic properties of carbon nanotube, but also has good mechanical properties and stable chemical properties. The preparation and application of carbon nanotubes (CNTS) have attracted extensive attention from scholars at home and abroad. In this paper, the research on carbon nanotube films in recent years is reviewed. Based on the preparation of carbon nanotube films, chemical vapor deposition, LB (Langmuir-Blodgett) film and electrostatic layer-by-layer self-assembly techniques are briefly described. In addition, the applications of carbon nanotubes in biological field, photoelectric nano devices, water treatment, seawater desalination and other fields are also described.
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