Synthesis of macro-mesoporous Titania (Titanium dioxide-TiO2) nanospheres was successfully achieved using a modified template-free methodology to incorporate macroporous channels into a mesoporous TiO2 framework to form mixed macro-mesoporous TiO2 spheres (MMPT), which were doped with carbon dots (C-dots) to form improved nanocomposites (C-dots@MMPT). Elemental composition, surface bonding and optical properties of these nanocomposites were characterized by X-ray diffraction (XRD), Fourier transforms infrared spectroscopy (FTIR) and ultraviolet-visible absorption spectroscopy (UV-VIS). Evaluation of photocatalytic activity for each (C-Dots@MMPT) sample was performed via degrading the Methylene Blue (MB) dye compared with bare samples (MMPT) under visible light irradiation using 300 Watt halogen lamp.
The modification of the Turia River’s course in the 1960s marked a pivotal transformation in Valencia’s urban landscape, evolving from a flood protection measure into a hallmark of sustainable urban development. However, recent rainfalls and flooding events produced directly by the phenomenon known as DANA ((Isolated Depression at High Levels) in October 2024 have exposed vulnerabilities in the infrastructure, particularly in the rapidly urbanized southern areas, raising questions about the effectiveness of past solutions in the context of climate change and urban expansion. As a result of this fragility, more than 200 deaths have occurred, along with material losses in 87 municipalities, whose industrial infrastructure accounts for nearly one-third of the economic activity in the Province of Valencia, valued at 479.6 million euros. This paper presents, for the first time, a historical-document-based approach to evaluate the successes and shortcomings of Valencia’s flood management strategies through policy and spatial planning analysis. Also, this paper remarks the ongoing challenges and potential strategies for enhancing Valencia’s urban resilience, emphasizing the need for innovative water management systems, improved drainage infrastructure, and the renaturalization of flood-prone areas. The lessons learned from Valencia’s experience in 1957 and 2024 can inform future urban planning efforts in similar contexts facing the dual pressures of environmental change and urbanization.
Among carbon nanoparticles, fullerene has been observed as a unique zero-dimensional hollow molecule. Fullerene has a high surface area and exceptional structural and physical features (optical, electronic, heat, mechanical, and others). Advancements in fullerene have been observed in the form of nanocomposites. Application of fullerene nanocomposites has been found in the membrane sector. This cutting-edge review article basically describes the potential of fullerene nanocomposite membranes for water remediation. Adding fullerene nanoparticles has been found to amend the microstructure and physical features of the nanocomposite membranes in addition to membrane porosity, selectivity, permeation, water flux, desalination, and other significant properties for water remediation. Variations in the designs of fullerene nanocomposites have resulted in greater separations between salts, desired metals, toxic metal ions, microorganisms, etc. Future investigations on ground-breaking fullerene-based membrane materials may overcome several design and performance challenges for advanced applications.
Water splitting has been one of the potential techniques as a clean and renewable energy resource for the fulfillment of world energy demands. One of the major aspects of this procedure is the exploitation of efficient and inexpensive electrocatalysts due to the fact that the water oxidation procedure is accompanied by a delayed reaction. In this research, ZnO-CoFe2O4 nanostructure was successfully synthesized via the green method and green resources from cardamom seeds and ginger peels for oxygen evolution reaction (OER). The modified Glassy carbon electrode (GCE) with ZnO-CoFe2O4 is effective for the electrochemical water oxidation interaction since it has sufficient electrical strength and excellent catalytic performance. The creation of rice-like and small granular structures of ZnO-CoFe2O4 nano-catalysts was confirmed by characterization methods such as XRD, FESEM, EDS and MAP. According to the achieved results, in the electrolysis of water, with in-cell voltage of 1.40 V and 50 mA cm–2 for current density in a 0.1 M KOH electrolyte and OER only has 170 mV overpotentials.
The paper deals with the issues of the influence of forest cover on the average annual runoff of rivers in the Pripyat River basin. In the study area, under the influence of solar radiation, the temperature of the air and the soil surface increases, evaporation from the water surface also increases, and the moisture content of the upper layers of the soil decreases. In general, with an increase in forest cover, the annual layer of the runoff of the studied rivers increases, as well as with an increase in the amount of precipitation (in contrast to the runoff of short-term floods). However, with a forest cover of more than 20%–30% and a relatively small amount of precipitation, the runoff decreases, which is associated with the retention of part of the precipitation by the forest cover. With a large amount of precipitation and low forest cover, the runoff also decreases, which is probably due to the loss of precipitation water for evaporation, etc. The conducted studies show that, just as the forest affects water resources, the flow of moisture to watersheds also affects the state of forest systems. Moreover, this interaction is expressed by evaporation from forests. Under influence of change of a climate growth of evaporation is observed.
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