Deficiencies in postharvest technology and the attack of phytopathogens cause horticultural products, such as tomatoes to have a very short shelf life. In addition to the economic damage, this can also have negative effects on health and the environment. The objective of this work is to evaluate an active coating of sodium alginate in combination with eugenol-loaded polymeric nanocapsules (AL-NP-EUG) to improve the shelf life of tomato. Using the nanoprecipitation technique, NPs with a size of 171 nm, a polydispersity index of 0.113 and a zeta potential of −2.47 mV were obtained. Using the HS-SPME technique with GC-FID, an encapsulation efficiency percentage of 31.85% was determined for EUG. The shelf-life study showed that the AL-NP-EUG-treated tomatoes maintained firmness longer than those without the coating. In addition, the pathogenicity test showed that tomatoes with AL-NP-EUG showed no signs of damage caused by the phytopathogen Colletotrichum gloesporoides. It was concluded that the formulation of EUG nanoencapsulated and incorporated into the edible coating presents high potential for its application as a natural nanoconservative of fruit and vegetable products such as tomato.
The increased awareness of the environmental effects of petroleum based plastics has stimulated the coffee price emergence of biodegradable polymers such as polylactic acid (PLA). In a bid to increase the sustainability of PLA agricultural residues of animal feeds (corn stover, rice straw, and soybean hulls) have been explored and examined as reinforcing fillers to PLA composites. The consideration of such applications is suitable to the goals of the circular economy as it recycles low-value agricultural products. The current review critically evaluates lately carried out life cycle assessment (LCA) studies on PLA composites that have implemented such waste fillers with the full focus being on their environmental performance as well as methodological consistency. The review shows that these fillers have a potential of reducing the amount of greenhouse emission, energy usage, and other environmental effects, compared to pure PLA. However, unevenness in LCA methodology, especially in functional units, the system boundaries, and impacts categories obstructs direct LCA comparisons. The 1997 State of the Market report also has limited options of feedstocks and the lack of appraisals in the socio-economic front, so the overall sustainability analysis is restricted. Some of the remaining limitations that can be critical are to have generalized LCA frameworks, extended exploration of waste-based fillers, as well as combination of techno-economic analysis and social impact. Future inquiries ought to devise design considerations that would optimize both the functional characteristics and the performance of the environment and improve the reliability of sustainability measures. This review is evidence to the potential of agricultural waste reinforced PLA composites in the progress towards environmentally friendly materials and the need of integrative evaluation in the sustainable maturation of bioplastics.
The integration of digitalization and servitization has become a significant trend in transforming the manufacturing industry due to digital intelligence technology. This paper examines the impact of the integration of digitalization and servitization on the performance of manufacturing companies and how small-scale enterprises can promote digital transformation leading to servitization. The study involved surveying 331 manufacturing companies in China using a seven-point Likert scale questionnaire. Measurement scales were validated using confirmatory factor analysis and discriminant validity tests. Mediation analysis assessed digitalization’s impact on servitization and firm performance. The study’s findings emphasize the significant impact of digitalization and servitization on enterprises’ performance. Digitalization plays a crucial role in mediating this relationship. The study highlights three critical dimensions of digital variables, including digital technology, digital labor, and digital relationship resources, essential in enabling effective servitization. Manufacturing enterprises generally prefer aligning their technology investments and organizational changes within the digitalization framework to implement servitization successfully. The study suggests two integration strategies, namely conservative and aggressive. The finding emphasizes that the convergence of digitalization and servitization leads to a new manufacturing production mode called digital servitization.
The low V-notch impact toughness is a notable limitation of the PBT/PA6 blend. In this study, we maintained a fixed PBT/PA6 ratio of 50/50 while varying the proportion of PP in the given blend at levels of 0%, 70%, 80%, 90%, and 100% neat PP. The results from the unnotched impact toughness tests for the PP/PBT/PA6 blends showed favorable outcomes. Specifically, the impact toughness of the PP/PBT/PA6 samples progressively increased with the rise in PP content. Initially, the toughness dropped from 10.13 kJ/m² in the 0% PP sample to 8.6 kJ/m² in the 70% PP sample, before increasing gradually from 8.6 kJ/m² in the 70% PP sample to 17.45 kJ/m² in the 90% PP sample to 17.45 kJ/m² in the 90% PP sample, which represents an increase of about 72% relative to the 0% PP sample. These positive results demonstrate that the addition of PP significantly enhances the impact toughness of the blend compared to formulations without PP.
Although public-private partnership (PPP) is regarded as one of the key effective tools in the development of many countries, various challenges surrounding PPPs are not well understood. This paper explores nine key challenges in PPP implementation: (1) different organizational cultures and goals between the partners, (2) poor institutional environment and support, (3) weak political and legal frameworks, (4) unreliable mechanisms for sharing risk and responsibility, (5) inadequate procedures for the selection of PPP partners, (6) inconsistency between resource inputs and quality, (7) inadequate monitoring and evaluation of PPP processes, (8) lack of transparency, and (9) the inherent nature of PPPs. This paper aims to provide the perceptions in the existing literature on many of these challenges, as well as provide solutions to each challenge.
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