The present article reports the applications of Caputo-Fabrizio time-fractional derivatives. This article generalizes the idea of unsteady MHD free convective flow in a Walters.-B fluid with heat and mass transfer study over an exponential isothermal vertical plate embedded in a porous medium. The governing equations are converted into dimensionless form and extended to fractional model. The generalized Walters-B fluid model has been solved analytically using the Laplace transform technique. From the general solutions we reduce limiting solutions when to the similar motion for Newtonian fluid. The corresponding expressions for and Nusselt and Sherwood numbers are also assessed. Numerical results for velocity, temperature and concentration are demonstrated graphically for various factors of interest and discussed. As a result, we have plotted the influence of fractional parameter on fluid flow and drawn comparison between fractional Walters’-B and fractional Newtonian fluid and found that fractional Newtonian fluid is faster than fractional Walters’-B fluids.

BiVO₄ was hydrothermally synthesized under different preparing conditions and characterized by XRD, SEM, Raman spectrum and BET specific surface area. The influence of different pH value and annealing temperature and hydrothermal time on the morphologies and structures of the BiVO₄ samples was investigated systematically. It can be found that annealing would eliminate the effects caused by the pH of precursor, heating temperature and heating time, but preparing conditions still influenced the size and specific surface area of samples. Furthermore, the photocatalytic activities of the fabricated BiVO₄ were also evaluated by the degradation of methyl blue in aqueous solution under UV and visible light irradiation.

We have studied the effect of the series resistance on the heating of the cathode, which is based on carbon nanotubes and serves to realize the field emission of electrons into the vacuum. The experiment was performed with the single multi-walled carbon nanotube (MCNT) that was separated from the array grown by CVD method with thin-film Ni-Ti catalyst (nickel 4 nm/Ti 10 nm). The heating of the cathode leads to the appearance of a current of the thermionic emission. The experimental voltage current characteristic exhibited the negative resistance region caused by thermal field emission. This current increases strongly with increasing voltage and contributes to the degradation of the cold emitter. The calculation of the temperature of the end of the cathode is made taking into account the effect of the phenomenon that warms up and cools the cathode. We have developed a method for processing of the emission volt-ampere characteristics of a cathode, which relies on a numerical calculation of the field emission current and the comparison of these calculations with experiments. The model of the volt-ampere characteristic takes into account the CNT’s geometry, properties, its contact with the catalyst, heating and simultaneous implementation of the thermionic and field emission. The calculation made it possible to determine a number of important parameters, including the voltage and current of the beginning of thermionic emission, the temperature distribution along the cathode and the resistance of the nanotube. The phenomenon of thermionic emission from CNTs was investigated experimentally and theoretically. The conditions of this type emission occurrence were defined. The results of the study could form the basis of theory of CNT emitter’s degradation.

This paper is devoted to the discussion of dynamical properties of anisotropic dark energy cosmological model of the universe in a Bianchi type-V space time in the framework of scale covariant theory of gravitation formulated by Canuto et al.(phys.Rev.Lett.39:429,1977).A  dark energy cosmological model is presented by solving the field equations of this theory by using some physically viable conditions. The dynamics of the model is  studied  by computing the cosmological parameters, dark energy density, equation of state(EoS) parameter, skewness parameters, deceleration parameter and the jerk parameter. This being a scalar field model gives us the quintessence model of the universe which describes a significant dark energy candidate of our accelerating universe. All the physical quantities discussed are in agreement with the recent cosmological observations.

Diamond-like Nanocomposites (DLN) is a newly member in amorphous carbon (a:C) family. It consists of two or more interpenetrated atomic scale network structures. The amorphous silicon oxide (a:SiO) is incorporated within diamond-like carbon (DLC) matrix i.e. a:CH and both the network is interpenetrated by Si-C bond. Hence, the internal stress of deposited DLN film decreases remarkably compare to DLC. The diamond-like properties have come due to deform tetrahedral carbon with sp³ configuration and high ratio of sp³ to sp² bond. The DLN has excellent mechanical, electrical, optical and tribological properties. Those properties of DLN could be varied over a wide range by changing deposition parameters, precursor and even post deposition treatment also. The range of properties are: Resistivity 10^-4 to 10¹⁴ Ωcm, hardness 10–22 GPa, coefficient of friction 0.03-0.2, wear factor 0.2-0.4 10^-7mm³/Nm, transmission Vis-far IR, modulus of elasticity 150-200 GPa, residual stress 200-300 Mpa, dielectric constant 3-9 and maximum operating temperature 600^°C in oxygen environment and 1200^°C in O₂ free air. Generally, the PECVD method is used to synthesize the DLN film. The most common procedures used for investigation of structure and composition of DLN films are Raman spectroscopy, Fourier transformed infrared spectroscopy (FTIR), HRTEM, FESEM and X-ray photo electron spectroscopy (XPS). Interest in the coating technology has been expressed by nearly every industrial segment including automotive, aerospace, chemical processing, marine, energy, personal care, office equipment, electronics, biomedical and tool and die or in a single line from data to beer in all segment of life. In this review paper, characterization of diamond-like nanocomposites is discussed and subsequently different application areas are also elaborated.

Metal organic framework is a class of hybrid network of supramolecular solid materials comprised of a large number of inorganic and organic linkers all bounded to metal ions in a well-organized fashion. This type of compounds possess a greater surface area with an advantage of changing pore sizes, diversified and beautiful structure which withdrew an intense interest in this field. In the present review articles, the structural aspects, classification, methods of synthesis, various factors affecting the synthesis and stability, properties and applications have been discussed. Recent advances in the field and new directions to explore the future scope and applications of MOFs have been incorporated in this article to provide current status of the field.