The development of flexible, wearable electronic devices is one of the future directions of technology development. Flexible conductive materials are important supporting materials for wearable electronic devices. Polymer has excellent flexibility; it is an important way to prepare flexible conductors from polymer-based conductive composites. In this paper, the research progress of polymer-based flexible conductive composites is summarized in terms of preparation and characterization methods. The key factors to realize flexible conductors are put forward, namely, the maintenance of excellent polymer elasticity and the realization of stability. The design and preparation of the extensible conductor with high-elasticity matrix and nanofiller are introduced in detail, and the problems in the current research are summarized.

Benzoxazine resin, a new type of phenolic resin, has many advantages, such as a strong molecular design, no small molecular release in the curing process, excellent thermal stability and mechanical properties, and a high residual carbon ratio. Thus, it is important for electronic communication industry matrix material. To meet the needs of high-frequency and high-speed communication technology for low-dielectric polymer resin, the low-dielectric modification of benzoxazine resin is of great significance to the high frequency and high-speed propagation of the signal, which attracts a wide range of materials researchers’ attention. In this paper, we review a series of studies on the low dielectric modification of benzoxazine resin in recent years, including the synthesis of new monomers, inorganic - organic hybridization, copolymerization with other resins, and low molecular weight benzoxazine resin research trends.