In order to explore the influence of the ferroelectric surface on the structure and properties of semiconductor oxides, the growth of CdS nanocrystals was regulated and controlled by taking single-crystal perovskite PbTiO3 nanosheets as the substrate through a simple hydrothermal method. Through composition design, a series of PbTiO3-CdS nanocomposite materials with different loading concentrations were prepared, and their microstructure and photocatalytic properties were systematically analyzed. Studies show that in the prepared product, CdS nanoparticles selectively grow on the surfaces of PbTiO3 nanosheets, and their morphology is affected by the exposed surfaces of PbTiO3 nanosheets. There is a clear interface between the PbTiO3 substrate and CdS nanoparticles. The concentration of the initial reactant and the time of hydrothermal reaction also significantly affect the crystal morphology of CdS. Photocatalysis studies have shown that the prepared PbTiO3-CdS nanocomposite material has a significant degradation effect on 10 mg/L of Rhodamine B aqueous solution. The degradation efficiency rises with the increase of CdS loading concentration. When degrading 10 mg/L Rhodamine B aqueous solution, the PbTiO3-CdS sample with a mass fraction of 3% can reach a degradation rate of 72% within 120 min.
Municipal authorities in industrialized and in developing countries face unceasingly the issues of congestion, insufficiency of transport means capacity, poor operability of transport systems and a growing demand for reliable and effective urban transport. While the expansion of infrastructure is generally considered as an undesirable option, in specific cases, when short links or ring roads are missing, new infrastructure projects may provide beneficial solutions. The upgrading and renewal of existing networks is always a challenge to the development of a modern city and the welfare of citizens. Central governance and management of transport systems, the establishment of smart and digital infrastructure, advanced surveillance and traffic monitoring, and intra-city energy-harvesting policy are some of the steps to be taken during the transition to a green and sustainable urban future.
Municipal authorities have also to consider other options and strategies to create a citizen-friendly setting for mobility: diminish the need for trips (digitalization of services, e-commerce, etc.), shift from private to public transport and transform the urban form to promote non-motorized transport in favor of the natural environment and public health. A citizen-friendly policy based on the anticipation of future needs and technological development seems to be a requisite for European cities searching for a smooth integration of their networks into urban space.
An α, α′-dipyridyl adduct of a complex compound hexaaquatribenzene-1,2,4,5-tetracarbonatotetra iron (III) with porous structure was synthesized for the first time. According to the results of elemental, X-ray, IR-spectroscopic and differential-thermal analyses the individuality, chemical formula, thermal destruction, and form of coordination of acidic anion and dipyridyl were established. During interaction of a complex compound with dipyridyl, it completely loses all crystallization molecule of water resulting in a compound with a chemical formula of Fe4(C6H2(COO)4)3(dpy)2(dipyridyl). Using the identification of diffraction pattern the parameters of lattice cell of the complex compound were determined.
This paper analyzed the equitable allocation of infrastructure across regional states in Ethiopia. In general, in the past years, there has been a good start in the infrastructure sector in Ethiopia. However, the governance and equity system of infrastructure in Ethiopia is not flexible, not technology-oriented, not fair, and not easily solved. The results of in-depth interviews and focus group discussions (FGDs) showed that there is a lack of institutional capacity, infrastructure governance, and equity, which has negatively impacted the state- and nation-building processes in Ethiopia. According to the interviewees, so long as the unmet demand for infrastructure exists, it remains a key restrain on doing business in most Ethiopian regional states. This is due to the lack of integrated frameworks, as there are coordination failures (lack of proper government intervention, including a lack of proper understanding and implementation of the constitution and the federal system). In Ethiopia, to reduce these bottlenecks arising from the lack of institutional capacity, infrastructure governance, and equity and their effects on nation-building, first of all, the government has to critically hear the people, deeply assess the problems, and come to the point and then discuss the problems and the way forward with the society at large.
The world has complex mega-cities and interdependent infrastructures. This complication in infrastructure relations makes it sensitive to disasters and failures. Cascading failure causes blackouts for the whole system of infrastructures during disasters and the lack of performance of the emergency management stakeholders is clear during a disaster due to the complexity of the system. This research aimed to develop a new concurrent engineering model following the total recovery effort. The objectives of this research were to identify the clustered intervention utilized in the field of resilience and developing a cross-functional intervention network to enhance the resilience of societies during a disaster. Content analysis was employed to classify and categorize the intervention in the main divisions and sub-divisions and the grouping of stakeholders. The transposing system was employed to develop an integrated model. The result of this research showed that the operations division achieved the highest weight of information interchange during the response to improve the resilience of the system. The committee of logistics and the committee of rescue and relief needed the widest bandwidth of information flow in the concurrent engineering (CE) model. The contributed CE model helped the stakeholders provide a resilient response system. The final model and the relative share value of exchanging information for each workgroup can speed up recovery actions. This research found that concurrent engineering (CE) is a viable concept to be implemented as a strategy for emergency management. The result of this research can help policymakers achieve a collaborative teamwork environment and to improve resilience factors during emergency circumstances for critical infrastructures.
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