We report a method for effectively and homogeneously incorporating carbon nanotubes (CNTs) in the form of double-wall (DWCNTs) and multi-wall (MWCNTs) structures into commercial paints without the use of additives, surfactants, or chemical processes. The process involves the physical mixing of the nanotubes and polymers using the cavitation energy of an ultrasonic bath. It is a simple, fast method that allows for uniform distribution of carbon nanotube bundles within the polymer for direct application. Due to the hydrophobic properties of the carbon nanotubes as grown, we used paint samples containing 0.3% by mass of both types of CNTs and observed an improvement in waterproofing through wettability and water absorption through immersion tests on the samples. Different solvents such as water, formaldehyde, and glycerin were used, and the results showed an increase in paint impermeability of 30% and 25% with the introduction of DWCNTs and MWCNTs, respectively. This indicates a promising, economically viable, and revolutionary method for applying nanotechnology in the polymer industry.
The semiclassical boron–boron interatomic pair potential is constructed in an integral form allowing its converting into the analytical one. It is an ab initio B–B potential free of any semiempirical adjusting parameters, which would serve as an effective tool for the theoretical characterization of all-boron and boron-rich nanomaterials.
Forest transition is a trend change process from decreasing to increasing forest area in a country or region. Since the 1990s, ecological and environmental problems such as climate change and loss of biodiversity have received constant attention. The research theory and method of forest transformation has gradually become the frontier and hot topic pursued by international academic circle. With forest transformation as the theme, on the basis of introducing the origin of forest transformation research, along the development vein and internal logic of forest transformation research, this paper reviews the research progress of forest transition theory from the perspectives of Kuznets curve of forest environment and forest transition path, and summarizes the major issues in forest transformation research. The main direction of future research is proposed, including the impact of economic globalization on forest transition, the refinement of research units and the analysis of forest quality transition.
This article refers to Hallstatt in Austria and Ioannina in Greece. The goals analyze the two locations that have similarities in geometric shape, digital elevation model (DEM), and geomorphology. Firstly, Hallsatt’s advances were more technical than aesthetic. There is a general tendency towards extravagance and baroque and Greco-Oriental influences. Secondly, Ioannina is a mountainous city located around Lake Pamvotis. The geometry develops parallel to the lake. The city experiences many cultures. The ancient city had an urban planning that characterized the Ottoman Empire. In the old part, there is the castle, old stone streets, wooden houses, and the house of the Greek Muslim Ali Pasha. The author obtains numerous aerial photographs using Google Earth software. The photographs were received dynamically for all the perimeters of the regions. In short, the cartographer has between 15 and 20 photographs. The next step is to align the photographs in Zephyr photogrammetry software. Configuring resolutions, distance, camera locations, contrast, and brightness is essential. The final products are the 3D texture, 3D model, and orthophotos from Hallstatt and Ioannina. Digital products are suitable for measuring areas, circumferences, and heights. Furthermore, digital products represent a digital archiving practice: conservation and visualization are crucial factors today as they share, represent, promote, and document urban planning, historical memory, and the natural environment.
Knowledge of the presence of heavy metals in soils of agricultural areas is important to prevent their accumulation in cultivated plants. The objective of the present investigation was to evaluate the total concentrations and fractions of heavy metals Cd, Pb, Zn, Fe, Mn, Ni, Cu, Cr and Co in the tobacco-growing area of Pinar del Río, Cuba and their relationship with the physicochemical properties of soil. For the study, 59 samples of three types of soils were collected at 20 cm depth. The pseudo-total concentrations of metals in the soils are low and lower than the prevention values registered for Cuban soils. In general, the heavy metals studied present a high affinity for the most stable fractions of the soil, which means a low risk of transfer to the tobacco crop or accumulation in groundwater. The pseudo-total concentrations of heavy metals were low, below the alert values established for soils in the region. The heavy metals studied were mainly associated with the residual fraction, the second fraction with the highest association with metals was that linked to manganese and iron oxides. The principal component analysis showed that their main source is pedogenetic and that these elements are closely related to cation exchange capacity and calcium content.
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