Polymers obtained from renewable sources are gaining popularity over their petroleum based counter parts in recent years due to their capability to address the environmental pollution related concerns emanating from the widespread usage of synthetic polymers. Even though the polymers from renewable sources are attractive in an environmental point of view, some of the property limitations and the high cost of these materials pose limitations for their extensive commercial applications. These aspects opened the door for a large chunk of research activities in development of polyblends and composites containing polymers from renewable sources as one of the components. Poly (lactic acid) (PLA) is one of the most discussed and commercialized polymer originated from renewable resources. Even though it has many useful properties, certain disadvantages like high brittleness, low impact resistance etc. limit the wide spread commercialization of PLA. In this review article, the recent research activities which are aimed to fill this gap by various modifications of PLA are discussed with special emphasis on the latest research advancements in the field of biodegradable and non biodegradable systems containing PLA.
Regarding to the influence of chloride and fluoride ions on the corrosion resistance, the electrochemical behavior of Ti alloys has been deeply studied. In this work, the main goal was to investigate the electrochemical behavior of cp-Ti and Ti-Mo alloys containing 6, 10 and 15 wt% of Mo concentrations. All the samples were immersed in different solutions, such as 0.15 mol L-1 Na2SO4, 0.15 mol L-1 Ringer, 0.15 mol L-1 Ringer plus 0.036 mol L-1 NaF and 0.036 mol L-1 NaF. Simulating the commercial fluorinated gels, the NaF solutions naturally-aerated were prepared with 1450 ppm of fluoride ions. The electrochemical techniques applied in this work were the open-circuit potential, cyclic voltammetry, besides the technique for chemical identification, which was X-ray photoelectron spectroscopy. The formation and growth of TiO2 and MoO2 were identified, without pitting corrosion. The electrochemical stability and the corrosion resistance of the Ti-Mo alloys decreased in the solutions containing chloride and fluoride ions, with an appreciative decrease especially in the fluorinated medium. The Ti-Mo alloy with higher Mo content concentration was the material with higher corrosion resistance. Therefore, it is a promising candidate as a biomaterial, once the osseointegration needs a satisfactory corrosion resistance for being achieved.
To investigate the possible role of arbuscular mycrrhizal fungi (AMF) in alleviating the negative effects of salinity on Stevia rebaudiana (Bert.), the regenerated plantlets in tissue culture was transferred to pots in greenhouse and inoculated with Glomus intraradices. Salinity caused a significant decrease in chlorophyll content, photosynthesis efficiency and enhanced the electrolyte leakage. The use of AMF in salt –affected plants resulted in improved all above mentioned characteristics. Hydrogen peroxide and malondialdehyde (MDA) contents increased in salt stressed plants while a reduction was observed due to AMF inoculation. CAT activity showed a significant increase up to 2 g/l and then followed by decline at 5 g/l NaCl in both AMF and non-AMF treated stevia, however, AMF inoculated plants maintained lower CAT activity at all salinity levels (2 and 5 g/l). Enhanced POX activities in salt- treated stevia plants were decreased by inoculation of plants with AMF. The addition of NaCl to stevia plants also resulted in an enhanced activity of SOD whilst, AMF plants maintained higher SOD activity at all salinity levels than those of non-AMF inoculated plants. AMF inoculation was capable of alleviating the damage caused by salinity on stevia plants by reducing oxidative stress and improving photosynthesis efficiency.
In recent years, the foundry sector has been showing an increased interest in reclamation of used sands. Grain shape, sieve analysis, chemical and thermal characteristics must be uniform while molding the sand for better casting characteristics. The problem that tackled by every foundry industry is that of processing an adequate supply of sand which has the properties to meet many requirements imposed upon while molding and core making. Recently, fluidized bed combustors are becoming core of ‘clean wastes technology’ due to their efficient and clean burning of sand. For proven energy efficient sand reclamation processing, analysis of heating system in fluidized bed combustor (FBC) is required. The objective of current study is to design heating element and analysis of heating system by calculation of heat losses and thermal analysis offluidized bed combustorfor improving efficiency.
Numerical study of subcooled and saturated flow boiling in the curved and helically coiled tubes in presence of phase change is one of the challenging area of CFD studies. In this paper, the CFD modeling of the nucleate and convective flow boiling in the small helically coiled tube at low vapor quality (up to the 18.93 percent) region is studied. A proper Eulerian-based mathematical model is used for interphase exchange forces and heat transfer between two phases in CFD modeling using Bulk boiling model. The results show that, the inner and the bottom wall of the helically coiled tube have the lowest and the highest heat transfer coefficient, respectively. The effect of change in coil diameter, helical pitch and tube diameter is investigated on the counters of vapor volume fraction. It is seen that at low vapor quality flows, the heat transfer coefficient is enhanced by decreasing in coil diameter, tube diameter and increasing in coil pitch of helically coiled tube.
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