Cobalt-ion batteries are considered a promising battery chemistry for renewable energy storage. However, there are indeed challenges associated with co-ion batteries that demonstrate undesirable side reactions due to hydrogen gas production. This study demonstrates the use of a nanocomposite electrolyte that provides stable performance cycling and high Co²⁺ conductivity (approximately 24 mS cm⁻¹). The desirable properties of the nanocomposite material can be attributed to its mechanical strength, which remains at nearly 68 MPa, and its ability to form bonds with H₂O. These findings offer potential solutions to address the challenges of co-dendrite, contributing to the advancement of co-ion batteries as a promising battery chemistry. The exceptional cycling stability of the co-metal anode, even at ultra-high rates, is a significant achievement demonstrated in the study using the nanocomposite electrolyte. The co-metal anode has a 3500-cycle current density of 80 mA cm⁻², which indicates excellent stability and durability. Moreover, the cumulative capacity of 15.6 Ah cm⁻² at a current density of 40 mA cm⁻² highlights the better energy storage capability. This performance is particularly noteworthy for energy storage applications where high capacity and long cycle life are crucial. The H₂O bonding capacity of the component in the nanocomposite electrolyte plays a vital role in reducing surface passivation and hydrogen evolution reactions. By forming strong bonds with H₂O molecules, the polyethyne helps prevent unwanted reactions that can deteriorate battery performance and efficiency. This mitigates issues typically associated with excess H₂O and ion presence in aqueous Co-ion batteries. Furthermore, the high-rate performance with excellent stability and cycling stability performance (>500 cycles at 8 C) of full Co||MnO₂ batteries fabricated with this electrolyte further validates its effectiveness in practical battery configurations. These results indicate the potential of the nanocomposite electrolyte as a valuable and sustainable option, simplifying the development of reliable and efficient energy storage systems and renewable energy applications.

Tomato is one of the major solanaceous vegetables, which has a unique place in the global vegetable market. Instead of being a high-value crop, there is still a need to do improvement in its potential against various biotic and abiotic stressors that adequately demolish its real yield. Alternaria solani (causing early blight disease) is designated as one of the fatal organisms that may reduce tomato crop yield by up to 80%. There were lots of methods, viz., chemical, cultural and biological suggested to overcome it. However, chemical strategies are much in vogue, but they have several negative consequences for human health and the ecosystem. Enlightening this issue, the efficacy of various treatments, viz., chemical fungicides (Amistar Top^®, Nativo^®, and Contaf^®), biochar and fungal bioagent (Trichoderma viride) was assessed under both in vivo and in vitro conditions. Induced resistance is mediated by several regulating pathways, like salicylic acid and jasmonic acid. These mediating pathways manipulate different physiological processes like growth and development, stress tolerance, and defence mechanisms of the plant. The assessment of results revealed that among all treatments biochar at 3.25% by weight consistently displayed remarkable effectiveness against the early blight infection by triggering resistance and improving the overall performance of tomato plants. This result is attributed to improved soil health, fastening mineralization as well as absorption processes, and boosting the plant’s immunity with the use of a higher concentration of biochar. Hence, it could be recommended for the overall improvement of tomato crop and its sustainability.

Organisational culture stands as a fundamental prerequisite for the efficacious operation of any given organisation. The primary aim of this study is to discern potential alterations within the dimensions of organisational culture across the pre-COVID-19, contemporary, and favoured paradigms within the realm of public administration. The data set was obtained from a cohort of 1189 officials in the Czech Republic. The Organisational Culture Assessment Instrument (OCAI) was deployed for the purposes of conducting an online survey. The dominance of the clan archetype across all examined time frames has been corroborated. In addition, a statistically significant manifestation of these dimensions has been determined. In relation to pertinent variables, specifically gender, age, tenure, manager gender, and the dimensions typifying organisational culture, no statistically significant correlations have emerged. Respondents have not reported a sense of work-life imbalance in the aftermath of the pandemic. In summary, it is deduced that the pandemic has not exerted a drastic influence on the metamorphosis of organisational culture within the ambit of public administration. This study provides invaluable information on the repercussions of the pandemic within a sphere that, as an intangible constituent, often goes under-recognised. Mastery of the positioning of dimensions across diverse archetypes is of paramount significance for managers, as it can provide guidance in the cultivation of an apt organisational culture.

The current study provides a comprehensive analysis of MHD hybrid nanofluids and stagnation point flow toward a porous stretched cylinder in the presence of thermal radiation. Here, alumina (Al₂O₃) and copper (Cu) are considered the hybrid nanoparticles, while water (H₂O) is the base fluid. To begin, the required similarity transformations are applied to transform the nonlinear coupled PDEs into nonlinear coupled ODEs. The obtained highly nonlinear sets of ODEs are then solved analytically by using the HAM procedure. The calculations of the thermal radiation term in the energy equation are done based on the Roseland approximation. The result of various embedded variables on temperature and velocity profiles is drawn and explained briefly. Aside from that, the numerical solution of well-known physical quantities, like skin friction and the Nusselt number, is computed by means of tables for the modification of the relevant parameter. The analysis shows that the magnetic field has opposite behavior on θ(η) and f'(η) profiles. It is seen that more magnetic factors M decline f'(η) and upsurge θ(η). Moreover, the behavior of skin friction and the Nusselt number are the same for the magnetic parameter M. Meanwhile, a higher Reynolds number R_e declines temperature profile and skin friction while upsurging the local Nusselt number. There are many applications of this study that are not limited to engineering and manufacturing, such as polymer industry, crystal growth, tumor therapy, plasma, fusing metal in electric heaters, nuclear reactors, asthma treatment, gastric medication, cooling of atomic systems, electrolytic biomedicine, helical coil heat exchangers, axial fan design, polymer industry, plane counter jets, and solar collectors.

Herein, we report a facile preparation of super-hydrophilic sand by coating the sand particles with cross-linked polyacrylamide (PAM) hydrogels for enhanced water absorption and controlled water release aimed at desert agriculture. To prepare the sample, 4 wt% of aqueous PAM solution is mixed with organic cross-linkers of hydroquinone (HQ) and hexamethylenetetramine (HMT) in a 1:1 weight ratio and aqueous potassium chloride (KCl) solution. A specific amount of the above solution is added to the sand, well mixed, and subsequently cured at 150 °C for 8 h. The prepared super-hydrophilic sands were characterized by Fourier-transform infrared spectroscopy (FT-IR) for chemical composition and X-ray diffraction (XRD) for successful polymer coating onto the sand. The water storage for the samples was studied by absorption kinetics at various temperature conditions, and extended water release was studied by water desorption kinetics. The water swelling ratio for the super-hydrophilic sand has reached a maximum of 900% (9 times its weight) at 80 °C within 1 h. The desorption kinetics of the samples showed that the water can be stored for up to a maximum of 3 days. Therefore, super-hydrophilic sand particles were successfully prepared by coating them with PAM hydrogels, which have great potential to be used in sustainable desert agriculture.

The journey towards better healthcare sustainability in Asian nations demands a comprehensive investigation into the impact of urban governance, poverty, and female literacy on infant mortality rates. This study undertakes a rigorous exploration of these key factors to pave the way for evidence-based policy interventions, utilizing data from a panel of six selected Asian countries: Pakistan, China, India, Indonesia, Malaysia, and the Philippines, spanning the years 2001 to 2020. The findings reveal that adequate sanitation facilities, higher female literacy rates, and sustained economic growth contribute to a reduction in infant mortality. Conversely, increased poverty levels and limited women’s autonomy exacerbate the infant mortality rates observed in these countries. The Granger causality analysis validates the reciprocal relationship between urban sanitation (and poverty) and infant mortality rates. Furthermore, the study establishes a causal relationship where female literacy rates Granger-cause infant mortality rates, and conversely, infant mortality rates Granger-cause women’s autonomy in these countries. The variance decomposition analysis indicates that sustained economic growth, improved female literacy rates, and enhanced women’s empowerment will likely impact infant mortality rates in the coming decade. Consequently, in low-income regions where numerous children face potentially hazardous circumstances, it is imperative to allocate resources towards establishing and maintaining accessible fundamental knowledge regarding sanitation services, as this will aid in reducing infant mortality rates.