The developmental dilemma of infant and toddler care is examined from a family perspective, and in-depth analyses of infant and toddler care are conducted using Family Systems Theory and Cultural Capital Theory,which are essential to the holistic development of children, the balance between family and work, and the sustainable development of society and the economy.The developmental dilemmas of infant and toddler care are discussed in depth from the family perspective, and solutions are proposed accordingly. By applying family systems theory and cultural capital theory to analyze the root causes and influencing factors of the problem, it provides useful thoughts and suggestions for improving infant and toddler care practices.

This paper is devoted to the determination of the dispersive component of the surface energy of two boron materials such as h-BN and BPO₄ surfaces by using the inverse gas chromatography (IGC) at infinite dilution. The specific interactions and Lewis’s acid-base parameters of these materials were calculated on the light of the new thermal model concerning the dependency of the surface area of organic molecules on the temperature, and by using also the classical methods of the inverse gas chromatography as well as the different molecular models such as Van der Waals, Redlich-Kwong, Kiselev, geometric, Gray, spherical, cylindrical and Hamieh models. It was proved that h-BN surface exhibits higher dispersive surface energy than BPO₄ material.

The specific properties of interaction of the two boron materials were determined. The results obtained by using the new thermal model taking into account the effect of the temperature on the surface area of molecules, proved that the classical IGC methods, gave inaccurate values of the specific parameters and Lewis’s acid base constants of the solid surfaces. The use of the thermal model allowed to conclude that h-BN surface has a Lewis basicity twice stronger than its acidity, whereas, BPO₄ surface presents an amphoteric character.

The work is devoted to the numerical solution of the initial boundary value problem for the heat equation with a fractional Riesz derivative. Explicit and implicit difference schemes are constructed that approximate the boundary value problem for the heat equation with a fractional Riesz derivative with respect to the coordinate. In the case of an explicit difference scheme, a condition is obtained for the time step at which the difference scheme converges. For an implicit difference scheme, a theorem on unconditional convergence is proved. An example of a numerical calculation using an implicit difference scheme is given. It has been established that when passing to a fractional derivative, the process of heat propagation slows down.

China's famous educator Mr. Tao Xingzhi once said that "education is the first, observation first", only scientific and effective observation can change the teachers' narrow understanding of kindergarten curriculum. From the observation record to the derived "Little Secrets in the Toilet" garden-based course, the original is just an ordinary life segment, become warm, have curriculum awareness. With an observational perspective, the teachers capture the interests and needs of the children in their lives, understand their experience levels, and provide valuable learning growth points. At the same time, in the activity, teachers reflect on their own educational content, organization mode and environment creation, and make dynamic adjustment and transformation, which promotes the development of children and improves teachers' leadership in the curriculum.

The cultivation of sugar beet (Beta vulgaris L.) for table or horticultural purposes is largely carried out in the conventional way which is characterized by intense mechanization causing soil degradation and high labor costs. New cultivation techniques are being employed in the production of vegetables aiming to ensure improvements in environmental and economic conditions, such as the no-till farming system. Thus, the objective of this work was to evaluate the vegetable classification and physicochemical characteristics of beets from different corn planting densities. The experiment was conducted in the period from October 2018 to June 2019 in the municipality of Nova Laranjeiras (PR). Corn was used as a cover plant and the vegetable used was beet cultivar Early Wonder Tall Top. The experimental design used was in interspersed blocks in unifactorial scheme (corn densities 40, 60, 80, 100 thousand plants/ha and control) with four blocks, with plots 3.60 m long and 1.20 m wide. The parameters evaluated 60 days after planting were: commercial classification (class, group, subgroup, category), length, diameter, mass, pulp firmness, soluble solids, titratable acidity, pH and ratio, phenolic compounds. Of which the variables that were not significant at 0.5 probability were length, category (defects), firmness, subgroup (flesh color), soluble solids and phenolic compounds. It is concluded that high densities of corn as mulch for SPDH of sugar beet crop negatively affect the grade and physicochemical characterization of the products.