Magnetic graphene oxide nanocomposites (M-GO) were successfully synthesized by partial reduction co-precipitation method and used for removal of Sr(II) and Cs(I) ions from aqueous solutions. The structures and properties of the M-GO was investigated by X-ray diffraction, Fourier transformed infrared spectroscopy, X-ray photoelectron spectroscopy, transmission electron microscopy, scanning electron microscopy, vibrating sample magnetometer (VSM) and N2-BET measurements. It is found that M-GO has 2.103 mg/g and 142.070 mg/g adsorption capacities for Sr(II) and Cs(I) ions, respectively. The adsorption isotherm matches well with the Freundlich for Sr(II) and Dubinin–Radushkevich model for Cs(I) and kinetic analysis suggests that the adsorption process is pseudo-second-ordered.
The cultivation of sugar beet (Beta vulgaris L.) for table or horticultural purposes is largely carried out in the conventional way which is characterized by intense mechanization causing soil degradation and high labor costs. New cultivation techniques are being employed in the production of vegetables aiming to ensure improvements in environmental and economic conditions, such as the no-till farming system. Thus, the objective of this work was to evaluate the vegetable classification and physicochemical characteristics of beets from different corn planting densities. The experiment was conducted in the period from October 2018 to June 2019 in the municipality of Nova Laranjeiras (PR). Corn was used as a cover plant and the vegetable used was beet cultivar Early Wonder Tall Top. The experimental design used was in interspersed blocks in unifactorial scheme (corn densities 40, 60, 80, 100 thousand plants/ha and control) with four blocks, with plots 3.60 m long and 1.20 m wide. The parameters evaluated 60 days after planting were: commercial classification (class, group, subgroup, category), length, diameter, mass, pulp firmness, soluble solids, titratable acidity, pH and ratio, phenolic compounds. Of which the variables that were not significant at 0.5 probability were length, category (defects), firmness, subgroup (flesh color), soluble solids and phenolic compounds. It is concluded that high densities of corn as mulch for SPDH of sugar beet crop negatively affect the grade and physicochemical characterization of the products.
Branched micro/nano Se was prepared by the redaction of L-Cys•HCl and H2SeO3 in hydrothermal method, as β-CD was used as soft template. The structures of products were characterized by SEM, TEM and XRD. Some important factors influencing the morphology of products were studied and discussed, including the amounts of soft template, the reaction temperature and the reaction time. The results showed that external causes had a potent effect on the morphology of micro/nano Se. The uniform branched micro/nano Se prepared under the optimal reaction condition was rhombohedral trigonal selenium t-Se0, but its crystallinity degree was low.
Among major global threats to papaya cultivation, papaya ringspot virus (PRSV) is the most challenging one. In the absence of any PRSV resistant commercial papaya cultivar, PRSV management is restricted to minimizing yield losses. ICAR-Indian Agricultural Research Institute, Regional Station, Pune has developed PRSV tolerant dioecious papaya lines, Pune Selection (PS)-1, PS-2, PS-3 and PS-5. Being dioecious these lines have limited acceptability among farmers. Gynodioecious population from these lines were developed and characterized. They are numbered PS-1-1, PS-2-1, PS-3-1 and PS-5-1. These lines were characterized against prevailing commercial gynodioecious cultivar, Red Lady, for five generations. The average plant height of PS-2-1 and PS-5-1 (183 cm) was more than Red Lady (158 cm), however, stem girth of all lines was lesser than Red Lady. The fruiting height of all lines was less than Red Lady (87 cm). Length of the fruiting column of all lines was more than Red Lady (37 cm), except in PS-1-1. Fruit yield of all lines was more than Red Lady (16 kg/plant). Intensity of PRSV infection in Red Lady (48%) was considerably more than all lines. These lines can be used for developing PRSV tolerant gynodioecious papaya variety.
In the present work, a series of butyl methacrylate/1-hexene copolymers were synthesized, and their efficiency as viscosity index improvers, pour point depressants, and shear stabilizers of lube oil was investigated. The effect of 1-hexene molar ratio, type, and concentration of Lewis acids on the incorporation of 1-hexene into the copolymer backbone was investigated. The successful synthesis of the copolymers was confirmed through FTIR and 1H NMR spectroscopy. Results obtained from quantitative 1H NMR and GPC revealed that an increase in the molar ratio of 1-hexene to butyl methacrylate, along with concentration of Lewis acids led to an increase in 1-hexene incorporation and a reduction in Mn and Ð. Similar trends were observed when the Lewis acid changed from AlCl3 to organometallic acids. The maximum 1-hexene incorporation (26.4%) was achieved for sample BHY3, with a [1-hexene/BMA] ratio of 4 mol% and a [Yb(OTf)3/BMA] ratio of 2.5 mol%. Evaluation of the synthesized copolymers as lube oil additives demonstrated that the viscosity index was more significantly influenced by samples with higher molecular weight. Sample BHA13 represents maximum VI of 137. The copolymer containing Yb(OTf)3 as a catalyst exhibited superior efficiency as a pour point depressant. Furthermore, sample BHY3 showed the lowest shear stability index (6.4).
Land suitability analysis using geographic information systems (GIS) is one of the most widely used method today. In this type of studies, GIS and geo-spatial statistical tools are used to evaluate land units and present the results in suitability maps. The present work aims to characterize the suitability of soils in the province of Catamarca for pecan nut production according to the variables: rockiness, salinity, risk of water-logging, depth, texture and drainage described in the Soil Map of Argentina at a scale of 1:500,000 published by the National Institute of Agricultural Technology. A classification of the suitability of the soil cartographic units was made according to crop requirements, applying the methodology proposed by FAO. The standardization of variables made by omega score and the calculation of the spatial classification score were carried out as a result of the synthesis of the spatial distribution of soil suitability. The applied methodology allowed obtaining the soil suitability map resulting in a total of 60,662 km2 suitable for pecan nut production, which accounts for 59.8% of the total area of the province.
Copyright © by EnPress Publisher. All rights reserved.