Research into electro-conductive textiles based on conductive polymers like polypyrrole has increased in recent years due to their high potential applications in various fields. Conductive polymers behave like insulators in their neutral states, with typical electrical conductivity in the range 10–10 to 10–25 Scm–1. These neutral polymers can be converted into semi-conductive or conductive states with conductivities ranging from 1 Scm–1 to 10–4 Scm–1 through chemical or electro-chemical redox reactions. By applying these polymers to a textile surface, we can obtain novel composites that are strong, flexible, lightweight, and highly electroconductive. These textile composites are suitable for applications such as heating pads, sensors, corrosion-protecting materials, actuators, electrochromic devices, EMI shielding, etc. The methods of application of conductive polymers onto the textile surface, such as in-situ chemical, in-situ electrochemical, in-situ vapor phase, in-situ polymerization in a supercritical fluid, and solution coating processes, are described here briefly. The merits and demerits of these methods are mentioned here. The reaction mechanisms of chemical and electrochemical polymerization proposed by the different researchers are described. Different factors affecting the kinetics of chemical and electrochemical polymerization are accounted for. The influence of textile materials on the kinetics of chemical polymerization is reviewed and reported.
For five different regions in Kırklareli province, heavy metals; such as Pb, Ni, Cu, Mn, Cd, Cr, Co, Zn, Mo, and Fe in the mixture of leaves and flowers from linden trees (Tilia tomentosa L.) were analyzed by using flame atomic absorption spectroscopy after the samples were dissolved with microwave method. Also, organochloride pesticides; such as ∑BHC: [α-BHC, β-BHC, γ-BHC, and δ-BHC], ∑DDT: [4,4’-DDD, 4,4’-DDE, and 4,4’-DDT], α-Endosulfan, β-Endosulfan, Endosulfan sulfate, Heptachlor, Heptachlor-endo-epoxide, Aldrin, Dieldrin, Endrin aldehyde, Endrin ketone, Endrin and Methoxychlor in these samples were determined by utilizing gas chromatography mass spectroscopy after the samples were prepared for analyses by using QuEChERS method. The metal concentrations in the samples were in the range of 45.3 to 268 mg/kg for Mn, 0.25 to 18.8 mg/kg for Cu, 11.5 to 46.1 mg/kg for Zn, 128 to 1310 mg/kg for Fe, 10.4 to 38.6 mg/kg for Mo, 0.82 to 1.34 mg/kg for Cd, 0 to 6.45 mg/kg for Ni, 0 to 19.2 mg/kg for Pb, and 0 to 8.25 mg/kg for Cr. Moreover, the concentrations of organochloride pesticides in samples were usually determined to be lower than their maximum residue level values given the pesticide residue limit regulation of Turkish Food Codex.
Soil and groundwater remediation Act was enacted in year 2000. More than ten years has already passed, Monitoring project has been completed,pollution status has been defined,contaminated sites depollution have been launched,a great progress has been made. This paper majorly to depict the extensive farmland soil qauality monittoring which is unpredent in Taiwan and believe has never been done worldwide.
This project was initiated from February 8th, 2002 to August 8th, 2002. The project tasks including digitalization of cadastre, farmland listing, basic information collecting, field investigation, sampling & analysis planning, field sampling, soil sample analysis, data evaluation, suggestion of contaminated farmland control, and analysis of potential pollution sources and transfer routes.
2,251 soil samples,had been sampled from Chang-Hwa County, Yun-Lin County, Nan-Tao County, and Chia-Yi City, and been analyzed in this project. 44% of these samples concentration exceed the soil pollution control standard (Table 1), including 492 farmlands (125.65 ha registered) with total contaminated farming area of 108.38 ha in Chang-Hwa, and 6 farmlands (0.39 ha registered) with total contaminated farming area of 0.39 ha in Nan-Tao County. However, the concentration of samples from Ynu-Lin County and Chia-Yi City do not exceed the soil pollution control standard.
To coordinate with the investigation results of the relative project regarding to water and sediment quality of irrigation channels in Chang-Hwa area, the pollution sources are preliminary concluded to be the irrigation channels surrounding the farmlands in Chang-Hwa area. As to the Nan-Tao County, the abandoned brick furnace plants neighboring the farmland are suspected to be the pollution sources.
The results show that the soil of the investigation area in Chang-Hwa County is the most polluted. Base on the Geostatistics study and the distribution of the irrigation channels; the area neighboring the investigated farmland in this project is suspected being polluted. For the farmlands exceeding soil control standard, Geostatistics method is suggested to coordinate with the information of the irrigation system to clarify the contaminated area so as to be the basis of land control and remediation work. As to the farmlands, not being investigated in this project but with high pollution potential according to the Geostatistics study, detail investigations are suggested. Regarding to soil pollution remediation, it is suggested to coordinate with the effluent control and irrigation channel remediation to achieve an all-out success.
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