The article aims at developing an efficient and stable catalysts for simultaneous hydrogenation of o-chloronitrobenzene to o-chloroaniline and 1,4-butanediol dehydrogenation to γ-butyrolactone. A series of CoO-Cu-MgO catalysts, composed of 10 wt% of copper, various amount of cobalt loadings (1, 5 and 10 wt%) and remaining of MgO were developed by co-precipitation followed by thermal treatment. o-Chloroaniline and γ-butyrolactone were the main products with high yield of 85% and 90%, respectively. The advantage of the coupling process is that the hydrogenation reaction was conducted without external hydrogen, demonstrating minimize the hydrogen consumption known as hydrogen economy route. From N₂O characterization results, the high activity of 5CoO-10Cu-MgO was found that it has high amount of Cu species (Cu⁰/Cu⁺¹) which govern the stable activity and selectivity on time on stream study in presence of cobalt in Cu-MgO.

This problem is a solar hut photovoltaic cell in the attached and overhead two installation methods, the type of photovoltaic cells and array mode and inverter type optimization design issues. In question 1, since the photovoltaic cells are attached to the roof and exterior surfaces, the direction and angle of the battery are uniquely determined by the direction and angle of the attached surface. The problem is translated to optimize the installation of a certain type on a single surface area (array) of photovoltaic cells, so that the total amount of solar photovoltaic power generation as much as possible, and the unit power generation costs as small as possible, which is a multi-objective optimization problem. The problem can be discussed in the ideal environment in a single surface area of the battery installation optimization program, and then the actual environment of the multi-surface optimization. In the solution to Problem 1, the unit on the south of the roof of the battery at the moment to accept the solar energy formula is generated. The definition of and is the moment of direct radiation intensity, for the moment the sun and the south of the roof of the plane where the angle, for the level of horizontal radiation intensity, for the south of the roof and the horizontal angle, the planefor the plane, the center of the heart, the vertical upward direction is the axis of the positive coordinate system, obtained with the sun height angle , the sun azimuth , red angle, angle and the sun when the relationship is generated. The conclusion is only installed in the small roof surface type of battery C11, and the rest of the surface is not installed. 35 years of electricity generation is 77126 degrees, the economic benefits of 16,488 yuan, the recovery period of 21.3 years. In question 2, because the photovoltaic cells in the roof and the external wall surface can be installed overhead, the panel orientation and tilt will affect the efficiency of photovoltaic cells. Therefore, in the optimization scheme of Problem 1, the orientation and inclination of the panel on each surface are further adjusted to calculate the optimum orientation and inclination of the panel on each surface. The problem can be in the ideal weather environment to establish the sun running and the battery board efficiency model, and then the measured environment test. The optimal orientation of the panel is southward, and the optimal angle with the ground plane is 39.89 degrees. The conclusion is only installed in the small roof surface type of battery C11, and the rest of the surface is not installed. 35 years of generating capacity of 82165.2 degrees, the economic benefits of 18,998 yuan, the recovery period of 13 years. In question 3, by the optimization of the above two issues, in the building to meet the requirements of the hut under the design of the various aspects of the cabin and battery installation, and further optimize the total power generation of the hut, economic benefits. The whole model solver is run in MATLAB7.0.

Stimuli-responsive, smart, or intelligent polymers are materials that significantly change their physical or chemical properties when there is a small change in the surrounding environment due to either internal or external stimuli. In the last two decades or so, there has been tremendous growth in the strategies to develop various types of stimuli-responsive polymer (SRP) materials/systems that are suitable for various fields, including biomedical, material science, nanotechnology, biotechnology, surface and colloid sciences, biochemistry, and the environmental field. The wide acceptability of SRPs is due to their availability in different architectural forms such as scaffolds, aggregates, hydrogels, pickering emulsions, core-shell particles, nanogels, micelles, membranes, capsules, and layer-by-layer films. The present review focuses on different types of SRPs, such as physical, chemical, and biological, and various important applications, including controlled drug delivery (CDD), stabilization of colloidal dispersion, diagnostics (sensors and imaging), tissue engineering, regenerative medicines, and actuators. The applications of SRPs have immense potential in various fields, and the author hopes these polymers will add a new field of applications through new concepts.

Financial shocks have an incredible socioeconomic effect on both developed and developing countries. Various recent studies demonstrated that bad public governance impacted public health across all nations. In fact, this study aims to use panel data for 21 countries from the Middle East and North Africa (MENA) region over the period 2000–2020 to scrutinize the effect of both governance and financial crises on public health. We use the generalized method of moments (GMM) approach to carry out the empirical analysis. The objective of using this method is to deal with the issue of endogeneity between exogen variables. Results outline that there is a significant positive association between public governance indicators and public health. Moreover, we found a strong negative association between financial shocks and public health. Thus, the direct negative impact of financial crisis on public health could be mitigated by the indirect positive impacts via institutions and good public governance. This study gives insights to policymakers to take appropriate measures to decrease the severity of the financial shocks and improve healthcare services.

Introduction: Growth, yield and quality of okra (Abelmoschus esculentus (L.) Moench) are related to fertilizer application, being nitrogen (N) the most outstanding, due to its direct relationship with photosynthesis and vegetative growth of the plant. Objective: The objective was to evaluate the agronomic and productivity characteristics of okra as a function of N dose. Materials and methods: The study was conducted at the experimental area of Campus Gurupi, the Universidad Federal de Tocantins (UFT), Brazil, in two planting periods (autumn/winter and spring/summer). The experimental design used was randomized block design (RBD) with six treatments (50, 100, 150, 150, 200 and 250 kg N ha^-1) and four replications. Urea was used as a source of N. The characteristics evaluated were: productivity, average fruit mass, height and plant chlorophyll index. Results: Productivity and plant height were superior in the fall/winter crop. Mean fruit mass and chlorophyll index were not influenced by planting time. For productivity, a linear response was obtained with increasing dose up to the limit of the N dose used (250 kg ha^-1), with a mean value higher than 14 t of fruit. Mean mass and plant height responded linearly to increasing N dose. Nitrogen affected the chlorophyll index, with maximum values of 45.96 and 47.19, observed in the two evaluation periods. Conclusion: Planting time and N content in the soil interacted with plant height, being favorable in the period without precipitation. N influenced all the characteristics, demonstrating the importance of nitrogen fertilization in the development of okra plants.

The use of plant viruses as bioherbicides represents a fascinating and promising frontier in modern agriculture and weed management. This review article delves into the multifaceted world of harnessing plant viruses for herbicidal purposes, shedding light on their potential as eco-friendly, sustainable alternatives to traditional chemical herbicides. We begin by exploring the diverse mechanisms through which plant viruses can target and control weeds, from altering gene expression to disrupting essential physiological processes. The article highlights the advantages of utilizing plant viruses, such as their specificity for weed species, minimal impact on non-target plants, and a reduced environmental footprint. Furthermore, we investigate the remarkable versatility of plant viruses, showcasing their adaptability to various weed species and agricultural environments. The review delves into the latest advancements in genetic modification techniques, which enable the engineering of plant viruses for enhanced herbicidal properties and safety. In addition to their efficacy, we discuss the economic and ecological advantages of using plant viruses as bioherbicides, emphasizing their potential to reduce chemical herbicide usage and decrease the development of herbicide-resistant weeds. We also address the regulatory and safety considerations associated with the application of plant viruses in agriculture. Ultimately, this review article underscores the immense potential of plant viruses as bioherbicides and calls for further research, development, and responsible deployment to harness these microscopic agents in the ongoing quest for sustainable and environmentally friendly weed management strategies.