An α, α^′-dipyridyl adduct of a complex compound hexaaquatribenzene-1,2,4,5-tetracarbonatotetra iron (III) with porous structure was synthesized for the first time. According to the results of elemental, X-ray, IR-spectroscopic and differential-thermal analyses the individuality, chemical formula, thermal destruction, and form of coordination of acidic anion and dipyridyl were established. During interaction of a complex compound with dipyridyl, it completely loses all crystallization molecule of water resulting in a compound with a chemical formula of Fe₄(C₆H₂(COO)₄)₃(dpy)₂(dipyridyl). Using the identification of diffraction pattern the parameters of lattice cell of the complex compound were determined.

This article concerns  with  the  construction of the  analytical traveling  wave so- lutions  for the Generalized-Zakharov System  by the Riccati-Bernoulli Sub- ODE technique. Also, we will discuss this  technique  in random  case by using random  traveling  wave trans- formation  in order  to  find what  is the  effect of the  randomness  input  for this  technique. We presented the Generalized-Zakharov System as an example to show the difference effect between the deterministic and stochastic Riccati-Bernoulli Sub-ODE technique.  The first moment of random solution is computed for different statistical probability distributions.

Climate and vegetation are variables of the physical space that have a dynamic and interdependent relationship. Flora modifies climatic elements and gives rise to a microclimate whose characterization is a function of regional climatic conditions and vegetation structure. The objective of this work was to compare the climatic variations (inside and outside) of the Caldén Forest in the Parque Luro Provincial Reserve. Temperature, relative humidity, wind speed, wind direction and precipitation data from two meteorological stations for 2012 were analyzed and statistically compared. The influence of the forest on climatic parameters was demonstrated and it was found that the greatest variations were in wind speed, daily temperature and precipitation.

With the deep integration of artificial intelligence technology in education, the development of AI integration capabilities among pre-service teachers—as the core of future educational human resources—has become crucial for enhancing educational quality and driving digital transformation in education. Based on the AI-TPACK (Artificial Intelligence-Technological Pedagogical Content Knowledge) theoretical framework, this study employs questionnaire surveys and structural equation modeling to explore the structural characteristics, influencing factors, and formation mechanisms of AI-TPACK competencies among pre-service teachers in Chinese universities. Findings indicate that while pre-service teachers demonstrate moderately high overall AI-TPACK levels, their technical knowledge (AI-TK) and technological integration competencies (e.g., AI-TPK, AI-TCK) remain relatively weak. School technical support, technological attitudes, and technological competence significantly influence their AI-TPACK capabilities, with institutional level and teaching experience serving as important external moderating factors. Building on these findings, this paper proposes a systematic framework for developing pre-service teachers' AI integration capabilities from a human resource development perspective. This framework encompasses four dimensions: curriculum optimization, practice enhancement, resource support, and policy guidance. It aims to provide theoretical foundations and practical pathways for pre-service teacher training and teacher human resource development in higher education institutions.

Google Earth images in the Marche Region of Central Italy revealed a circular structure consisting of a ring system made up of concentric hills and valleys. Cartography, DEM, geological, and available geophysical data were used to constrain the possible origin of the structure. Located in the Messinian foredeep deposits of the Central Apennines, it has a rim diameter of 3.75 km and a central uplift connected to its southernmost part. As it was formed in the clays of the Lower Pliocene, and clays are believed to have emerged definitively after the Upper Pliocene, its age might be constrained to the Lower Pleistocene. Similar concentric structures are usually found in impact craters, sedimentary domes, and volcanic landforms. As salt domes and magmatic activity are not found in this region, this study seeks to validate the results of previous work that it was the result of an ancient impact crater of hydrological, brachyanticline, or clayey diapiric origins. Specifically, an observed second ring portion with a curvature radius about double the first in size will be investigated in this work. This second ring portion appears to be concentric to the first one and is visible along its northern and western parts. Although double concentric rings are usually due to impact craters, the absence of the ring portion in the other two directions and the probable deviation of a river, deduced by studying hydrography, support the hypothesis that it might be of clay diapir origin.