Four alloys based on niobium and containing about 33wt.%Cr, 0.4wt.C and, in atomic content equivalent to the carbon one, Ta, Ti, Hf or Zr, were elaborated by classical foundry under inert atmosphere. Their as-cast microstructures were characterized by X-ray diffraction, electron microscopy, energy dispersion spectrometry and while their room temperature hardness was specified by Vickers indentation. The microstructures are in the four cases composed of a dendritic Nb-based solid solution and of an interdendritic NbCr₂ Laves phase. Despite the MC-former behavior of Ta, Ti, Hf and Zr usually observed in nickel or cobalt-based alloys, none of the four alloys contain MC carbides. Carbon is essentially visible as graphite flakes. These alloys are brittle at room temperature and hard to machine. Indentation shows that the Vickers hardness is very high, close to 1000HV_10kg. Indentation lead to crack propagation through the niobium phase and the Laves areas. Obviously no niobium-based alloys microstructurally similar to high performance MC-strengthened nickel-based and cobalt-based can be expected. However the high temperature mechanical and chemical properties of these alloys remain to be investigated.

Deficiencies in postharvest technology and the attack of phytopathogens cause horticultural products, such as tomatoes to have a very short shelf life. In addition to the economic damage, this can also have negative effects on health and the environment. The objective of this work is to evaluate an active coating of sodium alginate in combination with eugenol-loaded polymeric nanocapsules (AL-NP-EUG) to improve the shelf life of tomato. Using the nanoprecipitation technique, NPs with a size of 171 nm, a polydispersity index of 0.113 and a zeta potential of −2.47 mV were obtained. Using the HS-SPME technique with GC-FID, an encapsulation efficiency percentage of 31.85% was determined for EUG. The shelf-life study showed that the AL-NP-EUG-treated tomatoes maintained firmness longer than those without the coating. In addition, the pathogenicity test showed that tomatoes with AL-NP-EUG showed no signs of damage caused by the phytopathogen Colletotrichum gloesporoides. It was concluded that the formulation of EUG nanoencapsulated and incorporated into the edible coating presents high potential for its application as a natural nanoconservative of fruit and vegetable products such as tomato.

The cultivation of sugar beet (Beta vulgaris L.) for table or horticultural purposes is largely carried out in the conventional way which is characterized by intense mechanization causing soil degradation and high labor costs. New cultivation techniques are being employed in the production of vegetables aiming to ensure improvements in environmental and economic conditions, such as the no-till farming system. Thus, the objective of this work was to evaluate the vegetable classification and physicochemical characteristics of beets from different corn planting densities. The experiment was conducted in the period from October 2018 to June 2019 in the municipality of Nova Laranjeiras (PR). Corn was used as a cover plant and the vegetable used was beet cultivar Early Wonder Tall Top. The experimental design used was in interspersed blocks in unifactorial scheme (corn densities 40, 60, 80, 100 thousand plants/ha and control) with four blocks, with plots 3.60 m long and 1.20 m wide. The parameters evaluated 60 days after planting were: commercial classification (class, group, subgroup, category), length, diameter, mass, pulp firmness, soluble solids, titratable acidity, pH and ratio, phenolic compounds. Of which the variables that were not significant at 0.5 probability were length, category (defects), firmness, subgroup (flesh color), soluble solids and phenolic compounds. It is concluded that high densities of corn as mulch for SPDH of sugar beet crop negatively affect the grade and physicochemical characterization of the products.

In this study, the influence of sewage sludge ash (SSA) waste particle contents on the mechanical properties and interlaminar fracture toughness for mode I and mode II delamination of S-glass fiber-reinforced epoxy composites was investigated. Composite laminate specimens for tensile, flexural double-cantilever beam (DCB), and end-notched fracture (ENF) tests were prepared and tested according to ASTM standards with 5, 10, 15, and 20 wt% SSA-filled S-glass/epoxy composites. Property improvement reasons were explained based on optical and scanning electron microscopy. The highest improvement in tensile and flexural strength was obtained with a 10 wt% content of SSA. The highest mode I and mode II interlaminar fracture toughness’s were obtained with 15 wt% content of SSA. The mode I and mode II interlaminar fracture toughness improved by 33% and 63.6%, respectively, compared to the composite without SSA.