In this paper, electrically conductive composites comprised of silicone rubber and titanium diboride (TiB2) were synthesized by conventional mixing methods. Fine particles of TiB2 (in micron size) and 10 parts per hundred parts of rubber (phr) proportion of carbon black (XC-72) were used to make the composites with HTV silicone rubber. The composites were cured at appropriate temperature and pressure and the effect on the electrical properties was studied. The resistance of the silicone rubber is ~ 1015Ω which decreases to 1–2 kΩ in case of composites with negligible effect of heat ageing. The hardness increases by ~ 35% simultaneous to the decrease of ~ 47% in the tensile strength. Morphological characterization indicates the homogeneous dispersion of the fillers in the composite.
Nanocomposites are high performance materials which reveal rare properties. Nanocomposites have an estimated annual growth rate of 25% and fastest demand to be in engineering plastics and elastomers. Their prospective is so prominent that they are valuable in numerous areas ranging from packaging to biomedical applications. In this review, the various types of matrix nanocomposites are discussed highlighting the need for these materials, their processing approaches and some recent results on structure, properties and potential applications. Perspectives include need for such future materials and other interesting applications. Being environmentally friendly, applications of nanocomposites propose new technology and business opportunities for several sectors of the aerospace, automotive, electronics and biotechnology industries.
In this study, the influence of sewage sludge ash (SSA) waste particle contents on the mechanical properties and interlaminar fracture toughness for mode I and mode II delamination of S-glass fiber-reinforced epoxy composites was investigated. Composite laminate specimens for tensile, flexural double-cantilever beam (DCB), and end-notched fracture (ENF) tests were prepared and tested according to ASTM standards with 5, 10, 15, and 20 wt% SSA-filled S-glass/epoxy composites. Property improvement reasons were explained based on optical and scanning electron microscopy. The highest improvement in tensile and flexural strength was obtained with a 10 wt% content of SSA. The highest mode I and mode II interlaminar fracture toughness’s were obtained with 15 wt% content of SSA. The mode I and mode II interlaminar fracture toughness improved by 33% and 63.6%, respectively, compared to the composite without SSA.
The nylon 66/nano-CaCO3 composites were prepared by melt blending on a twin-screw extruder. Scanning electron microscopy (SEM), polarized light microscopy (PLM), thermal loss (TGA) and differential scanning calorimetry (DSC) The effects of nanometer calcium carbonate on the polycrystalline behavior and thermal properties of nylon 66/nano CaCO3 composites were investigated. The results show that the nanometer calcium carbonate particles are dispersed in the nylon 66 matrix and exist in the form of aggregates. The nanometer calcium carbonate has the effect of heterogeneous nucleation, which can reduce the size of the spherules. The decomposition temperature of the nylon 66 is 400 ℃, the addition of nano-CaCO3 to reduce the decomposition temperature. At the same time, DSC test showed that the β-crystalline form in the material reduced the melting temperature of the material. The addition of nano-CaCO3 in the nylon 66 matrix resulted in the decrease of the crystallization temperature and the increase of the half-height width of the endothermic peak. The lower the crystallization temperature, the wider the crystallization temperature range.
This work investigates epoxy composites reinforced by randomly oriented, short glass fibres and silica microparticles. A full-factorial experiment evaluates the effects of glass fibre mass fraction (15 wt% and 20 wt%) and length (5 mm and 10 mm), and the mass fraction of silica microparticles (5 wt% and 10 wt%) on the apparent density and porosity, as well as the compressive and tensile strength and modulus of the hybrid composites. Hybrid epoxy composites present significantly higher tensile strength (9%) and modulus (57%), as well as compressive strength (up to 15%) relative to pure epoxy.
This research implements sustainable environmental practices by repurposing post-industrial plastic waste as an alternative material for non-conventional construction systems. Focusing on the development of a recycled polymer matrix, the study produces panels suitable for masonry applications based on tensile and compressive stress performance. The project, conducted in Portoviejo and Medellín, comprises three phases combining bibliographic and experimental research. Low-density polyethylene (LDPE), high-density polyethylene (HDPE), and polypropylene (PP) were processed under controlled temperatures to form a composite matrix. This material demonstrates versatile applications upon cooling—including planks, blocks, caps, signage, and furniture (e.g., chairs). Key findings indicate optimal performance of the recycled thermoplastic polymer matrix at a 1:1:1 ratio of LDPE, HDPE, and PP, exhibiting 15% deformation. The proposed implementation features 50 × 10 × 7 cm panels designed with tongue-and-groove joints. When assembled into larger plates, these panels function effectively as masonry for housing construction, wall cladding, or lightweight fill material for slab relieving.
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