Due to rising global environmental challenges, air/water pollution treatment technologies, especially membrane techniques, have been focused on. In this context, air or purification membranes have been considered effective for environmental remediation. In the field of polymeric membranes, high-performance polymer/graphene nanocomposite membranes have gained increasing research attention. The polymer/graphene nanomaterials exposed several potential benefits when processed as membranes. This review explains the utilization of polymer and graphene-derived nanocomposites towards membrane formation and water or gas separation or decontamination properties. Here, different membrane designs have been developed depending upon the polymer types (poly(vinyl alcohol), poly(vinyl chloride), poly(dimethyl siloxane), polysulfone, poly(methyl methacrylate), etc.) and graphene functionalities. Including graphene in polymers influences membrane microstructure, physical features, molecular permeability or selectivity, and separations. Polysulfone/graphene oxide nanocomposite membranes have been found to be most efficient with an enhanced rejection rate of 90%–95%, a high water flux >180 L/m2/h, and a desirable water contact angle for water purification purposes. For gas separation membranes, efficient membranes have been reported as polysulfone/graphene oxide and poly(dimethyl siloxane)/graphene oxide nanocomposites. In these membranes, N2, CO2, and other gases permeability has been found to be higher than even >99.9%. Similarly, higher selectivity values for gases like CO2/CH4 have been observed. Thus, high-performance graphene-based nanocomposite membranes possess high potential to overcome the challenges related to water or gas molecular separations.
The chemical reinforcement of sandy soils is usually carried out to improve their properties and meet specific engineering requirements. Nevertheless, conventional reinforcement agents are often expensive; the process is energy-intensive and causes serious environmental issues. Therefore, developing a cost-effective, room-temperature-based method that uses recyclable chemicals is necessary. In the current study, poly (styrene-co-methyl methacrylate) (PS-PMMA) is used as a stabilizer to reinforce sandy soil. The copolymer-reinforced sand samples were prepared using the one-step bulk polymerization method at room temperature. The mechanical strength of the copolymer-reinforced sand samples depends on the ratio of the PS-PMMA copolymer to the sand. The higher the copolymer-to-sand ratio, the higher the sample’s compressive strength. The sand (70 wt.%)-PS-PMMA (30 wt.%) sample exhibited the highest compressive strength of 1900 psi. The copolymer matrix enwraps the sand particles to form a stable structure with high compressive strengths.
Researchers from all over the world have been working tirelessly to combat the severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) COVID-19 pandemic since the World Health Organization (WHO) proclaimed it to be a pandemic in 2019. Expanding testing capacities, creating efficient medications, and creating safe and efficient COVID-19 (SARS CoV-2) vaccinations that provide the human body with long-lasting protection are a few tactics that need to be investigated. In clinical studies, drug delivery techniques, including nanoparticles, have been used since the early 1990s. Since then, as technology has advanced and the need for improved medication delivery has increased, the field of nanomedicine has recently seen significant development. PNPs, or polymeric nanoparticles, are solid particles or particulate dispersions that range in size from 10 to 1000 nm, and their ability to efficiently deliver therapeutics to specific targets makes them ideal drug carriers. This review article discusses the many polymeric nanoparticle (PNP) platforms developed to counteract the recent COVID-19 pandemic-related severe acute respiratory syndrome coronavirus (SARS-CoV-2). The primary subjects of this article are the size, shape, cytotoxicity, and release mechanism of each nanoparticle. The two kinds of preparation methods in the synthesis of polymeric nanoparticles have been discussed: the first group uses premade polymers, while the other group depends on the direct polymerization of monomers. A few of the PNPs that have been utilized to combat previous viral outbreaks against SARS-CoV-2 are also covered.
Water pollution has become a serious threat to our ecosystem. Water contamination due to human, commercial, and industrial activities has negatively affected the whole world. Owing to the global demanding challenges of water pollution treatments and achieving sustainability, membrane technology has gained increasing research attention. Although numerous membrane materials have focused, the sustainable water purification membranes are most effective for environmental needs. In this regard sustainable, green, and recyclable polymeric and nanocomposite membranes have been developed. Materials fulfilling sustainable environmental demands usually include wide-ranging polyesters, polyamides, polysulfones, and recyclable/biodegradable petroleum polymers plus non-toxic solvents. Consequently, water purification membranes for nanofiltration, microfiltration, reverse osmosis, ultrafiltration, and related filtration processes have been designed. Sustainable polymer membranes for water purification have been manufactured using facile techniques. The resulting membranes have been tested for desalination, dye removal, ion separation, and antibacterial processes for wastewater. Environmental sustainability studies have also pointed towards desired life cycle assessment results for these water purification membranes. Recycling of water treatment membranes have been performed by three major processes mechanical recycling, chemical recycling, or thermal recycling. Moreover, use of sustainable membranes has caused positive environmental impacts for safe waste water treatment. Importantly, worth of sustainable water purification membranes has been analyzed for the environmentally friendly water purification applications. There is vast scope of developing and investigating water purification membranes using countless sustainable polymers, materials, and nanomaterials. Hence, value of sustainable membranes has been analyzed to meet the global demands and challenges to attain future clean water and ecosystem.
This review comprehensively summarizes various preparatory methods of polymeric bone scaffolds using conventional and modern advanced methods. Compilations of the various fabrication techniques, specific composition, and the corresponding properties obtained under clearly identified conditions are presented in the commercial formulations of bone scaffolds in current orthopedic use. The gaps and unresolved questions in the existing database, efforts that should be made to address these issues, and research directions are also covered. Polymers are unique synthetic materials primarily used for bone and scaffold applications. Bone scaffolds based on acrylic polymers have been widely used in orthopedic surgery for years. Polymethyl methacrylate (PMMA) is especially known for its widespread applications in bone repair and dental fields. In addition, the PMMA polymers are suitable for carrying antibiotics and for their sustainable release at the site of infection.
This review summarizes some of the recent advances related to shallow penetration conformance sealants (SPCS) based on cross-linked polymer nanocomposite gels. The cross-linked polymer nanocomposite gels formed a three-dimensional (3D) gel structure upon contact with either water or oil when placed at the downhole. Therefore, the cross-linked polymer nanocomposite gels offer a total or partial water shutoff. Numerous polymeric gels and their nanocomposites prepared using various techniques have been explored to address the conformance problems. Nevertheless, their instability at high temperature, high pressure, and high salinity down-hole conditions (HT-HP-HS) often makes the treatments unsuccessful. Incorporating inert particles into the cross-linked polymer nanocomposite gel matrices improves stability under harsh down-hole conditions. This review discusses potential polymeric nanocomposite gels and their successful application in conformance control.
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