Work is reported on thermal-induced redshifts of quantum particle plasmon. The redshifts are predicted to be caused indirectly by the quantum size effects. The particles are enlarged when temperature increases, and consequently, quantum size effects modify the plasmon but not the band structure. It has been modeled for metallic quantum particles. The results are also instructive to other quantum systems, such as complex molecules. Every electron inside the quantum particle is taken into account. Tiny quantum size effects are harvested, and the redshift becomes significant. Experimental evidence is also given for the spectral redshift. Faujasite zeolites were synthesized. Optical spectroscopy has been carried out, and the resulting spectra showed a significant redshift with the increase in temperature.

The rare earth mining area in South China is the main production base of ionic rare earth in the world, which has brought inestimable economic value to the local area and even the whole nation. However, due to the lack of mining technology and excessive pursuit for economic profits, a series of environmental problems have arisen, which is a great threat to the ecosystem of the mining area. Taking Lingbei rare earth mining area in Ganzhou as an example, this paper discriminated and analyzed such aspects as the ecological source, ecological corridor and ecological nodes of the mining area based on the landscape ecological security pattern theory and the minimum cumulative resistance model (MCR) method, and constructed a landscape ecological security pattern of the mining area during the 2009, 2013 and 2018. The results show that: i) The patch area of the ecological source of rare earth mining area is small, mainly concentrated in the east and west sides of the mining area. ii) During the selected year, the ecological source area, ecological corridors, radiation channels and the number of ecological nodes in the rare earth mining area are increasing, indicating that the landscape ecological security of the rare earth mining area has been improved to some extent, but it remains necessary for relevant departments to make a optimized planning to further reconstruct the ecological security pattern of the rare earth mining area.

Under the developing trend of artificial intelligence (AI) technology gradually penetrating all aspects of society, the traditional language education industry is also greatly affected ^[1]. AI technology has had a positive impact on college English teaching, but it also presents challenges and negative impacts. On the positive side, AI technology can provide personalized learning experiences, real-time feedback, and autonomous learning opportunities, and so on. However, it may also lead to a lack of communication between students and humans, resulting in a decline in students’ interpersonal skills, and cause students’ dependence on online learning resources as well as possible risks to student data privacy and security, and other negative impacts. To address these challenges, teachers can adopt the following countermeasures: improving teachers’ skills in the use of AI technology incorporated in the classroom, offering personalized instruction to reduce students’ dependence on AI technologies, emphasizing the cultivation of students’ humanistic literacy and interpersonal communication ability. Additionally, colleges and technology providers should strengthen data security and privacy protection to ensure the safety and confidentiality of student data. By implementing comprehensive measures, we can maximize the advantages of AI technology in college English teaching while overcoming potential issues and challenges.

Artificial intelligence has transformed teachers’ teaching models. This article explores the application of artificial intelligence in basic education in Macao middle schools. This study adopts case analysis in qualitative research, using a total of eight cases from the innovative technology education platform of the Macau education and Youth Development Bureau. These data illustrate how Macao’s artificial intelligence technology promotes teaching innovation in basic education. These eight cases are closely related to the application of artificial intelligence in basic education in Macao. The survey results show that Macao’s education policy has a positive effect on teaching innovation in artificial intelligence education. In teaching practice, the school also cooperates with the government’s policy. The application of AI technology in teaching, students’ learning styles, changes in teachers’ roles, and new needs for teacher training are all influential.

Public-private partnerships (PPPs) were established in Brazil at the beginning of this century, following a global trend of using these partnerships to stimulate investment in infrastructures, particularly in a framework of restrictive budgetary and fiscal conditions. Despite their growing importance and the expectation of an expanding role in the future, not much is known about the actual facts on the ground. The objective of this paper is to be a first step in the direction of filling this information gap by providing important stylized facts about the universe of PPPs in Brazil: the quantitative evolution of PPP adoptions; the characterization of the geographical distribution of PPPs by government level (federal, state, district, and municipal); the characterization of the PPP intervention areas, including the total value of contracts and the modalities of PPP concession (sponsored and administrative). This objective is rendered possible by the development of a new database that covers the entire process of PPP contracting from 2005 to 2022, including the opening of public consultation procedures, the publication of the official notice, and the signing of contracts, as well as multiple thematic, financial, jurisdictional, and regional indicators. In turn, we see the establishment of these stylized facts as a necessary first step in the direction of understanding the factors that may determine or condition their adoption. In general, having a clear picture of the universe of the PPPs in Brazil is fundamental as their use and their role are expected to significantly increase in the future as the country pursues a path of improved economic activity and well-being of the population.

During his 22-year rule, Turkey’s populist leader Erdoğan not only ensured his control of mainstream media ownership, but he also aligned the language and style of these media with his own populist politics. This investigation presents a unique perspective by highlighting the AKP’s establishment of a network of loyal media outlets and business individuals through crony capitalism while also demonstrating that the party garnered loyalty from religious foundations, and the urban poor due to the aid and financial support provided by AKP municipalities. The primary objective of this research is to offer a distinct scholarly contribution by analyzing the influence of crony capitalism and welfare policies within the context of populist politics. This study employed a methodology centered around network graphs designed to reveal connections between the AKP, various media outlets, and associations and foundations, thereby highlighting the AKP’s association with key actors involved in the establishment of a neoliberal-conservative hegemony.