The importance of improving industrial transformation processes for more efficient ones is part of the current challenges. Specifically, the development of more efficient processes in the production of biofuels, where the reaction and separation processes can be intensified, is of great interest to reduce the energy consumption associated with the process. In the case of Biodiesel, the process is defined by a chemical reaction and by the components associated to the process, where the thermochemical study seeks to develop calculations for the subsequent understanding of the reaction and purification process. Thus, the analysis of the mixture of the components using the process simulator Aspen Plus V9^® unravels the thermochemical study. The UNIFAC-DMD thermodynamic method was used to estimate the binary equilibrium parameters of the reagents using the simulator. The analyzed aspects present the behavior of the components in different temperature conditions, the azeotropic behavior and the determined thermochemical conditions.

The study examined the socio-demographic factors affecting access to and utilization of social welfare services in Yenagoa Local Government Area of Bayelsa State, Nigeria. Quantitative and qualitative approaches were adopted to select 570 respondents from the study area. Probability and non-probability sampling techniques were adopted in the selection of communities, and respondents. The quantitative data were analyzed using frequency distribution tables and percentages, while chi-square statistic was used to determine the relationship between socio-demographic variables and access to and utilization of social welfare services. The qualitative data were analyzed in themes as a complement to the quantitative data. This study reveals that although all the respondents reported knowing available social welfare services, 44.3% reported not having access to existing social services due to factors connected to serendipity variables, such as terrain condition, ethnicity and knowing someone in government. Therefore, the study recommends that the government and other stakeholders should push for the massive delivery of much-needed social welfare services to address the issue of welfare service deficit across the nation, irrespective of the ethnic group and whether the community is connected to the government of the day or not, primarily in rural areas.

Using matricant method elastic moduli of occasionally heterogeneous isotropic and anisotropic elastic media were received. Anisotropic behaviour and conditions for change in anisotropy of media associated with averaging of one-dimensional periodic structures was determined.

The boom in nanotechnology over the last three decades is undeniable. Responsible for this interest in nanomaterials are mainly the nanostructured forms of carbon, since historically they were the ones that inaugurated the study of nanomaterials with the discovery of fullerenes in 1985 and carbon nanotubes in 1991. Although a variety of techniques exist to produce these materials, chemical vapor deposition (CVD) is particularly valuable as it allows the production of a wide variety of carbon nanostructures, is versatile, scalable, easy to implement and relatively low cost. This review article highlights the importance of CVD and details its principles, operating conditions and parameters, as well as its main variants. A description of the technique used to produce fullerenes, nano-ceramics, carbon nanotubes, nanospheres, graphene and others is made, emphasizing the specific parameters for each synthesis.

Introduction: The selection of genotypes with determinate growth habit in tomato should contemplate adequate selection criteria to increase the efficiency of the breeding program. Objective: The objective of this work was to estimate selection criteria for “chonto” type tomato lines with determined growth habit. Materials and methods: This work was carried out at the Universidad Nacional de Colombia (Palmira Campus), in 2016, with seven lines with determinate growth habit and a control with indeterminate growth. Heritability in a broad sense (h² g), coefficient of environmental variation, coefficient of genetic variation, selection efficiency and genetic gain were determined in parameters of morphological, phonological, fruit quality, fruit shape and production, using the RELM/BLUP procedure of the SELEGEN software. Results: There were three ranges of h² g, the first with values of h² g greater than 0.76, the second between 0.53 and 0.38, and the third with a value less than 0.38. The highest values of h² g were for final plant height with 0.92, plant height at harvest with 0.88, yield per plant with 0.83, days to flowering with 0.83, number of fruits per plant with 0.82, and days to harvest with 0.82. For genetic gain it was found that the control had the highest values for final plant height, plant height at harvest, internode length, days to harvest, harvest duration, soluble solids content, number of fruits per plant, fruit weight and yield per plant; however, in some parameters such as height and phenology for selection by determined growth habit, the lowest values were better. Conclusion: There was evidence of genetic parameters that could be considered as selection criteria for “chonto” type tomato lines with determinate growth habit.

The article aims at developing an efficient and stable catalysts for simultaneous hydrogenation of o-chloronitrobenzene to o-chloroaniline and 1,4-butanediol dehydrogenation to γ-butyrolactone. A series of CoO-Cu-MgO catalysts, composed of 10 wt% of copper, various amount of cobalt loadings (1, 5 and 10 wt%) and remaining of MgO were developed by co-precipitation followed by thermal treatment. o-Chloroaniline and γ-butyrolactone were the main products with high yield of 85% and 90%, respectively. The advantage of the coupling process is that the hydrogenation reaction was conducted without external hydrogen, demonstrating minimize the hydrogen consumption known as hydrogen economy route. From N₂O characterization results, the high activity of 5CoO-10Cu-MgO was found that it has high amount of Cu species (Cu⁰/Cu⁺¹) which govern the stable activity and selectivity on time on stream study in presence of cobalt in Cu-MgO.