The relationship between transport infrastructure and accessibility has long stood as a central research area in regional and transport economics. Often invoked by governments to justify large public spending on infrastructure, the study of this relationship has led to conflicting arguments on the role that transport plays in productivity. This paper expands the existing body of knowledge by adopting a spatial analysis (with spillover effects) that considers the physical effects of investment in terms of accessibility (using distinct metrics). The authors have used the Portuguese experience at regional level over the last 30 years as a case study. The main conclusions are as follows: i) the choice of transport variables matters when explaining productivity, and more complex accessibility indicators are more correlated with; ii) it is important to account for spill-over effects; and iii) the evidence of granger causality is not widespread but depends on the regions.

The effects of different storage temperatures (2, 4 and 8 ℃) and their corresponding optimal heat treatment conditions on the quality, physiological and biochemical indexes of Cucumber Fruits during storage were studied by using the quadratic regression orthogonal rotation combination design. The effects of different storage temperatures (2, 4 and 8 ℃) and their corresponding optimal heat treatment conditions on the chilling injury, hardness, weightlessness rate, polyphenol oxidase (PPO), catalase (CAT), peroxidase (POD), H₂O₂, super oxygen anion free radical (O^2-), ASA and GSH were determined. The results showed that heat treatment could inhibit chilling injury, while heat treatment combined with 4 ℃ low temperature storage could effectively inhibit the decline of fruit hardness and weight loss rate, delay the increase of peroxidase (POD) and polyphenol oxidase (PPO) activities, inhibit the increase of H₂O₂ and superoxide anion free radical O^2- and significantly inhibit the browning of cucumber, delay the decline of ascorbic acid and maintain the content of GSH, it was beneficial to adjust the balance of active oxygen system. The results showed that under the storage condition of 4 ℃, the hot water treatment condition of cucumber was 39.4 ℃ and 24.3 min, which could delay the senescence of cucumber fruit and better maintain the quality of cucumber fruit.

This study focused on the formulation and characterization of silver nanoparticles (AgNP) functionalized with d-limonene. The nanoparticles were functionalized by phase inversion and the synthesis of the nanoparticles was performed in situ; particle size was determined by laser diffraction, zeta potential and optical colloidal stability using Multiscan 20 for a period of 24 hours at 37 °C; the minimum inhibitory concentration (MIC) and minimum bactericidal concentration (MBC) of the formulated material on Escherichia coli ATCC 25922, Staphylococcus aureus ATCC 29213, Klebsiella oxytoca ATCC 700324, Enterococcus casseliflavus ATCC 700327, Escherichia coli BLEE, carbapenem-resistant Pseudomona aeruginosa were determined. The nanoparticles showed colloidal stability at a d-limonene concentration of 3.93%, silver ions at 1.61 × 10⁻³%, non-ionic adjuvant at 24% and ascorbic acid at 5.88%; citric acid/citrate (1:1) 0.48M for a pH of 4.5 was used as a buffer system. The formulation was classified as a polydisperse system (PD = 0.0851), with a zeta potential of −11.6 mV and average particle size of 81.5 ± 0.9 nm. A particle migration velocity of −0.199 ± 0.006 mm∙h⁻¹, a constant transmission profile and backscattering profile with variations of 10% were evidenced, which represents a stable formulation. The nanoparticles presented an MIC and an MBC of 28 μg∙mL⁻¹ (5.6 × 10⁻²% d-limonene and 4.7 × 10⁻⁵% AgNP) against all tested bacteria.

Forest fire, as a discontinuous ecological factor of forest, causes the changes of carbon storage and carbon distribution in forest ecosystem, and affects the process of forest succession and national carbon capacity. Taking the burned land with different forest fire interference intensity as the research object, using the comparison method of adjacent sample plots, and taking the combination of field investigation sampling and indoor test analysis as the main means, this paper studies the influence of different forest fire interference intensity on the carbon pool of forest ecosystem and the change and spatial distribution pattern of ecosystem carbon density, and discusses the influence mechanism of forest fire interference on ecosystem carbon density and distribution pattern. The results showed that forest fire disturbance reduced the carbon density of vegetation (P < 0.05). The carbon density of vegetation in the light, moderate and high forest fire disturbance sample plots were 67.88, 35.68 and 15.50 t∙hm^-2, which decreased by 15.86%, 55.78% and 80.79% respectively compared with the control group. In the light, moderate and high forest fire disturbance sample plots, the carbon density of litter was 1.43, 0.94 and 0.81 t∙hm^-2, which decreased by 28.14%, 52.76% and 59.30% respectively compared with the control group. The soil organic carbon density of the sample plots with different forest fire disturbance intensity is lower than that of the control group, and the reduction degree gradually decreases with the increase of soil profile depth. The soil organic carbon density of the sample plots with light, moderate and high forest fire disturbance is 103.30, 84.33 and 70.04 t∙hm^-2 respectively, which is 11.670%, 27.899% and 40.11% lower than that of the control group respectively; the carbon density of forest ecosystem was 172.61, 120.95 and 86.35 t∙hm^-2 after light, moderate and high forest fire disturbance, which decreased by 13.53%, 39.41% and 56.74% respectively compared with the control group; forest fire disturbance reduced the carbon density of eucalyptus forest, which showed a law of carbon density decreasing with the increase of forest fire disturbance intensity. Compared with the control group, the effect of light forest fire disturbance intensity on the carbon density of eucalyptus forest was not significant (P > 0.05), while the effect of moderate and high forest fire disturbance intensity on the carbon density of eucalyptus forest was significant (P < 0.05).

The Cu_2–xSe nanoparticles were synthesized by high temperature pyrolysis, modified with aminated polyethylene glycol in aqueous solution and loaded with compound 2,2′–azobis[2–(2–imidazolin–2–yl)propane] dihydrochloride (AIPH). The obtained nanomaterials can induce photothermal effect and use heat to promote the generation of toxic AIPH radicals under the irradiation of near-infrared laser (808 nm), which can effectively kill cancer cells. A series of in vitro experiments can preliminarily prove that Cu_2–xSe–AIPH nanomaterials have strong photothermal conversion ability, good biocompatibility and anticancer properties.

Based on first-principles methods, the authors of this paper investigate spin thermoelectric effects of one-dimensional spin-based devices consisting of zigzag-edged graphene nanoribbons (ZGNRs), carbon chains and graphene nanoflake. It is found that the spin-down transmission function is suppressed to zero, while the spin-up transmission function is about 0.25. Therefore, an ideal half-metallic property is achieved. In addition, the phonon thermal conductance is obviously smaller than the electronic thermal conductance. Meantime, the spin Seebeck effects are obviously enhanced at the low-temperature regime (about 80K), resulting in the fact that spin thermoelectric figure of merit can reach about 40. Moreover, the spin thermoelectric figure of merit is always larger than the corresponding charge thermoelectric figure of merit. Therefore, the study shows that they can be used to prepare the ideal thermospin devices.