The present study demonstrates the fabrication of heterogeneous ternary composite photocatalysts consisting of TiO₂, kaolinite, and cement (TKCe),which is essential to overcome the practical barriers that are inherent to currently available photocatalysts. TKCe is prepared via a cost-effective method, which involves mechanical compression and thermal activation as major fabrication steps. The clay-cement ratio primarily determines TKCe mechanical strength and photocatalytic efficiency, where TKCe with the optimum clay-cement ratio, which is 1:1, results in a uniform matrix with fewer surface defects. The composites that have a clay-cement ratio below or above the optimum ratio account for comparatively low mechanical strength and photocatalytic activity due to inhomogeneous surfaces with more defects, including particle agglomeration and cracks. The TKCe mechanical strength comes mainly from clay-TiO₂ interactions and TiO₂-cement interactions. TiO₂-cement interactions result in CaTiO₃ formation, which significantly increases matrix interactions; however, the maximum composite performance is observed at the optimum titanate level; anything above or below this level deteriorates composite performance. Over 90% degradation rates are characteristic of all TKCe, which follow pseudo-first-order kinetics in methylene blue decontamination. The highest rate constant is observed with TKCe 1-1, which is 1.57 h⁻¹ and is the highest among all the binary composite photocatalysts that were fabricated previously. The TKCe 1-1 accounts for the highest mechanical strength, which is 6.97 MPa, while the lowest is observed with TKCe 3-1, indicating that the clay-cement ratio has a direct relation to composite strength. TKCe is a potential photocatalyst that can be obtained in variable sizes and shapes, complying with real industrial wastewater treatment requirements.

Eco-friendly and greener barrier materials are required to replace the synthetic packaging materials as they produce a threat to environment. These can be fabricated by natural polymers such as cellulose nanofiber (CNF). The sustainability of CNF was so amazing due to its potential for circular economy and provides alternative platform for synthetic plastics. The challenging task to fabricate CNF films still existed and also current methods have various limitations. CNF films have good oxygen permeability and the value was lower than synthetic plastics. However, CNF films have poor water vapour permeability and higher than that of synthetic plastics. The fabrication method is one of strong parameters to impact on the water permeability of CNF films. The deposition of CNF suspension on the stainless-steel plate via spraying, is a potential process for fabrication for CNF films acting as barrier material against water vapour. In spraying process, the time required to form CNF films in diameter of 15.9 cm was less than 1 min and it is independent of CNF content in the suspension. The uniqueness of CNF films via the spraying process was their surfaces, such as rough surface exposed to air and smooth surface exposed to stainless steel. Their surfaces were investigated by SEM, AFM and optical profilometry micrographs, confirming that the smooth surface was evaluated notable lower surface roughness. The spray coated surface was smooth and glossy and its impact on the water vapor permeability remains obscure. The spraying process is a flexible process to tailor the basis weight and thickness of CNF films can be adjusted by the spraying of CNF suspension with varying fibre content. The water vapour permeability of CNF films can be tailored via varying density of CNF films. The plot between water vapour transfer rate (WVTR)/water vapour and density of CNF films has been investigated. The WVP of spray coated CNF films varied from 6.99 ± 1.17 × 10⁻¹¹ to 4.19 ± 1.45 × 10⁻¹¹ g/m.s.Pa. with the density from 664 Kg/m³ to 1,412.08 Kg/m³. The WVP of CNF films achieved with 2 wt% CNF films (1,120 Kg/m³) was 3.91 × 10⁻¹¹ g/m.s.Pa. These values were comparable with the WVP of synthetic plastics. Given this correspondence, CNF films via spraying have a good barrier against water vapour. This process is a potential for scale up and commercialization of CNF films as barrier materials.

The melon culture is one of the Brazilian horticultural crops, due to its productive potential and socio-economic role. It is recommended for the State of Goiás and the Federal District for it is easy to plant and having need of zoning of climatic conditions and thus, being able to perform their sowing. The present work used the Sarazon program to perform the water balance of the melon crop, for the 2nd, 4th and 6th five-day sowing dates in August, September and October and in relation to the water reserves in the soil of 50 mm and 75 mm. The data were spatialized using the SPRING 4.3 program. It was observed that the producers are performing in practice what can be demonstrated in theory that the period October 16–20 is the most indicated for sowing in soils of 50 mm of water reserve and October 6–10 the beginning of sowing in soil of 75 mm of water reserve for the cultivation of melon and have adequate profitability.

The agronomic and oenological behavior of the Pinot noir grape variety was studied in relation to different rootstocks on the Agroscope estate in Leytron (VS): 3309 C, 5 BB, Fercal, 41 BMGt, Riparia Gloire, 420 AMGt, 101-14 MGt and 161-49 C. Rootstock primarily influenced vigor, speed of vine establishment, and mineral nutrition of the graft. Riparia Gloire, 41 BMGt, 420 AMGt and 161-49 C rootstocks were less vigorous and, for the last three, induced a lower nitrogen and potassium supply leading to the production of slightly more acidic wines. The less vigorous rootstocks and 101-14 MGt were slightly more sensitive to water stress.

It increased the demands on ground-water supplies that prolonged drought and improper maintenance of water resources. So it is necessary to evaluate ground-water resources in the hard rock terrain. In recent years, Remote-Sensing methods have been increasingly recognized as a means of obtaining crucial geoscientific data for both regional and site-specific investigations. This work aims to develop and apply integrated methods combining the information obtained by geo-hydrological field mapping and those obtained by analyzing multi-source remotely sensed data in a GIS environment for better understanding the Groundwater condition in hard rock terrain. In this study, digitally enhanced Landsat ETM+ data was used to extract information on geology, geomorphology. The Hill-Shading techniques are applied to SRTM DEM data to enhance terrain perspective views, and extract Geomorphological features and morphologically defined structures through the means of lineament analysis. A combination of Spectral information from Landsat ETM+ data plus spatial information from SRTM-DEM data is used to address the groundwater potential of alluvium, colluvium, and fractured crystalline rocks in the study area. The spatial distribution of groundwater potential zones shows regional patterns related to lithologies, lineaments, drainage systems, and landforms. High-yielding wells and springs are often related to large lineaments and corresponding structural features such as dykes. The results show that the combination of remote sensing, GIS, traditional fieldwork, and models provide a powerful tool for water resources assessment and management, and groundwater exploration planning.