In order to explore the influence of the ferroelectric surface on the structure and properties of semiconductor oxides, the growth of CdS nanocrystals was regulated and controlled by taking single-crystal perovskite PbTiO3 nanosheets as the substrate through a simple hydrothermal method. Through composition design, a series of PbTiO3-CdS nanocomposite materials with different loading concentrations were prepared, and their microstructure and photocatalytic properties were systematically analyzed. Studies show that in the prepared product, CdS nanoparticles selectively grow on the surfaces of PbTiO3 nanosheets, and their morphology is affected by the exposed surfaces of PbTiO3 nanosheets. There is a clear interface between the PbTiO3 substrate and CdS nanoparticles. The concentration of the initial reactant and the time of hydrothermal reaction also significantly affect the crystal morphology of CdS. Photocatalysis studies have shown that the prepared PbTiO3-CdS nanocomposite material has a significant degradation effect on 10 mg/L of Rhodamine B aqueous solution. The degradation efficiency rises with the increase of CdS loading concentration. When degrading 10 mg/L Rhodamine B aqueous solution, the PbTiO3-CdS sample with a mass fraction of 3% can reach a degradation rate of 72% within 120 min.
Space is a product of society. Driven by industrialization, urbanization, informatization and government policies, China’s rural space is undergoing drastic reconstruction. As one of the core contents of international rural geography research, rural space research are multi-disciplinary, multi perspective, multi-dimensional and multi-method, forming a rich research field. In order to comprehensively grasp the progress of rural space research abroad, this study reviewed international rural space research literature in recent 40 years. The study found that foreign scholars described the connotation of rural space from the aspects of material, imagination and practice, emphasize the importance of daily life practice. It introduced living space to construct a more systematic research framework of rural space by establishing a “three-fold model of rural space”. With regard to the theoretical perspective, international research on rural space has experienced three stages: functionalism, political economics and social constructivism. In the evolution of time, it has realized the transformation from productivism to post-productivism; in the spatial dimension, it realizes the multiple superposition of settlement space, economic space, social space and cultural space. As a whole, international research on rural space has realized the transformation from material level to social representation, from objective space to subjective space, and from static one-dimensional space to dynamic multi-dimensional space, which enlightens us on the importance of interdisciplinary research and “social cultural” research on rural space. The construction of rural space in China needs to pay attention to the subject status of farmers and multifunction of rural space, respect the role of locality and difference of various places, and recover the function of production of meaning of rural space.
The rare earth mining area in South China is the main production base of ionic rare earth in the world, which has brought inestimable economic value to the local area and even the whole nation. However, due to the lack of mining technology and excessive pursuit for economic profits, a series of environmental problems have arisen, which is a great threat to the ecosystem of the mining area. Taking Lingbei rare earth mining area in Ganzhou as an example, this paper discriminated and analyzed such aspects as the ecological source, ecological corridor and ecological nodes of the mining area based on the landscape ecological security pattern theory and the minimum cumulative resistance model (MCR) method, and constructed a landscape ecological security pattern of the mining area during the 2009, 2013 and 2018. The results show that: i) The patch area of the ecological source of rare earth mining area is small, mainly concentrated in the east and west sides of the mining area. ii) During the selected year, the ecological source area, ecological corridors, radiation channels and the number of ecological nodes in the rare earth mining area are increasing, indicating that the landscape ecological security of the rare earth mining area has been improved to some extent, but it remains necessary for relevant departments to make a optimized planning to further reconstruct the ecological security pattern of the rare earth mining area.
This paper analyzed the equitable allocation of infrastructure across regional states in Ethiopia. In general, in the past years, there has been a good start in the infrastructure sector in Ethiopia. However, the governance and equity system of infrastructure in Ethiopia is not flexible, not technology-oriented, not fair, and not easily solved. The results of in-depth interviews and focus group discussions (FGDs) showed that there is a lack of institutional capacity, infrastructure governance, and equity, which has negatively impacted the state- and nation-building processes in Ethiopia. According to the interviewees, so long as the unmet demand for infrastructure exists, it remains a key restrain on doing business in most Ethiopian regional states. This is due to the lack of integrated frameworks, as there are coordination failures (lack of proper government intervention, including a lack of proper understanding and implementation of the constitution and the federal system). In Ethiopia, to reduce these bottlenecks arising from the lack of institutional capacity, infrastructure governance, and equity and their effects on nation-building, first of all, the government has to critically hear the people, deeply assess the problems, and come to the point and then discuss the problems and the way forward with the society at large.
Learning from experience to improve future infrastructure public-private partnerships is a focal issue for policy makers, financiers, implementers, and private sector stakeholders. An extensive body of case studies and “lessons learned” aims to improve the likelihood of success and attempts to avoid future contract failures across sectors and geographies. This paper examines whether countries do, indeed, learn from experience to improve the probability of success of public-private partnerships at the national level. The purview of the paper is not to diagnose learning across all aspects of public-private partnerships globally, but rather to focus on whether experience has an effect on the most extreme cases of public-private partnership contract failure, premature contract cancellation. The analysis utilizes mixed-effects probit regression combined with spline models to test empirically whether general public-private partnership experience has an impact on reducing the chances of contract cancellation for future projects. The results confirm what the market intuitively knows, that is, that public-private partnership experience reduces the likelihood of contract cancellation. But the results also provide a perhaps less intuitive finding: the benefits of learning are typically concentrated in the first few public-private partnership deals. Moreover, the results show that the probability of cancellation varies across sectors and suggests the relative complexity of water public-private partnerships compared with energy and transport projects. An estimated $1.5 billion per year could have been saved with interventions and support to reduce cancellations in less experienced countries (those with fewer than 23 prior public-private partnerships).
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