Europium (Eu) doped Calcium borophosphate (CBP) phosphors were synthesized via the solid-state diffusion method. The prepared Europium (Eu) doped Calcium borophosphate (CBP) powder was heated up to 600 ℃ for 6 h for a complete diffusion of ions in the powder system. XRD results showed that the prepared phosphors exhibit a well-crystallized hexagonal phase. The complete diffusion inside the CBP/Eu powder system has been confirmed by the presence of elements such as P, O, Bi, Ca, C, Eu, and B. Apart from that, the synthesized powder system has shown a down-conversion property where the Eu3+-activated ion was excited at 251 nm. Under the excitation of 251 nm, CBP/Eu phosphor showed intense emissions peaking at 591,617, and 693 nm due to the 5D0 → 7F1, 5D0 → 7F2, and 5D0 → 7F4 transition of Eu3+ ions. The obtained results suggest that the CBP/Eu phosphors have the potential for spectral response coating materials to improve photovoltaic (PV) panel efficiency.
The provided material presents a priority article on the scientific discovery titled “The phenomenon of simultaneous destruction of water-oil and oil-water emulsions”. The authors propose the corresponding formula: the previously unknown phenomenon of simultaneous destruction of water-oil and oil-water emulsions occurs when polynanostructured surfactant demulsifiers with characteristics akin to crystalline liquids, intramolecular interblock activity, and enduring intramolecular nanomotors (such as block copolymers of ethylene and propylene oxides, which act as sources of oligomer homologues of oxyethylene ethers) are added to crude oil during primary oil processing. This phenomenon is attributed to the redistribution of oligomer homologues, with the most hydrophobic oxyethylene ethers being dispersed in water-oil emulsions and the most hydrophilic ones in oil-water emulsions, resulting in robust nanodispersed phases with crystalline liquid properties.
The regularity and variability of the composition distribution of the pyrolysis products of corn stover fermentation residue and phenolic resin with the pyrolysis temperature were investigated by thermogravimetry (TG) and lyser-gas/mass spectrometer (Py-GC/MS). The results show that toluene, phenol and methyl phenol are the main common components of the two systems, 2,3-dihydrobenzofuran, alkoxy compounds and a small amount of carboxylic acid are the unique components in the pyrolysis products of corn straw fermentation residue, while dimethyl phenol, 9H-xanthene and other components in the phenolic. This is a reflection of the differences in the composition and structure of the two raw materials.
The problem of the synthesis of new type nanomaterials in the form of nano-coatings with sub-nanometric heterogeneity has been formulated. It has been presented an analysis of influences of physical vapor deposition in ultrahigh vacuum on the process of intermixing a film with a substrate, including the results, which has been obtained under the formation of transition metal – silicon interface. The generalization of the obtained experimental results develops an approach to the development of new nano-coatings with low-dimensional heterogeneity. The principles of constructing such low-dimensional nano-coatings, their properties and possible applications are considered.
A metakaolin-based geopolymer was fabricated with 5 ratios of two different nanomaterials. On the one hand, silicon carbide nanowhiskers and, on the other hand, titanium dioxide nanoparticles. Both were placed in water and received ultrasonic energy to be dispersed. The effects on mechanical properties and reaction kinetics were analyzed. Compared to the reference matrix, the results showed a tendency to increase the flexural strength. Probably due to the geometry of the SiC nanowhiskers and the pore refinement by the nano-TiO2 particles. The calorimetry curves showed that incorporating TiO2 nanoparticles resulted in a 92% reduction in total heat, while SiC nanowhiskers produced a 25% reduction in total heat.
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