Water pollution has become a serious threat to our ecosystem. Water contamination due to human, commercial, and industrial activities has negatively affected the whole world. Owing to the global demanding challenges of water pollution treatments and achieving sustainability, membrane technology has gained increasing research attention. Although numerous membrane materials have focused, the sustainable water purification membranes are most effective for environmental needs. In this regard sustainable, green, and recyclable polymeric and nanocomposite membranes have been developed. Materials fulfilling sustainable environmental demands usually include wide-ranging polyesters, polyamides, polysulfones, and recyclable/biodegradable petroleum polymers plus non-toxic solvents. Consequently, water purification membranes for nanofiltration, microfiltration, reverse osmosis, ultrafiltration, and related filtration processes have been designed. Sustainable polymer membranes for water purification have been manufactured using facile techniques. The resulting membranes have been tested for desalination, dye removal, ion separation, and antibacterial processes for wastewater. Environmental sustainability studies have also pointed towards desired life cycle assessment results for these water purification membranes. Recycling of water treatment membranes have been performed by three major processes mechanical recycling, chemical recycling, or thermal recycling. Moreover, use of sustainable membranes has caused positive environmental impacts for safe waste water treatment. Importantly, worth of sustainable water purification membranes has been analyzed for the environmentally friendly water purification applications. There is vast scope of developing and investigating water purification membranes using countless sustainable polymers, materials, and nanomaterials. Hence, value of sustainable membranes has been analyzed to meet the global demands and challenges to attain future clean water and ecosystem.
In the present work, a series of butyl methacrylate/1-hexene copolymers were synthesized, and their efficiency as viscosity index improvers, pour point depressants, and shear stabilizers of lube oil was investigated. The effect of 1-hexene molar ratio, type, and concentration of Lewis acids on the incorporation of 1-hexene into the copolymer backbone was investigated. The successful synthesis of the copolymers was confirmed through FTIR and 1H NMR spectroscopy. Results obtained from quantitative 1H NMR and GPC revealed that an increase in the molar ratio of 1-hexene to butyl methacrylate, along with concentration of Lewis acids led to an increase in 1-hexene incorporation and a reduction in Mn and Ð. Similar trends were observed when the Lewis acid changed from AlCl3 to organometallic acids. The maximum 1-hexene incorporation (26.4%) was achieved for sample BHY3, with a [1-hexene/BMA] ratio of 4 mol% and a [Yb(OTf)3/BMA] ratio of 2.5 mol%. Evaluation of the synthesized copolymers as lube oil additives demonstrated that the viscosity index was more significantly influenced by samples with higher molecular weight. Sample BHA13 represents maximum VI of 137. The copolymer containing Yb(OTf)3 as a catalyst exhibited superior efficiency as a pour point depressant. Furthermore, sample BHY3 showed the lowest shear stability index (6.4).
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