Lead sulfide (PbS) is an important IV-VI semiconductor material with narrow bandwidth and wide wave width, which attracts people's attention. Nano-level PbS has many novel optoelectronic properties and has a wide range of applications in the field of optoelectronics, such as infrared optoelectronic devices, photovoltaic devices, light-emitting devices and display devices. In this paper, Pbs is produced by solvent thermal method by using lead acetate as lead source, sulfur power as sulfur source, ethylene glycol as solvent, and acetic acid to provide acidic environment. The reaction acidity, type of lead source, amount of sulfur source and other aspects will be explored. The products obtained under different conditions were characterized by X-ray diffraction (XRD), optical microscopy and scanning electron microscopy (SEM). The results showed that PbS produced at 140°C for 24 hours, using 14mL ethylene glycol and 1.2mL acetic acid has the best morphology. It has a non-planar six-arm symmetrical structure. Finally, we prepare the lead sulfide composite Ni/PbS, and characterized it.
Modern agricultural production technologies based on the widespread use of pesticides and mineral fertilizers have largely solved the problem of providing the population with food, and at the same time have generated multiple ecological, medical and environmental problems, problems of environmentally friendly and biologically valuable food products, land rehabilitation, restoration of their fertility, etc. Therefore, the emergence of new classes of pesticides with different mechanisms of action, high selectivity and low toxicity for warm-blooded animals is very modern. Currently, the development and application of new plant protection products that are not toxic to humans and animals is of global importance. Priority is given to research aimed at creating plant protection products based on microorganisms and their metabolites, as well as the search for plant substances with potential pesticide activity. In this regard, the question arose of finding new safe fertilizers that can also be economically profitable for production on an industrial scale. One of the current trends in this industry is the use of green microalgae. In this regard, the purpose of our research is the possibility of cultivating green microalgae on phosphorus production waste. During the work, traditional and modern research methods in biology were used. As a result of the work, several problems can be solved, such as the disposal of industrial waste and the production of safe biological fertilizer.
The size effect on the free vibration and bending of a curved FG micro/nanobeam is studied in this paper. Using the Hamilton principle the differential equations and boundary conditions is derived for a nonlocal Euler-Bernoulli curved micro/nanobeam. The material properties vary through radius direction. Using the Navier approach an analytical solution for simply supported boundary conditions is obtained where the power index law of FGM, the curved micro/nanobeam opening angle, the effect of aspect ratio and nonlocal parameter on natural frequencies and the radial and tangential displacements were analyzed. It is concluded that increasing the curved micro/nanobeam opening angle results in decreasing and increasing the frequencies and displacements, respectively. To validate the natural frequencies of curved nanobeam, when the radius of it approaches to infinity, is compared with a straight FG nanobeam and showed a good agreement.
This research study explores the addition of chromium (Cr6+) ions as a nucleating agent in the alumino-silicate-glass (ASG) system (i.e., Al2O3-SiO2-MgO-B2O3-K2O-F). The important feature of this study is the induction of nucleation/crystallization in the base glass matrix on addition of Cr6+ content under annealing heat treatment (600 ± 10 °C) only. The melt-quenched glass is found to be amorphous, which in the presence of Cr6+ ions became crystalline with a predominant crystalline phase, Spinel (MgCr2O4). Microstructural experiment revealed the development of 200–500 nm crystallite particles in Cr6+-doped glass-ceramic matrix, and such type microstructure governed the mechanical properties. The machinability of the Cr-doped glass-ceramic was thereby higher compared to base alumino-silicate glass (ASG). From the nano-indentation experiment, the Young’s modulus was estimated 25(±10) GPa for base glass and increased to 894(±21) GPa for Cr-doped glass ceramics. Similarly, the microhardness for the base glass was 0.6(±0.5) GPa (nano-indentation measurements) and 3.63(±0.18) GPa (micro-indentation measurements). And that found increased to 8.4(±2.3) (nano-indentation measurements) and 3.94(±0.20) GPa (micro-indentation measurements) for Cr-containing glass ceramic.
The micro staring hyperspectral imager can simultaneously acquire two spatial and one spectral images, and only record the external orientation elements of the entire hyperspectral image rather than the external orientation elements of each frame of the image, which avoids the geometric instability during scanning, effectively solves the problem of large geometric deformation of the small line scanning hyperspectral imager, and is suitable for the small UAV load platform with unstable attitude. At present, most of the research focuses on the radio-metric correction method of line scan hyperspectral imager. The application time of staring hyperspectral imager is short, and there is no mature data processing re-search at home and abroad, which hinders the application of UAV micro staring hyperspectral imaging system. In this paper, the calibration method of the linearity and variability of the radiation response of the micro staring hyperspectral imager on the UAV is studied, and the effectiveness of this method is quantitatively evaluated. The results show that the hyperspectral image has obvious vignetting effect and strip phenomenon before the correction of radiation response variability. After the correction, the radiation response variation coefficient of pixels in different bands decreases significantly, and the vignetting effect and image strip decrease significantly. In this paper, a multi-target radiometric calibration method is proposed, and the accuracy of radiometric calibration is verified by comparing the calibrated hyperspectral image spectrum with the measured ground object spectrum of the ground spectrometer. The results show that the calibration results of the multi-target radiometric calibration method show better results, especially for the near-infrared band, and the difference with the surface reflectance measured by the spectrometer is small.
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